Citation: MA De-Yun, LI Xiang, GUO Hai-Fu, MA Yan-Hua, LIN Wan-Chun, WEN Mei-Ling, CAI Li-Wen, ZHU Li-Feng. Metal Ions Controlled Assembly of Two Coordination Polymers:Structures and Luminescence Properties[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(7): 1266-1272. doi: 10.11862/CJIC.2017.162 shu

Metal Ions Controlled Assembly of Two Coordination Polymers:Structures and Luminescence Properties

School of Chemistry and Chemical Engineering, Zhaoqing University, Zhaoqing, Guangdong 526061, China

Corresponding author: MA De-Yun, mady@zqu.edu.cn
Received Date: 18 January 2017
Revised Date: 15 May 2017

Fund Project: 广东省自然科学基金 2015A0303104072017年大学生科技创新培育专项资金（“攀登”计划专项资金） pdjh2017b0551大学生创新训练计划项目（No.201610580008）、广东省自然科学基金（No.2015A030310407）、广东省普通高校特色创新项目（No.2015KTSCX156）、2017年大学生科技创新培育专项资金（“攀登”计划专项资金）（No.pdjh2017b0551）和广东高校优秀青年教师培训计划项目（No.YQ2015168）资助大学生创新训练计划项目 201610580008广东省普通高校特色创新项目 2015KTSCX156广东高校优秀青年教师培训计划项目 YQ2015168

Figures(8)

Two zinc/cadmium-based coordination polymers (CPs), [Zn (FDC)(DMF)₂]_n(1) and{(Me₂NH₂)₂[Cd₂(FDC)₃(H₂O)₂]·4H₂O}_n(2)(H₂FDC=2, 5-furandicarboxylic acid, DMF=N, N-dimethyl formamide) have been prepared based on 2, 5-furandicarboxylate under the same reaction conditions (130℃ and DMF) and were structurally characterized by elemental analysis, IR, TGA, powder X-ray diffraction and single-crystal X-ray diffraction.Complex 1 performs a 1D chain structure, where the chains are further connected into 2D layer structure by hydrogen bonds, whereas 2 shows 2D (4, 4) network and is unstable in air.The results of thermal analysis indicate that 1 is stable up to 300℃ after the DMF molecules are removed, but 2 is unstable after the aqua ligands, cations and solvent molecules are removed.Moreover, the luminescent properties of 1 and 2 were detected at room temperature under the excitations of 303 nm and 350 nm, respectively.Both of 1 and 2 emit the intensely blue characteristic luminescence at room temperature (λ_max=406 and 470 nm), with lifetimes of up to 76.2 and 138.1 ns, respectively.CCDC:1489352, 1; 1527106, 2.
- coordination polymers,
- crystal structure,
- 2, 5-furandicarboxylate,
- metal ions effect,
- luminescent 0 Introduction
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