Citation: WANG Ping-Ping, CHEN Dan-Ping, WANG Shu-Hua, CHEN Chao. Chiral Postsynthetic Modification of Cr-MIL-101-NH₂[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(5): 817-822. doi: 10.11862/CJIC.2017.095 shu

Chiral Postsynthetic Modification of Cr-MIL-101-NH₂

WANG Ping-Ping ^1,2,*,, ,
CHEN Dan-Ping ² ,
WANG Shu-Hua ² ,
CHEN Chao ^2,*,,

1.
Zunyi Medical College, Zunyi, Guizhou 563000, China
2.
Institute of Applied Chemistry, Nanchang University, Nanchang 330031, China

Corresponding author: WANG Ping-Ping, chouchongbaobao@163.com CHEN Chao, chaochen@ncu.edu.cn
Received Date: 28 December 2016
Revised Date: 22 March 2017

Figures(10)

By postsynthetic modification method (PSM), chiral metal-organic frameworks (MOFs) were designed and synthesized. The L-proline derivative (Boc-L-ProCl) was anchored on the pore of Cr-MIL-101-NH₂ by PSM method to gain a chiral MOFs (Cr-MIL-101-PaB₂). ¹H NMR spectra confirmed the yield up to 64% by twice process of PSM, and solid circular dichroism (CD) result showed that Cr-MIL-101-PaB₂ was a chiral compound. Their structures were characterized by infrared spectroscopy (IR), nitrogen desorption-adsorption, thermogravimetry (TGA), powder X-ray diffraction (PXRD). The experimental results confirmed that synthesized chiral MOFs by PSM method for the needed purpose can avoid the self-assembly uncertainty of MOFs.
- MOFs,
- PSM,
- Cr-MIL-101-NH₂,
- chiral
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1.
沈阳化工大学材料科学与工程学院沈阳 110142

Chiral Postsynthetic Modification of Cr-MIL-101-NH2

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通讯作者: 陈斌, bchen63@163.com

Chiral Postsynthetic Modification of Cr-MIL-101-NH₂