Citation: DU Ceng-Ceng, FAN Jian-Zhong, LI Jin-Ping, WANG Duo-Zhi. Co(Ⅱ), Cu(Ⅱ)and Cd(Ⅱ)Complexes Based on 3-(2-Pyridyl)-1, 2, 4-triazole:Syntheses, Structures, and Fluorescent Properties[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(9): 1685-1696. doi: 10.11862/CJIC.2017.194 shu

Co(Ⅱ), Cu(Ⅱ)and Cd(Ⅱ)Complexes Based on 3-(2-Pyridyl)-1, 2, 4-triazole:Syntheses, Structures, and Fluorescent Properties

College of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046, China

Corresponding author: WANG Duo-Zhi, wangdz@xju.edu.cn
Received Date: 22 April 2017
Revised Date: 1 June 2017

Figures(10)

Five complexes[Co(HL)₂(H₂O)₂](NO₃)₂(1), [Cu₂(L)₂(NO₃)₂(H₂O)₄] (2), [Cu₂(L)₂(AcO)₂(H₂O)₂]·6H₂O (3), [Cu₂(L)₂(HL)₂(ClO₄)₂]·2CH₃CN (4) and[Cd₂(L)₂(HL)₂(NO₃)₂]·2H₂O (5) utilizing 3-(2-pyridyl)-1, 2, 4-triazole ligand(HL) as well as different metal salts have been synthesized and structurally characterized by single crystal X-ray diffraction, infrared spectroscopy (IR), elemental analysis, powder X-ray diffraction (PXRD) and thermogravimetric analysis (TGA). The structural analyses reveal that complex 1 has a mononuclear structure and forms a 2D supramolecular structure via hydrogen bonding interactions. Complexes 2~5 have dinuclear structures. Complexes 2 and 5 are arranged into 2D supramolecular structurs by the corresponding hydrogen bonding interactions, and complex 3 is also arranged into a 3D supramolecular structure through hydrogen bonding interactions. The coordination modes of HL ligand in the complexes were studied. Moreover, the fluorescent properties and fluorescence lifetimes of ligand HL, complexes 1 and 5 were investigated in the solid at room temperature.CCDC:1054520,1;1054521, 2; 1054522, 3;1054523, 4;1054524, 5
- complex,
- crystal structure,
- luminescent property
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