Citation: ZHANG Mei-Na, ZHENG Xiao-Li, QU Xiang-Long, LI Xia, GAO Yuan. Syntheses, Crystal Structures and Fluorescence Sensing for Fe³⁺ of Transition Metal Complexes with 3, 4, 5, 6-Tetrafluorophthalic Acid and N-Donor Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(7): 1172-1180. doi: 10.11862/CJIC.2017.137 shu

Syntheses, Crystal Structures and Fluorescence Sensing for Fe³⁺ of Transition Metal Complexes with 3, 4, 5, 6-Tetrafluorophthalic Acid and N-Donor Ligands

Department of Chemistry, Capital Normal University, Beijing 100048, China

Corresponding author: LI Xia, xiali@mail.cnu.edu.cn
Received Date: 27 December 2016
Revised Date: 9 May 2017

Figures(7)

Three new complexes, {[M (TFPT)(DPP)]·H₂O}_n(M=Cd (1), Ni (2)), {[Cd (TFPT)(BTB)_0.5]·2H₂O}_n(3) were synthesized by using transition metal salts, 3, 4, 5, 6-tetrafluorophthalate (TFPT), 1, 3-di (4-pyridyl)-propane (DPP) and 1, 4-bis (1, 2, 4-triazol-1-yl) butane (BTB) by hydrothermal method.The crystal structures were determined by single crystal X-ray diffraction.Complexes 1 and 2 have similar one-dimensional chain structure.The configuration of center metal ion is distorted octahedral of[MO₄N₂].Complex 3 is two-dimensional structure.The configuration of center metal ion is distorted octahedral of[CdO₅N].Complexes 1 and 3 have ligand-based fluorescence emissions, which are corresponding to π^*-π transition of the ligand at 424 nm and 442 nm, respectively.Complex 2 has very weak fluorescence emission at 356 nm.It is interesting to note that different metal cations have different effects on fluorescence of complexes 1 and 3.They would be regarded as a sensor for Fe³⁺ ions in aqueous solutions via a fluorescence quenching mechanism.
- transition metal complexes,
- 3, 4, 5, 6-tetrafluorophthalic acid,
- crystal structure,
- fluorescence
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Syntheses, Crystal Structures and Fluorescence Sensing for Fe3+ of Transition Metal Complexes with 3, 4, 5, 6-Tetrafluorophthalic Acid and N-Donor Ligands

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通讯作者: 陈斌, bchen63@163.com

Syntheses, Crystal Structures and Fluorescence Sensing for Fe³⁺ of Transition Metal Complexes with 3, 4, 5, 6-Tetrafluorophthalic Acid and N-Donor Ligands