Citation: DENG Qing-Feng, YU Liang-Min, LI Xia. Two Lanthanide Complexes with Maleichydrazide:Syntheses, Structures and Fluorescence Properties[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(9): 1561-1567. doi: 10.11862/CJIC.2017.210 shu

Two Lanthanide Complexes with Maleichydrazide:Syntheses, Structures and Fluorescence Properties

Key Laboratory of Marie Chemistry Theory and Technology, Ministry of Education, Ocean University of China, Qingdao, Shandong 266100, China

Corresponding author: LI Xia, xiali@ouc.edu.cn
Received Date: 24 February 2017
Revised Date: 31 July 2017

Figures(6)

Two lanthanide-organic frameworks[Dy₂(MH)₆]_n·0.5DMF (1) and[Eu₂(MH)₆]_n (2) (MH=maleichydrazide and DMF=N, N-dimethylformamide) have been synthesized and characterized by X-ray single-crystal diffraction and X-ray powder diffraction. Two complexes are both Triclinic P1 space group. Ln(Ⅲ)ions adopt same coordination environments, and seven-coordinated Ln(Ⅲ)atom form feature isostructural 3D structures, topological type:tsi. The luminescence properties of 1 and 2 were investigated. Under the excitation of 375 nm, the emission spectrum of complex 2 shows five peaks at 581, 593, 616, 652 and 705 nm, corresponding to ⁵D₀→⁷F_J (J=0~4) transitions of Eu³⁺. The emission spectrum of complex 1 shows a peak at 618 nm, which plausibly arises from π^*-π transition of ligands.CCDC: 1473814, 1; 1473816, 2.
- lanthanide complex,
- fluorescence,
- coordination,
- maleichydrazide
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沈阳化工大学材料科学与工程学院沈阳 110142

Two Lanthanide Complexes with Maleichydrazide:Syntheses, Structures and Fluorescence Properties

南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

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通讯作者: 陈斌, bchen63@163.com