Citation: CHEN Jin-Wei, WEN Bing-Song, CAO Fang-Li, QIU Wen-Da, LI Yu, CHEN Xiao-Ling. Syntheses, Crystal Structures and Magnetic Properties of 1D Manganese(Ⅱ) and 2D Copper(Ⅱ) Coordination Polymers Constructed from Biphenyl Tetracarboxylic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(12): 2322-2328. doi: 10.11862/CJIC.2017.229 shu

Syntheses, Crystal Structures and Magnetic Properties of 1D Manganese(Ⅱ) and 2D Copper(Ⅱ) Coordination Polymers Constructed from Biphenyl Tetracarboxylic Acid

1.
School of Light Chemical Engineering, Guangdong Industry Polytechnic, Guangzhou 510300, China
2.
School of Chemical Engineering and Light Industry, Guangdong University of Techlonogy, Guangzhou 510006, China
3.
School of Eco-Environmental Engineering, Guangdong Industry Polytechnic, Guangzhou 510300, China

Corresponding author: LI Yu, liyuletter@163.com CHEN Xiao-Ling, lggcxl@163.com
Received Date: 6 July 2017
Revised Date: 23 August 2017

Figures(8)

One-dimensional manganese(Ⅱ) and two-dimensional copper(Ⅱ) coordination polymers, namely[Mn(μ₃-2, 4-H₂bpta)(4, 4'-bipy)₂]_n (1) and {[Cu(μ₄-3, 5-bpta)_0.5(2, 2'-bipy)(H₂O)]·H₂O}_n (2), have been constructed hydro-thermally using 2, 4-H₄bpta (2, 4-H₄bpta=biphenyl-2, 2', 4, 4'-tetracarboxylic acid), 3, 5-H₄bpta (3, 5-H₄bpta=biphenyl-3, 3', 5, 5'-tetracarboxylic acid), 4, 4'-bipy (4, 4'-bipy=4, 4'-bipyridine) or 2, 2'-bipy (2, 2'-bipy=2, 2'-bipyridine), and manganese or copper chlorides. Single-crystal X-ray diffraction analyses reveal that the two complexes crystallize in the monoclinic system, space group P2₁/c or C2/c. In complex 1, the carboxylate groups of 2, 4-H₂bpta^2- ligands bridge alternately neighboring Mn(Ⅱ) ions to form a double-helix chain. Adjacent chains are assembled to a 2D supramolecular network through O-H…N hydrogen bond. Complex 2 shows a 2D sheet. Magnetic studies for complex 1 demonstrate a ferromagnetic coupling between the adjacent Mn(Ⅱ) centers.
- coordination polymer,
- hydrogen bonding,
- tetracarboxylic acid,
- magnetic properties
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沈阳化工大学材料科学与工程学院沈阳 110142