Citation: YANG Zhi-Sheng, KE Wei-Fang, WANG Yan-Xiang, HUANG Li-Qun, GUO Ping-Chun, ZHU Hua. Preparation and Characterization of Hybrid Perovskite (NH₃C₆H₁₂NH₃)CuCl₄[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(9): 1568-1572. doi: 10.11862/CJIC.2017.195 shu

Preparation and Characterization of Hybrid Perovskite (NH₃C₆H₁₂NH₃)CuCl₄

1.
Department of Materials Science and Engineering, Jingdezhen Ceramic Institute, Jingdezhen, Jiangxi 333403, China
2.
Department of Ceramic Art, Jingdezhen Ceramic Institute, Jingdezhen, Jiangxi 333403, China
3.
Department of Mechanical and Electrical Engineering, Jingdezhen Ceramic Institute, Jingdezhen, Jiangxi 333403, China

Corresponding author: YANG Zhi-Sheng, 85694626@qq.com
Received Date: 12 April 2017
Revised Date: 7 July 2017

Figures(6)

A novel organic-inorganic hybrid material containing diammonium cations, (NH₃C₆H₁₂NH₃)CuCl₄ with perovskite structure, was synthesized by low-temperature solution method and characterized by elemental analysis, FT-IR, XRD and UV-Vis absorption spectra techniques. The result shows that the UV-visible absorption peak of this material is located at 285 and 387 nm, with a layer spacing of 1.18 nm. The organic layer ⁺NH₃C₆H₁₂NH₃⁺ and two inorganic frameworks, CuCl₄^2-, are bound together by strong hydrogen bonds, so more orderly arrangement and good heat stability are obtained. The resistance of (NH₃C₆H₁₂NH₃)CuCl₄ is about 1.36×10⁵Ω·cm, three orders of magnitude less than hybrid perovskite that contain single ammonium cation, just because there is no weaker van der Waals force between two layers of organic molecules.
- organic-inorganic hybrid,
- perovskite,
- crystal structure,
- diammonium cations
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Preparation and Characterization of Hybrid Perovskite (NH₃C₆H₁₂NH₃)CuCl₄