Citation: YU Shuang-Lin, YU Xiao-Hua, LÜ Xiang, WANG Ying, FENG Pan, BIE Han-Bo, XIE Gang. Sn₆O₄(OH)₄ Coated on ZnO Surface:Preparation and Application in Zinc-Nickel Secondary Battery[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(9): 1573-1578. doi: 10.11862/CJIC.2017.209 shu

Sn₆O₄(OH)₄ Coated on ZnO Surface:Preparation and Application in Zinc-Nickel Secondary Battery

YU Shuang-Lin ¹ ,
YU Xiao-Hua ^1,, ,
LÜ Xiang ¹ ,
WANG Ying ¹ ,
FENG Pan ¹ ,
BIE Han-Bo ¹ ,
XIE Gang ^1,2

1.
Faculty of Metallurgical and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, China
2.
State Key Laboratory of Common Associated Non-ferrous Metal Resources Pressure Hydrometallurgy Technology, Kunming 650500, China

Corresponding author: YU Xiao-Hua, yxhyxh1978@aliyun.com
Received Date: 28 February 2017
Revised Date: 14 August 2017

Figures(6)

The hydrothermal-coprecipitation method was successfully used to prepare Sn₆O₄(OH)₄ coated on the surface of zinc oxide. The modified ZnO material was characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD) and energy dispersive spectrometer (EDS) analysis. The results show:Sn₆O₄(OH)₄ was coated on the surface of ZnO and the crystallinity was well at pH=12, and the coating composition is including Zn, Sn, O. The electrochemical performances of Sn₆O₄(OH)₄-coated ZnO was investigated by cyclic voltammetry (CV), electro-chemical impedance spectroscopy (EIS) and charge-discharge technology. Compared with pure ZnO, The CV curves and the electrochemical impedance spectroscopy show that Sn₆O₄(OH)₄-coated ZnO can improve the corrosion resistance and increase charge transfer resistance (R_ct), Sn₆O₄(OH)₄-coated ZnO electrode has best charge-discharge efficiency when the Sn₆O₄(OH)₄ content is 3%, and the capacity retention ratio of the coated ZnO is about 70% after over 40 cycles with the rate of 0.2C, which is much higher than that of the pure ZnO.
- zinc oxide,
- hydrothermal-coprecipitation method,
- Sn₆O₄(OH)₄ coated,
- electrochemical performance
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Sn₆O₄(OH)₄ Coated on ZnO Surface:Preparation and Application in Zinc-Nickel Secondary Battery