Citation: JI Qing-Yan, WANG Qian, LI Hong-Xin, XUE Dong-Xu, BAI Jun-Feng. An eea Topological Metal-Organic Framework with High Methane Uptake[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(11): 2031-2037. doi: 10.11862/CJIC.2017.245 shu

An eea Topological Metal-Organic Framework with High Methane Uptake

JI Qing-Yan ¹ ,
WANG Qian ^1,, ,
LI Hong-Xin ¹ ,
XUE Dong-Xu ¹ ,
BAI Jun-Feng ^1,2,,

1.
Key Laboratory of Applied Surface and Colloid Chemistry, Ministry of Education, School of Chemistry & Chemical Engineering, Shaanxi Normal University, Xi'an 710062, China
2.
State Key Laboratory f Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China

Corresponding author: WANG Qian, wangq@snnu.edu.cn BAI Jun-Feng, bjunfeng@nju.edu.cn
Received Date: 21 July 2017
Revised Date: 13 September 2017

Figures(6)

A new 3D porous MOF, {[CuL]·x(Solvent)}_n (1) have been successfully synthesized based upon a bifunctional organic ligand with two carboxyl groups and one nitrogen donor of 5-(quinolin-6-yl)isophthalic acid (H₂L). MOF 1 exhibits an eea topological network with the point (Schläfli) symbol of {4².6}₂{4⁴.6².8⁶.10³}. Remarkably, desolvated 1 performs a high CH₄ adsorption enthalpy and high methane uptake at high pressure and 298 K.
- Cu(Ⅱ) complex,
- eea topology,
- CH₄ storage
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