Citation: LUO Qian-Qian, LIN He-Chun, LUO Chun-Hua, ZHANG Yuan-Yuan, PENG Hui. Syntheses of Imidazole Template Fe₄ Sulfate Clusters and Iron-DMSO Complex Mediated by Brønsted Acid Ionic Liquids[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(12): 2186-2192. doi: 10.11862/CJIC.2017.259 shu

Syntheses of Imidazole Template Fe₄ Sulfate Clusters and Iron-DMSO Complex Mediated by Brønsted Acid Ionic Liquids

1.
Key Laboratory of Polar Materials and Devices, Ministry of Education, East China Normal University, Shanghai 200141, China
2.
Collaborative Innovation Center of Extreme Optics, Shanxi University, Taiyuan 030006, China

Corresponding author: LIN He-Chun, hclin@ee.ecnu.edu.cn
Received Date: 11 June 2017
Revised Date: 13 October 2017

Figures(7)

Imidazole template iron sulfate clusters, [HMIM]₂[Fe₂O(SO₄)₃(DMSO)₂]·0.5DMSO (1) and[HPIM]₄[Fe₄O₂(SO₄)₆(DMSO)₄]·2MeCN (2), were synthesized via the reaction of FeCl₂ with Brønsted acidic ionic liquid[HRIM] [HSO₄] using ethanol as solvent. The clusters crystallize in triclinic with a space group P1. The core contains 4 iron atoms, which are coplanar connected by the central μ₃-O bridge, μ₂-O and μ₃-O bridge of SO₄ groups. Protonated imidazoliums are the counter cations for the balance of charges of the core. Variable temperature magnetic susceptibility measurements of the Fe₄ sulfate clusters reveal weak antiferromagnetic exchange interactions between the metal centers. In contrast, the reaction of FeCl₃ under the similar experimental conditions didn't produce the similar cluster structure, whereas iron-DMSO complex[FeCl₂(DMSO)₄] [EtSO₄]·DMSO (3) was obtained.
- polynuclear ferric cluster,
- open-framework,
- brnsted acidic ionic liquid,
- antiferromagnetic
1. [1]
  Nair V S, Hagen K S. Inorg. Chem., 1992, 31:4048-4050 doi: 10.1021/ic00046a011
2. [2]
  Taft K L, Papaefthymiou G C, Lippard S J. Inorg. Chem., 1994, 33:1510-1520 doi: 10.1021/ic00085a049
3. [3]
  Frank P, DeTomaso A, Hedman B, et al. Inorg. Chem., 2006, 45:3920-3931 doi: 10.1021/ic051445x
4. [4]
  Taft K, Papaefthymiou G, Lippard S. Science, 1993, 259:1302-1305 doi: 10.1126/science.8446898
5. [5]
  Gomez-Coca S, Ruiz E, Kortus J. Chem. Commun., 2009:4363-4365
6. [6]
  Ruiz E, Cano J, Alvarez S. Chem. Eur. J., 2005, 11:4767-4771 doi: 10.1002/(ISSN)1521-3765
7. [7]
  Petukhov K, Bahr S, Wernsdorfer W, et al. Phys. Rev. B, 2007, 75:064408 doi: 10.1103/PhysRevB.75.064408
8. [8]
  Benelli C, Cano J, Journaux Y, et al. Inorg. Chem., 2001, 40:188-189 doi: 10.1021/ic000840e
9. [9]
  Schlegel C, Slageren J, Manoli M, et al. Polyhedron, 2009, 28:1834-1837 doi: 10.1016/j.poly.2009.01.030
10. [10]
  Zhu Y Y, Guo X, Cui C, et al. Chem. Commun., 2011, 47:8049-8051 doi: 10.1039/c1cc12831k
11. [11]
  Rigamonti L, Piccioli M, Malavolti L, et al. Inorg. Chem., 2013, 52:5897-5905 doi: 10.1021/ic400037c
12. [12]
  Jeon I R, Park J G, Xiao D J, et al. J. Am. Chem. Soc., 2013, 135:16845-16848 doi: 10.1021/ja409927v
13. [13]
  Nachtigall O, Kusserow M, Clérac R, et al. Angew. Chem. Int. Ed., 2015, 54:10361-10364 doi: 10.1002/anie.201503647
14. [14]
  Koumousi E S, Routzomani A, Nguyen T N, et al. Inorg. Chem., 2013, 52:1176-1178 doi: 10.1021/ic3023908
15. [15]
  Bagai R, Daniels M R, Abboud K A, et al. Inorg. Chem., 2008, 47:3318-3327 doi: 10.1021/ic7024022
16. [16]
  Alborés P, Rentschler E. Inorg. Chem., 2008, 47:7960-7962 doi: 10.1021/ic801113d
17. [17]
  Stamatatos T C, Boudalis A K, Sanakis Y, et al. Inorg. Chem., 2006, 45:7372-7381 doi: 10.1021/ic0604821
18. [18]
  Casey C P, Guan H. J. Am. Chem. Soc., 2009, 131:2499-2507 doi: 10.1021/ja808683z
19. [19]
  Jones L F, Low D M, Helliwell M, et al. Polyhedron, 2006, 25:325-333 doi: 10.1016/j.poly.2005.08.034
20. [20]
  Ferguson A, Thomas L H, Murrie M. Polyhedron, 2013, 52:227-233 doi: 10.1016/j.poly.2012.09.043
21. [21]
  Ferguson A, McGregor J, Brechin E K, et al. Dalton Trans., 2009:9395-9397
22. [22]
  Masello A, Sanakis Y, Boudalis A K, et al. Inorg. Chem., 2011, 50:5646-5654 doi: 10.1021/ic200348s
23. [23]
  Rajaraman G, Cano J, Brechin E K, et al. Chem. Commun., 2004:1476-1477
24. [24]
  Mitchell K J, Abboud K A, Christou G. Inorg. Chem., 2016, 55:6597-6608 doi: 10.1021/acs.inorgchem.6b00769
25. [25]
  Taguchi T, Stamatatos T C, Abboud K A, et al. Inorg. Chem., 2008, 47:4095-4108 doi: 10.1021/ic701756p
26. [26]
  Mulyana Y, Nafady A, Mukherjee A, et al. Inorg. Chem., 2009, 48:7765-7781 doi: 10.1021/ic900729d
27. [27]
  Murali M, Nayak S, Costa J S, et al. Inorg. Chem., 2010, 49:2427-2434 doi: 10.1021/ic902360x
28. [28]
  TIAN Ju-Mei, CUI Zheng, ZHANG Jing-Ping. Chinese J. Inorg. Chem., 2017, 33(9):1625-1630
29. [29]
  WANG Ming, PAN Qun-Hui, SHEN Tao, et al. Chinese J. Inorg. Chem., 2005, 21(9):1296-1300
30. [30]
  Choudhury A, Krishnamoorthy J, Rao C N R. Chem. Commun, 2001:2610-2611
31. [31]
  Maspoch D, Ruiz-Molina D, Veciana J. Chem. Soc. Rev., 2007, 36:770-818 doi: 10.1039/b501600m
32. [32]
  Yahyaoui S, Rekik W, Nali H, et al. J. Solid State Chem., 2007, 180:3560-3570
33. [33]
  Behera J N, Rao C N R. Chem. Eur. J., 2006, 1:742-750 doi: 10.1016/j.jssc.2007.10.019
34. [34]
  Paul G, Choudhury A, Sampathkumaran E V, et al. Angew. Chem. Int. Ed., 2002, 41:4297-4300 doi: 10.1002/1521-3773(20021115)41:22<4297::AID-ANIE4297>3.0.CO;2-E
35. [35]
  Behera J N, Rao C N R. Inorg. Chem., 2006, 45:9475-9479 doi: 10.1021/ic061457y
36. [36]
  Fu Y, Xu Z, Ren J, et al. Cryst. Growth Des., 2007, 7:1198-1204 doi: 10.1021/cg0607506
37. [37]
  Dan M. J. Mol. Struct., 2004, 706:127-131 doi: 10.1016/j.molstruc.2004.02.054
38. [38]
  Paul G, Choudhury A, Rao C N R. Chem. Mater., 2003, 15:1174-1180 doi: 10.1021/cm020772p
39. [39]
  Calligaris M. Coord. Chem. Rev., 2004, 248:351-375 doi: 10.1016/j.ccr.2004.02.005
40. [40]
  Lin H, de Oliveira P W, Huch V, et al. Chem. Mater., 2010, 22:6518-6523 doi: 10.1021/cm101490w
41. [41]
  Luo Q Q, Lin H C, Zhang Y Y, et al. Inorg. Chim. Acta, 2016, 447:32-37 doi: 10.1016/j.ica.2016.03.023
42. [42]
  Sheldrick G M. Acta Crystallogr. Sect. A:Found. Crystallogr., 2008, A64:112-122
43. [43]
  Dolomanov O V, Bourhis L J, Gildea R J, et al. J. Appl. Crystallogr., 2009, 42:339-341 doi: 10.1107/S0021889808042726
44. [44]
  Evans P N, Albertson J M. J. Am. Chem. Soc., 1917, 39:456-461 doi: 10.1021/ja02248a014
45. [45]
  Murali M, Nayak S, Costa J S, et al. Inorg. Chem., 2010, 49:2427-2434 doi: 10.1021/ic902360x
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Syntheses of Imidazole Template Fe4 Sulfate Clusters and Iron-DMSO Complex Mediated by Brønsted Acid Ionic Liquids

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通讯作者: 陈斌, bchen63@163.com

Syntheses of Imidazole Template Fe₄ Sulfate Clusters and Iron-DMSO Complex Mediated by Brønsted Acid Ionic Liquids