Citation: CAI Jian-Xin, LI Zhi-Peng, LI Wei, ZHAO Peng-Fei, YANG Zhen-Yu, YU Ji. Synthesis and Electrochemical Performance of Si@void@C Composite Anode Material for Lithium Ion Battery[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(10): 1763-1768. doi: 10.11862/CJIC.2017.226 shu

Synthesis and Electrochemical Performance of Si@void@C Composite Anode Material for Lithium Ion Battery

CAI Jian-Xin ^1,, ,
LI Zhi-Peng ¹ ,
LI Wei ¹ ,
ZHAO Peng-Fei ¹ ,
YANG Zhen-Yu ² ,
YU Ji ²

1.
College of Resources Environmental & Chemical Engineering, Nanchang University, Nanchang 330031, China
2.
College of Chemistry, Nanchang University, Nanchang 330031, China

Corresponding author: CAI Jian-Xin, cjx@ncu.edu.cn
Received Date: 21 February 2017
Revised Date: 1 September 2017

Figures(8)

The Si@void@C composites were prepared by a stober method with Si nanoparticles as the cores. This preparation process involved coating a SiO₂ layer through hydrolyzing and self-assembly approach of TEOS, coating a carbon layer through in-situ polymerization and high temperature carbonization of dopamine, and etching SiO₂ by HF. Crystalline structure, morphology and electrochemical performances of the composites were characterized by X-ray diffraction, scanning electron microscope, TEM and charge-discharge tests. The results indicate that the Si@void@C anode material retains a charge capacity of 1 319.5 mAh·g^-1 at current density of 0.1 A·g^-1 along with the capacity retention of 78.4% after 100 cycles, and shows an excellent electrochemical performance.
- silicon,
- carbon coating,
- Si@void@C anode material,
- lithium ion battery
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沈阳化工大学材料科学与工程学院沈阳 110142