Citation: WANG Lin-Xiang. Preparation and Luminescence Properties of CaWO₄:xEu³⁺, ySm³⁺, zLi⁺ Red Phosphors[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(10): 1741-1747. doi: 10.11862/CJIC.2017.213 shu

Preparation and Luminescence Properties of CaWO₄:xEu³⁺, ySm³⁺, zLi⁺ Red Phosphors

WANG Lin-Xiang ^1,2,,

1.
College of Physics and Electronic Engineering, Xinjiang Normal University, Urumqi 830054, China
2.
Key Laboratory of Novel Luminescent Materials and Nanostructures, Xinjiang Normal University, Urumqi 830054, China

Corresponding author: WANG Lin-Xiang, wanglinxiang23@126.com
Received Date: 28 March 2017
Revised Date: 15 May 2017

Figures(5)

CaWO₄:xEu³⁺, ySm³⁺, zLi⁺ red phosphors were prepared by the microwave solid state method. The XRD was used to analyze the microstructures of samples. The excitation spectra, emission spectra and luminescence decay curves of the samples were measured. The influences of the concentration of Sm³⁺, Eu³⁺, Li⁺ on the microstructure, luminescence properties, energy transfer, fluorescence decay and energy level lifetime for synthesized samples were researched. The results show that the doping of Eu³⁺, Sm³⁺ or Li⁺ can not cause the change of the crystalline phase of the synthesized powders, which is still single tetragonal structure of CaWO₄. For Eu³⁺ and Sm³⁺ co-doped samples, when the doping concentration of Sm³⁺ was 3%, and the energy transfer from Sm³⁺ to Eu³⁺ was the most effective. The doped Li⁺ acted as a flux and sensitizer, which improved the luminescent intensity of the sample. At the excitation wavelength 394 nm, compared with Eu³⁺ single doped CaWO₄, the luminescence of 3%Eu³⁺, 3%Sm³⁺ co-doped CaWO₄ and 3%Eu³⁺, 3%Sm³⁺, 1%Li⁺ co-doped CaWO₄ increased by 2 times and 2.4 times respectively. At the same excitation wavelength, Eu³⁺ single doped samples had the shortest lifestime. With the increase of Sm³⁺ concentration, the lifetime of Eu³⁺, Sm³⁺ co-doped samples first decreased and then increased. The ⁵D₀ energy level lifetime of the sample doped with Li⁺ increased compared the sample without Li⁺.
- microwave solid state method,
- CaWO₄:xEu³⁺, ySm³⁺, zLi⁺,
- energy transfer,
- luminescence intensity,
- energy level lifetime
1. [1]
  Xie W, Liu G X, Dong X T, et al. RSC Adv., 2016, 6:26239-26246 doi: 10.1039/C6RA02594C
2. [2]
  WU Jin-Xiu, LI Mei, LIU Shao-Gang, et al. Chinese J. Inorg. Chem., 2016, 32(1):34-42
3. [3]
  Zhang F, Li G Q, Huang Y, et al. J. Mater. Sci., 2015, 50(13):4772-4778 doi: 10.1007/s10853-015-9031-z
4. [4]
  Zhai Y Q, Wang M, Zhao Q, et al. J. Lumin., 2015, 172(4):161-167
5. [5]
  Zhou H P, Wang Q P, Jiang M S, et al. Dalton Trans., 2015, 44(31):13962-13968 doi: 10.1039/C5DT01441G
6. [6]
  Chen G, Wang F, Yu J, et al. J. Mol. Struct., 2017, 1128:1-4 doi: 10.1016/j.molstruc.2016.08.041
7. [7]
  Zhou J, Xia Z G, Bettinelli M, et al. RSC Adv., 2016, 6(3):2046-2054 doi: 10.1039/C5RA23373A
8. [8]
  WU Jin-Xiu, LI Mei, CUI Song-Song, et al. Chinese J. Inorg. Chem., 2017, 33(2):219-226 doi: 10.11862/CJIC.2017.036
9. [9]
  LIANG Feng, HU Yi-Hua, CHEN Li, et al. Acta Phys. Sin., 2013, 62(18):116-121
10. [10]
  GAO Yang, LÜQiang, WANG Yang, et al. Acta Phys. Sin., 2012, 61(7):459-467
11. [11]
  JIANG Xiao-Lan, LÜShu-Chen. Opt. Instrum., 2012, 34(3):66-70
12. [12]
  Du C F, Yi G E, Su Y G, et al. J. Mater. Sci., 2012, 47(17):6305-6314 doi: 10.1007/s10853-012-6553-5
13. [13]
  Li G F, Gao S, He W W. Optik, 2015, 126:3272-3275 doi: 10.1016/j.ijleo.2015.07.192
14. [14]
  HAO Min-Ru, HU Hui-Yong, LI Gui-Fang, et al. J. Chin. Ceram. Soc., 2015, 43(4):476-481
15. [15]
  Chen Y Q, Yang H K, Park S W, et al. J. Alloys Compd., 2012, 511:123-128 doi: 10.1016/j.jallcom.2011.09.004
16. [16]
  HAO Min-Ru, LI Gui-Fang, HE Wen-Wen. J. Chin. Ceram. Soc., 2013, 41(12):1730-1734
17. [17]
  ZHANG Li-De, MOU Ji-Mei. Nano-material and Nanostructure. Beijing:Science Press, 2001.
18. [18]
  FU Qi-Hui, LIU Jun-Wu. Powd. Metal. Ind., 2016, 5:11-15
19. [19]
  Saraf R, Shivakumara C, Dhananjaya N, et al. J. Mater. Sci., 2015, 50(1):287-298 doi: 10.1007/s10853-014-8587-3
20. [20]
  Kang D, Yoo H S, Jung S H, et al. J. Phys. Chem. C, 2011, 115(49):24334-24340 doi: 10.1021/jp202742m
21. [21]
  Xia Z G, Zhou J, Mao Z Y. J. Mater. Chem. C, 2013, 1(37):5917-5924 doi: 10.1039/c3tc30897a
22. [22]
  Xia Z G, Miao S H, Chen M Y, et al. Inorg. Chem., 2015, 54(16):7684-7691 doi: 10.1021/acs.inorgchem.5b00455
23. [23]
  Wang J, Zhang H R, Liu Y L, et al. J. Mater. Chem. C, 2015, 3(37):9572-9579 doi: 10.1039/C5TC01849H
24. [24]
  Zhang Y, Gong W T, Yu J J, et al. RSC Adv., 2016, 6(37):30886-30894 doi: 10.1039/C6RA01862A
25. [25]
  LIU Yun, GAO Wei-Ping, SHI Xiao-Lei, et al. J. Shaanxi Univ. Sci. Technol., 2015, 33(5):40-45
26. [26]
  WANG Lin-Xiang. Acta Opt. Sin., 2016, 36(3):0316001(7 Pages)
1. [1]
  Yujia Luo , Yunpeng Qi , Huiping Xing , Yuhu Li . The Use of Viscosity Method for Predicting the Life Expectancy of Xuan Paper-based Heritage Objects. University Chemistry, 2024, 39(8): 290-294. doi: 10.3866/PKU.DXHX202401037
2. [2]
  Tong WANG , Xuefang ZHU , Qi GAO , Hongbo ZHANG , Chao REN , Lixia GE . Luminescence and thermal stability of Tb³⁺-Eu³⁺ doped glass-ceramics containing Na_8.12Y_1.293Si₆O₁₈ crystal phase. Chinese Journal of Inorganic Chemistry, 2025, 41(11): 2237-2250. doi: 10.11862/CJIC.20250137
3. [3]
  Qiang Zhou , Pingping Zhu , Wei Shao , Wanqun Hu , Xuan Lei , Haiyang Yang . Innovative Experimental Teaching Design for 3D Printing High-Strength Hydrogel Experiments. University Chemistry, 2024, 39(6): 264-270. doi: 10.3866/PKU.DXHX202310064
4. [4]
  Yanhui Zhong , Ran Wang , Zian Lin . Analysis of Halogenated Quinone Compounds in Environmental Water by Dispersive Solid-Phase Extraction with Liquid Chromatography-Triple Quadrupole Mass Spectrometry. University Chemistry, 2024, 39(11): 296-303. doi: 10.12461/PKU.DXHX202402017
5. [5]
  Ruixin XU , Hongtuo LI , Chen SHI , Yanhong YAN . Factors influencing the spectral properties of composite luminescent materials SrTiO₃: Eu³⁺/SrAl₂O₄: Eu²⁺, Dy³⁺. Chinese Journal of Inorganic Chemistry, 2025, 41(11): 2307-2316. doi: 10.11862/CJIC.20250055
6. [6]
  Xingyuan Lu , Yutao Yao , Junjing Gu , Peifeng Su . Energy Decomposition Analysis and Its Application in the Many-Body Effect of Water Clusters. University Chemistry, 2025, 40(3): 100-107. doi: 10.12461/PKU.DXHX202405074
7. [7]
  Cuiping HE , Zhuxuan LI , Yuqing SUN , Jie LIU , Shicheng XU , Zhanchao WU . Ca²⁺ doping induced crystal phase transition and spectral regulation of Ba₃P₄O₁₃: Eu²⁺ phosphor. Chinese Journal of Inorganic Chemistry, 2025, 41(11): 2299-2306. doi: 10.11862/CJIC.20250074
8. [8]
  Ruoxi Sun , Yiqian Xu , Shaoru Rong , Chunmiao Han , Hui Xu . The Enchanting Collision of Light and Time Magic: Exploring the Footprints of Long Afterglow Lifetime. University Chemistry, 2024, 39(5): 90-97. doi: 10.3866/PKU.DXHX202310001
9. [9]
  Zhiwen HU , Weixia DONG , Qifu BAO , Ping LI . Low-temperature synthesis of tetragonal BaTiO₃ for piezocatalysis. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 857-866. doi: 10.11862/CJIC.20230462
10. [10]
  Yanhui XUE , Shaofei CHAO , Man XU , Qiong WU , Fufa WU , Sufyan Javed Muhammad . Construction of high energy density hexagonal hole MXene aqueous supercapacitor by vacancy defect control strategy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1640-1652. doi: 10.11862/CJIC.20240183
11. [11]
  Zhuo Han , Danfeng Zhang , Haixian Wang , Guorui Zheng , Ming Liu , Yanbing He . Research Progress and Prospect on Electrolyte Additives for Interface Reconstruction of Long-Life Ni-Rich Lithium Batteries. Acta Physico-Chimica Sinica, 2024, 40(9): 2307034-0. doi: 10.3866/PKU.WHXB202307034
12. [12]
  Yan ZHAO , Jiaxu WANG , Zhonghu LI , Changli LIU , Xingsheng ZHAO , Hengwei ZHOU , Xiaokang JIANG . Gd³⁺-doped Sc₂W3O₁₂: Eu³⁺ red phosphor: Preparation and luminescence performance. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 461-468. doi: 10.11862/CJIC.20240316
13. [13]
  Ruonan Li , Shijie Liang , Yunhua Xu , Cuifen Zhang , Zheng Tang , Baiqiao Liu , Weiwei Li . Chlorine-Substituted Double-Cable Conjugated Polymers with Near-Infrared Absorption for Low Energy Loss Single-Component Organic Solar Cells. Acta Physico-Chimica Sinica, 2024, 40(8): 2307037-0. doi: 10.3866/PKU.WHXB202307037
14. [14]
  Lin Song , Dourong Wang , Biao Zhang . Innovative Experimental Design and Research on Preparing Flexible Perovskite Fluorescent Gels Using 3D Printing. University Chemistry, 2024, 39(7): 337-344. doi: 10.3866/PKU.DXHX202310107
15. [15]
  Han ZHANG , Jianfeng SUN , Jinsheng LIANG . Hydrothermal synthesis and luminescent properties of broadband near-infrared Na₃CrF₆ phosphor. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 349-356. doi: 10.11862/CJIC.20240098
16. [16]
  Lingbang Qiu , Jiangmin Jiang , Libo Wang , Lang Bai , Fei Zhou , Gaoyu Zhou , Quanchao Zhuang , Yanhua Cui . In Situ Electrochemical Impedance Spectroscopy Monitoring of the High-Temperature Double-Discharge Mechanism of Nb₁₂WO₃₃ Cathode Material for Long-Life Thermal Batteries. Acta Physico-Chimica Sinica, 2025, 41(5): 100040-0. doi: 10.1016/j.actphy.2024.100040
17. [17]
  Qing Xue , Shengyi Li , Yanan Zhao , Peng Sheng , Li Xu , Zhengxi Li , Bo Zhang , Hui Li , Bo Wang , Libin Yang , Yuliang Cao , Zhongxue Chen . Novel Alkaline Sodium-Ion Battery Capacitor Based on Active Carbon||Na_0.44MnO₂ towards Low Cost, High-Rate Capability and Long-Term Lifespan. Acta Physico-Chimica Sinica, 2024, 40(2): 2303041-0. doi: 10.3866/PKU.WHXB202303041
18. [18]
  Shan Zhao , Xu Liu , Haotian Guo , Zonglin Liu , Pengfei Wang , Jie Shu , Tingfeng Yi . Synergistic design of high-entropy P2/O3 biphasic cathodes for high-performance sodium-ion batteries. Acta Physico-Chimica Sinica, 2026, 42(1): 100129-0. doi: 10.1016/j.actphy.2025.100129
19. [19]
  Liuyun Chen , Wenju Wang , Tairong Lu , Xuan Luo , Xinling Xie , Kelin Huang , Shanli Qin , Tongming Su , Zuzeng Qin , Hongbing Ji . Soft template-induced deep pore structure of Cu/Al₂O₃ for promoting plasma-catalyzed CO₂ hydrogenation to DME. Acta Physico-Chimica Sinica, 2025, 41(6): 100054-0. doi: 10.1016/j.actphy.2025.100054
20. [20]
  Xuewei BA , Cheng CHENG , Huaikang ZHANG , Deqing ZHANG , Shuhua LI . Preparation and luminescent performance of Sr_1-xZrSi₂O₇∶xDy³⁺ phosphor with high thermal stability. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 357-364. doi: 10.11862/CJIC.20240096

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(899)
HTML views(85)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and Luminescence Properties of CaWO4:xEu3+, ySm3+, zLi+ Red Phosphors

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation and Luminescence Properties of CaWO₄:xEu³⁺, ySm³⁺, zLi⁺ Red Phosphors