Citation: ZHANG Ying-Jie, LIU Jia-Ming, ZHAO Jin-Bao, HUANG Ling, LI Xue. Effect of Loading Content of Silver on Lithium Storage for TiO₂ Net-Work Flexible Film Electrode[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(5): 809-816. doi: 10.11862/CJIC.2017.087 shu

Effect of Loading Content of Silver on Lithium Storage for TiO₂ Net-Work Flexible Film Electrode

1.
Engineering Laboratory of Advanced Battery and Materials of Yunnan Province, Faculty of Metallurgical and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, China
2.
State Key Laboratory of Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, Fujian 361005, China

Corresponding author: LI Xue, 4386160734@qq.com
Received Date: 24 October 2016
Revised Date: 13 March 2017

Figures(7)

A series of silver-modified TiO₂ flexible film electrodes with hierarchical 3D nano-network structure are facilely synthesized using hydrothermal method followed via the traditional silver mirror reaction. Successful deposition of Ag nanoparticles on to the TiO₂ nanowires surface is confirmed by inductively coupled plasma (ICP) technique, X-ray diffraction (XRD), scanning electron microscope (SEM) with energy-dispersive X-ray analysis (EDX) and transmission electron microscopy (TEM). The electrochemical properties of the Ag@TiO₂ nanowires were researched in this work. Our results show that the Ag@TiO₂ nanowires with 4.0%(w/w) silver exhibits a better rate performance and more excellent reversibility than pristine one. At different current densities of 50, 100, 200, 400, 800 and 1 200 mA·g^-1, the discharge capacities of the Ag@TiO₂ electrodes are 261.4, 253.7, 239.5, 216.5, 193.1 and 185.1 mAh·g^-1, respectively. After 80 cycles at 200 mA·g^-1, its discharge capacity retention is 99.8% indicating Ag@TiO₂ electrodes are potentially useful for LIBs.
- lithium ion battery,
- flexible film electrodes,
- Ti-based materials,
- silver mirror reaction
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Effect of Loading Content of Silver on Lithium Storage for TiO2 Net-Work Flexible Film Electrode

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通讯作者: 陈斌, bchen63@163.com

Effect of Loading Content of Silver on Lithium Storage for TiO₂ Net-Work Flexible Film Electrode