Citation: LI Fu-An, XU Fu, YANG Wei-Chun. Syntheses, Structures and Photoluminescent Properties of Two 3D Coordination Polymers Based on a Flexible and Angular Organic Aromatic Multi-carboxylate Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(9): 1631-1638. doi: 10.11862/CJIC.2017.190 shu

Syntheses, Structures and Photoluminescent Properties of Two 3D Coordination Polymers Based on a Flexible and Angular Organic Aromatic Multi-carboxylate Ligand

College of Chemistry and Environmental Engineering, Pingdingshan University, Pingdingshan, Henan 467000, China

Corresponding author: LI Fu-An, lifuanpds@163.com
Received Date: 14 March 2017
Revised Date: 26 May 2017

Figures(6)

Two coordination polymers with 3D supramolecular network, {[Zn(L)(bpa)_0.5(H₂O)₂]·2.25H₂O}_n (1) and {[Cd(L)(H₂O)]·2H₂O}_n (2) (H₃LCl=5-(4-hydroxypyridinium-1-ylmethyl) isophthalic acid chloride, bpa=1, 2-bis(4-pyridyl)ethane) were hydrothermally synthesized and structurally characterized by X-ray diffraction analyses and further characterized by infrared spectra (IR), elemental analyses, and thermogravimetric (TG) analyses. Compound 1 exhibits a ladder-like chain structure, and such chains are further united together to generate a 3D supramolecular structure through the hydrogen bonding interactions. Compound 2 possesses a 2D coordination network with a 1D channel that run parallel to the coordination layers. Meanwhile, their luminescent properties have also been investigated in detail.CCDC:908522,1;908526,2.
- 5-(4-hydroxypyridinium-1-ylmethyl) isophthalic acid chloride,
- 1, 2-bis (4-pyridyl) ethane,
- zinc,
- cadmium
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