Citation: ZENG Xue-Hua, LUO Yan-Sheng, HE Li-Hua, CHEN Jing-Lin, ZHANG Meng-Li, LIAO Jin-Sheng, LIU Sui-Jun, WEN He-Rui. Luminescent Mononuclear Copper(Ⅰ) Diphosphine Complexes with 6-Methoxycarbonyl-4, 4'-dimethyl-2, 2'-bipyridine[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(10): 1810-1816. doi: 10.11862/CJIC.2017.234 shu

Luminescent Mononuclear Copper(Ⅰ) Diphosphine Complexes with 6-Methoxycarbonyl-4, 4'-dimethyl-2, 2'-bipyridine

School of Metallurgy and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou, Jiangxi 341000, China

Corresponding author: CHEN Jing-Lin, gzchenjinglin@126.com
Received Date: 13 April 2017
Revised Date: 26 August 2017

Figures(4)

Two new mononuclear copper(Ⅰ) diphosphine complexes based on 6-methoxycarbonyl-4, 4'-dimethyl-2, 2'-bipyridine (mmbpy), [Cu(mmbpy)(dppp)]ClO₄ (1) and [Cu(mmbpy)(dppb)]ClO₄ (2), have been synthesized and characterized. It is revealed that Cu(Ⅰ) complexes 1 and 2 all exhibit distorted N₂P₂ tetrahedral geometries with varied P-Cu-P angles regulated by auxiliary diphosphine ligands. The two Cu(Ⅰ) complexes are all emissive in the solid state at ambient temperature, and their photophysical properties are more markedly influenced by the P-Cu-P angle than the methylene chain length of diphosphine. It is also demonstrated that the introduction of two methyl substituents into the 2, 2'-bipyridyl ring is effective for improving luminescence properties of Cu(Ⅰ) complexes.
- Cu(Ⅰ) complex,
- methoxycarbonyl,
- methyl,
- diphosphine,
- luminescence
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