Citation: HE Deng-Liang, LIU Shu-Xin, QIN Hai-Li, SHEN Fang, WANG Xue-Li, LIU Lan, RUAN Qi-Ping. Synthesis of K₂FeO₄ for Removing Heavy Metals in the Phenol-Aqueous Solution[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(10): 1825-1834. doi: 10.11862/CJIC.2017.237 shu

Synthesis of K₂FeO₄ for Removing Heavy Metals in the Phenol-Aqueous Solution

HE Deng-Liang ^1,, ,
LIU Shu-Xin ^1,, ,
QIN Hai-Li ¹ ,
SHEN Fang ^1,2 ,
WANG Xue-Li ¹ ,
LIU Lan ¹ ,
RUAN Qi-Ping ¹

1.
School of chemistry and chemical engineering, Mianyang Normal University, Mianyang, Sichuan 621000, China
2.
College of Chemistry and Materials Science, Sichuan Normal University, Chengdu 610068, China

Corresponding author: HE Deng-Liang, 449011902@qq.com LIU Shu-Xin, liushuxin88@126.com
Received Date: 4 February 2017
Revised Date: 4 September 2017

Figures(11)

K₂FeO₄ was synthesized by wet chemical method with calcium hypochlorite and iron nitrate nonahydrate as raw material. The contrative analysis from X ray diffraction(XRD), scanning electron microscope(SEM), infrared absorption spectrometer(FTIR) and energy dispersive spectrometer(EDS) show that higher purity and more uniform K₂FeO₄ crystals can be obtained by second recrystallized purification from crude products. Several experiments were performed to investigate the removal properties of K₂FeO₄ on Cu(Ⅱ) and Cd(Ⅱ) ions in the phenol-aqueous solution, including dosage of K₂FeO₄, shock time, solution pH, shock temperature, initial concentration and mixed ions. The K₂FeO₄ can remove Cu(Ⅱ), Cd(Ⅱ) and degrade phenol from phenol-aqueous solution in a single step of treatment. In addition, the removal mechanisms of metal ions including of adsorption, co-precipitate and surface complexation were revealed by scanning electron microscope (SEM), energy dispersive spectrometer (EDS), fourier transform infrared absorption spectrum (FTIR) in detail. The research results can provide a water treatment agent, which may be used to treat wastewater containing heavy metal and organic matter.
- K₂FeO₄,
- synthesis,
- remove,
- heavy metal,
- phenol
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沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis of K2FeO4 for Removing Heavy Metals in the Phenol-Aqueous Solution

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通讯作者: 陈斌, bchen63@163.com

Synthesis of K₂FeO₄ for Removing Heavy Metals in the Phenol-Aqueous Solution