Citation: JIANG Xiu-Yan, RONG Nian-Xin, QIU Tian-Tian, QIAN Rui, WANG Yan-Zhen, HE Qing-Peng, HUANG Xian-Qiang. Cu(Ⅱ)/Mn(Ⅱ) Complexes Formed by Pyrazole-3-carboxylic Acid:Syntheses, Characterization and Highly Efficient Conversion of CO₂ at Atmospheric Pressure[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(12): 2303-2310. doi: 10.11862/CJIC.2017.222 shu

Cu(Ⅱ)/Mn(Ⅱ) Complexes Formed by Pyrazole-3-carboxylic Acid:Syntheses, Characterization and Highly Efficient Conversion of CO₂ at Atmospheric Pressure

1.
School of Chemical Engineering, Shengli College, China University of Petroleum, Dongying, Shandong 257061, China
2.
Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, School of Chemistry & Chemical Engineering, Liaocheng University, Liaocheng, Shandong 252059, China

Corresponding author: HE Qing-Peng, heqingpeng@lcu.edu.cn HUANG Xian-Qiang, hxqqxh2008@163.com
Received Date: 23 May 2017
Revised Date: 22 July 2017

Figures(6)

Two transition metal complexes:Cu₂(pca)₂(H₂O)₆·2H₂O (1) and Mn(Hpca)₂(phen)·3H₂O (2) (H₂pca=pyrazole-3-carboxylic acid; phen=phenanthroline) have been prepared based on pyrazole-3-carboxylic acid and structurally characterized. The single crystal X-ray diffraction analysis reveals that complex 1 crystallizes in the monoclinic system P2₁/n space group and the binuclear copper center in 1 and mononuclear Mn(Ⅱ) center in 2 possess the distorted octahedral geometry. The three dimensional 3D framework of 1 and 2 are formed by the intermolecular O-H…O, N-H…O hydrogen bonding interactions. Importantly, complex 1 exhibits excellent heterogeneous catalytic performance (Conversion:up to 97.4%, Selectivity:up to 98.9%) in the catalytic conversion of CO₂ to cyclic carbonate.
- pyrazole-3-carboxylic acid,
- complex,
- crystal structure,
- conversion of CO₂
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Cu(Ⅱ)/Mn(Ⅱ) Complexes Formed by Pyrazole-3-carboxylic Acid:Syntheses, Characterization and Highly Efficient Conversion of CO2 at Atmospheric Pressure

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通讯作者: 陈斌, bchen63@163.com

Cu(Ⅱ)/Mn(Ⅱ) Complexes Formed by Pyrazole-3-carboxylic Acid:Syntheses, Characterization and Highly Efficient Conversion of CO₂ at Atmospheric Pressure