Citation: YANG Qing-Xiang, REN Shuang-Shuang, ZHAO Qian-Qian, CHEN Zhi-Jun. Synthesis of Magnetic UiO-66 Composites for the Adsorption of Nitro Phenol Organic Molecules in Water[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(5): 843-852. doi: 10.11862/CJIC.2017.108 shu

Synthesis of Magnetic UiO-66 Composites for the Adsorption of Nitro Phenol Organic Molecules in Water

Mechanical and Electrical Engineering Institute, ZhengzhouUniversity of Light Industry, Zhengzhou 450002, China

Corresponding author: CHEN Zhi-Jun, chenzj@zzuli.edu.cn
Received Date: 5 December 2016
Revised Date: 28 March 2017

Figures(15)

Magnetic porous composites of Fe₃O₄@SiO₂-PSS@UiO-66 were prepared by hydrothermal method. The microstructure and morphology was characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), scanning electron microscope (SEM), infrared (IR), thermogravimetric analysis (TG), vibrating sample magnetometer (VSM) and N₂ adsorption-desorption. The results show that magnetic UiO-66 composites are a core shell structure with spherical Fe₃O₄ as core and cubic MOF as shell. The composites show good superparamagnetism. The adsorption performance of 2-nitroresorcinolon Fe₃O₄@SiO₂-PSS@UiO-66 was further studied. And the effects of contact time, adsorbent dose and initial 2-nitroresorcinol concentration on the adsorption process were explored. The results show that the maximum adsorption capacity is 161.36 mg·g^-1 in following experimental conditions:contact time is 120 min, adsorbent dose is 5 mg, initial 2-nitroresorcinol concentration is 400 mg·L^-1. In addition, the higher adsorption efficiency of 2-nitroresorcinol on magnetic UiO-66 composites may be due to the electrostatic interaction and π-π interaction of phenyl ring between UiO-66 and 2-nitroresorcinol.
- magnetic UiO-66 composites,
- 2-nitroresorcinol,
- adsorption performance,
- electrostatic attraction,
- π-π interaction
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