Citation: DONG Yi-Tian, TU Bo, XU Hong, HUANG Ya-Li, ZHANG Qi-Long, HU Zong-Chao, ZHU Bi-Xue. Syntheses and Crystal Structures of Cd(Ⅱ), Zn(Ⅱ) and Hg(Ⅱ) Complexes Based on Bis (pyridylurea) Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(4): 651-658. doi: 10.11862/CJIC.2017.088 shu

Syntheses and Crystal Structures of Cd(Ⅱ), Zn(Ⅱ) and Hg(Ⅱ) Complexes Based on Bis (pyridylurea) Ligand

DONG Yi-Tian ¹ ,
TU Bo ² ,
XU Hong ² ,
HUANG Ya-Li ² ,
ZHANG Qi-Long ^2,*,, ,
HU Zong-Chao ^1,3,*,, ,
ZHU Bi-Xue ¹

1.
College of Chemistry and Chemical Engineering, Guizhou University, Guiyang 550025, China
2.
Department of Chemistry, Guizhou Medical University, Guizhou, Guiyang 550025, China
3.
Guizhou Industry Polytechnic College, Guizhou, Guiyang 550008, China

Corresponding author: ZHANG Qi-Long, gzuqlzhang@126.com HU Zong-Chao, zchu@gzu.edu.cn
Received Date: 1 January 2017
Revised Date: 11 March 2017

Figures(14)

The urea-based pyridyl ligand L was synthesized from the reaction of 1, 3-Benzenediamine with 3-isocyanatopyridine in toluene heating to reflux. CdSO₄·8H₂O, ZnI₂, HgI₂ and HgCl₂ reacted with L to give the complexes {[Cd (L)(SO₄)(H₂O)₃]·H₂O}_n (1), {[Zn (L) I₂]·2C₂H₅OH}_n (2), {[Hg (L) I₂]·2C₂H₅OH}_n (3), [Hg (L) Cl₂]·H₂O (4), which were characterized by elemental analysis, FT-IR, single crystal X-ray diffraction and powder X-ray diffraction. Complex 1 forms a one-dimensional helix chain structure, complex 2 and complex 3 show a one-dimensional zigzag chain structure and complex 4 shows a 32-membered ring.
- bis (pyridylurea) ligand,
- Cd(Ⅱ) complex,
- Zn(Ⅱ) complex,
- Hg(Ⅱ) complex,
- crystal structure
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