Citation: WANG Ruo, JIANG Guang-Qi. Two Tetrapodal Schiff Bases Acting as Colorimetric Sensors for Iron in Environmental Water Samples[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(5): 881-889. doi: 10.11862/CJIC.2017.079 shu

Two Tetrapodal Schiff Bases Acting as Colorimetric Sensors for Iron in Environmental Water Samples

WANG Ruo ² ,
JIANG Guang-Qi ^1,2,*,,

1.
State Key Laboratory Breeding Base of Green Pesticide and Agricultural Bioengineering, Key Laboratory of Green Pesticide and Agricultural Bioengineering, Ministry of Education, Guizhou University, Guiyang 550025, China
2.
College of Chemistry and Chemical Engineering, Guizhou University, Guiyang 550025, China

Corresponding author: JIANG Guang-Qi, gqjiang@163.com
Received Date: 2 November 2016
Revised Date: 4 February 2017

Figures(8)

Two colorimetric sensors, derived from pentaerythrityltetramine and salicylaldehyde (1) or o-vanillin (2), had been synthesized. Both sensors showed selective colorimetric sensing ability for Fe (Ⅱ) and Fe (Ⅲ) by changing color from light yellow to either orange or purple when immersed in water samples. The sensors coordinated to Fe (Ⅲ) with 1:1 stoichiometry, as has been confirmed from the results of LC-MS spectrometry and UV-Vis spectrum titration. The detection limits of sensors 1 (0.19 μmol·L^-1) and 2 (0.21 μmol·L^-1) are lower than the WHO guideline (5 μmol·L^-1) in drinking water.
- Schiff base,
- colorimetric sensor,
- iron
1. [1]
  Callan J F, Silva A P, Magri D C. Tetrahedron, 2005, 61:8551-8588 doi: 10.1016/j.tet.2005.05.043
2. [2]
  Sen S, Sarkar S, Chattopadhyay B, et al. Analyst, 2012, 137:3335-3342 doi: 10.1039/c2an35258c
3. [3]
  Zhu J, Yuan H, Chan W, et al. Org. Biomol. Chem., 2010, 8:3957-3964 doi: 10.1039/c004871b
4. [4]
  Valeur B, Leray I. Chem. Rev., 2000, 205:3-40
5. [5]
  Shellaiah M, Wu Y H, Lin H C. Analyst, 2013, 138:2931-2942 doi: 10.1039/c3an36840h
6. [6]
  Lee D Y, Singh N, Jang D O, et al. Tetrahedron Lett., 2010, 51:1103-1106 doi: 10.1016/j.tetlet.2009.12.085
7. [7]
  H Kim, Na Y J, Song E J, et al. RSC Adv., 2014, 4:22463-22469 doi: 10.1039/c4ra02776k
8. [8]
  Berthon G. Handbook of Metal-Ligand Interactions in Biolo-gical Fluids: Bioinorganic Medicine: Vol. 1. New York: Dekker, 1995.
9. [9]
  Bertini I, Gray H B, Lippard S J, et al. Bioinorganic Chem-istry. Mill Valley:University Science Book, 1994.
10. [10]
  Yang Z, Yan C, Chen Y, et al. Dalton Trans., 2011, 40:2173-2176 doi: 10.1039/C0DT01053G
11. [11]
  Kim K B, Kim H, Song E J, et al. Dalton Trans., 2013, 42:16569-16577 doi: 10.1039/c3dt51916c
12. [12]
  Crichton R R, Wilmet S, Legssyer R, et al. Inorg. Biochem., 2002, 91:9-18 doi: 10.1016/S0162-0134(02)00461-0
13. [13]
  Philpott C C. J. Biol. Chem., 2012, 287:13518-13523 doi: 10.1074/jbc.R111.326876
14. [14]
  Nomngongo P N, Ngila J C. Spectrochim. Acta B, 2014, 98:54-59 doi: 10.1016/j.sab.2014.06.001
15. [15]
  Caldas L, Brum D M, Paula C. Talanta, 2013, 110:21-27 doi: 10.1016/j.talanta.2013.03.017
16. [16]
  Lai T T, Zheng E H, Chen L X. Nanoscale, 2013, 5:8015-8021 doi: 10.1039/c3nr02014b
17. [17]
  Kaya E N, Yuksel F, Ozpinar G A, et al. Sens. Actuators B, 2014, 194:377-388 doi: 10.1016/j.snb.2013.12.044
18. [18]
  Oh J W, Kim T H, Yoo S W. Sens. Actuators B, 2013, 177:813-817 doi: 10.1016/j.snb.2012.11.066
19. [19]
  Potts L W. Quantitative Analysis. New York:Theory and Practice, 1987:656
20. [20]
  Arthur I V. Textbook of Macro and Semimicro Qualitative Inorganic Analysis. New York:Longman, 1979:605
21. [21]
  Harvey D. Modern Analytical Chemistry. New York:Wiley, 2000:816
22. [22]
  Zhang Z Y, Lu S Z, Sha C M, et al. Sens. Actuators B, 2015, 208:258-266 doi: 10.1016/j.snb.2014.10.136
23. [23]
  Kozak J, Jodlowska N, Kozak M, et al. Anal. Chim. Acta, 2011, 702:213-217 doi: 10.1016/j.aca.2011.06.053
24. [24]
  You G R, Park G J, Lee S A. Sens. Actuators B, 2015, 215:188-195 doi: 10.1016/j.snb.2015.03.064
25. [25]
  Li P, Zhao Y, Yao L, et al. Sens. Actuators B, 2014, 191:332-336 doi: 10.1016/j.snb.2013.09.051
26. [26]
  Li S H, Li Y C, Cao J. et al. Anal. Chem., 2014, 86:10201-10207 doi: 10.1021/ac503183y
27. [27]
  Nandre J, Patil S, Patil V, et al. Biosens. Bioelectron., 2014, 61:612-617 doi: 10.1016/j.bios.2014.06.017
28. [28]
  Goel A, Umar S, Nag P, et al. Chem. Commun., 2015, 51:5001-5004
29. [29]
  Chen Y J, Yang S C, Tsai C C, et al. Chem. Asian J., 2015, 10:1025-1034 doi: 10.1002/asia.v10.4
30. [30]
  Chereddy N R, Nagaraju P, Raju M, et al. Biosens. Bioelec-tron., 2015, 68:749-756 doi: 10.1016/j.bios.2015.01.074
31. [31]
  Ju J, Chen W. Biosens. Bioelectron., 2014, 58:219-225 doi: 10.1016/j.bios.2014.02.061
32. [32]
  Yang L, Yang W, Xu D M, et al. Dyes Pigm., 2013, 97:168-174 doi: 10.1016/j.dyepig.2012.12.016
33. [33]
  Wang J H, Zhang D, Liu Y Q, et al. Sens. Actuators B, 2014, 191:344-350 doi: 10.1016/j.snb.2013.10.018
34. [34]
  Wang C C, Zhang D, Huang X Y, et al. Talanta, 2014, 128:69-74 doi: 10.1016/j.talanta.2014.03.073
35. [35]
  Wang M, Wang J G, Xue W J. Dyes Pigm., 2013, 97:475-480 doi: 10.1016/j.dyepig.2013.02.005
36. [36]
  Jiang G Q, Cai J, Zhang Y Q, et al. J. Struct. Chem., 2012, 31:385-388
37. [37]
  Jiang G Q, Cai J, Zhang Y Q, et al. Acta Crystallogr. Sect. E, 2008, E64:o1455
38. [38]
  Meier M, Schubert U S. Chem. Commun., 2005, 36:4610-4612
39. [39]
  Choi Y W, Park G J, Na Y J, et al. Sens. Actuators B, 2014, 194:343-352 doi: 10.1016/j.snb.2013.12.114
40. [40]
  Job P. Ann. Chim., 1928, 9:113-203
41. [41]
  Kim H, Kim K B, Song E J, et al. Chem. Comm., 2013, 36:72-76
42. [42]
  Wang Z H, Qin Y X, Wang C, et al. Appl. Surf. Sci., 2012, 258:2017-2021 doi: 10.1016/j.apsusc.2011.05.005
43. [43]
  Dong L, Wu C, Zeng X. Sens. Actuators B, 2010, 145:433-437 doi: 10.1016/j.snb.2009.12.057
44. [44]
  Zhou Y M, Zhang J L, Zhou H. Spectrochim. Acta Part A, 2013, 106:68-72 doi: 10.1016/j.saa.2012.12.084
1. [1]
  Maitri Bhattacharjee , Rekha Boruah Smriti , R. N. Dutta Purkayastha , Waldemar Maniukiewicz , Shubhamoy Chowdhury , Debasish Maiti , Tamanna Akhtar . Synthesis, structural characterization, bio-activity, and density functional theory calculation on Cu(Ⅱ) complexes with hydrazone-based Schiff base ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1409-1422. doi: 10.11862/CJIC.20240007
2. [2]
  Jinlong YAN , Weina WU , Yuan WANG . A simple Schiff base probe for the fluorescent turn-on detection of hypochlorite and its biological imaging application. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1653-1660. doi: 10.11862/CJIC.20240154
3. [3]
  Tao Yu , Vadim A. Soloshonok , Zhekai Xiao , Hong Liu , Jiang Wang . Probing the dynamic thermodynamic resolution and biological activity of Cu(Ⅱ) and Pd(Ⅱ) complexes with Schiff base ligand derived from proline. Chinese Chemical Letters, 2024, 35(4): 108901-. doi: 10.1016/j.cclet.2023.108901
4. [4]
  Xiaofen GUAN , Yating LIU , Jia LI , Yiwen HU , Haiyuan DING , Yuanjing SHI , Zhiqiang WANG , Wenmin WANG . Synthesis, crystal structure, and DNA-binding of binuclear lanthanide complexes based on a multidentate Schiff base ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2486-2496. doi: 10.11862/CJIC.20240122
5. [5]
  Zhongsen Wang , Lijun Qiu , Yunhua Huang , Meng Zhang , Xi Cai , Fanyu Wang , Yang Lin , Yanbiao Shi , Xiao Liu . Alcohothermal synthesis of sulfidated zero-valent iron for enhanced Cr(Ⅵ) removal. Chinese Chemical Letters, 2024, 35(7): 109195-. doi: 10.1016/j.cclet.2023.109195
6. [6]
  Jiangshan Xu , Weifei Zhang , Zhengwen Cai , Yong Li , Long Bai , Shaojingya Gao , Qiang Sun , Yunfeng Lin . Tetrahedron DNA nanostructure/iron-based nanomaterials for combined tumor therapy. Chinese Chemical Letters, 2024, 35(11): 109620-. doi: 10.1016/j.cclet.2024.109620
7. [7]
  Xianzheng Zhang , Yana Chen , Zhiyong Ye , Huilin Hu , Ling Lei , Feng You , Junlong Yao , Huan Yang , Xueliang Jiang . Magnetic field-assisted microbial corrosion construction iron sulfides incorporated nickel-iron hydroxide towards efficient oxygen evolution. Chinese Journal of Structural Chemistry, 2024, 43(1): 100200-100200. doi: 10.1016/j.cjsc.2023.100200
8. [8]
  Xing Tian , Di Wu , Wanheng Wei , Guifu Dai , Zhanxian Li , Benhua Wang , Mingming Yu . A lipid droplets-targetable fluorescent probe for polarity detection in cells of iron death, inflammation and fatty liver tissue. Chinese Chemical Letters, 2024, 35(6): 108912-. doi: 10.1016/j.cclet.2023.108912
9. [9]
  Mengjun Zhao , Yuhao Guo , Na Li , Tingjiang Yan . Deciphering the structural evolution and real active ingredients of iron oxides in photocatalytic CO2 hydrogenation. Chinese Journal of Structural Chemistry, 2024, 43(8): 100348-100348. doi: 10.1016/j.cjsc.2024.100348
10. [10]
  Yanan Zhou , Li Sheng , Lanlan Chen , Wenhua Zhang , Jinlong Yang . Axial coordinated iron-nitrogen-carbon as efficient electrocatalysts for hydrogen evolution and oxygen redox reactions. Chinese Chemical Letters, 2025, 36(1): 109588-. doi: 10.1016/j.cclet.2024.109588
11. [11]
  Yunlong Li , Xinyu Zhang , Shuang Liu , Chunsheng Li , Qiang Wang , Jin Ye , Yong Lu , Jiating Xu . Engineered iron-based metal-organic frameworks nanoplatforms for cancer theranostics: A mini review. Chinese Chemical Letters, 2025, 36(2): 110501-. doi: 10.1016/j.cclet.2024.110501
12. [12]
  Cheng-Shuang Wang , Bing-Yu Zhou , Yi-Feng Wang , Cheng Yuan , Bo-Han Kou , Wei-Wei Zhao , Jing-Juan Xu . Bifunctional iron-porphyrin metal-organic frameworks for organic photoelectrochemical transistor gating and biosensing. Chinese Chemical Letters, 2025, 36(3): 110080-. doi: 10.1016/j.cclet.2024.110080
13. [13]
  Zhenfei Tang , Yunwu Zhang , Zhiyuan Yang , Haifeng Yuan , Tong Wu , Yue Li , Guixiang Zhang , Xingzhi Wang , Bin Chang , Dehui Sun , Hong Liu , Lili Zhao , Weijia Zhou . Iron-doping regulated light absorption and active sites in LiTaO₃ single crystal for photocatalytic nitrogen reduction. Chinese Chemical Letters, 2025, 36(3): 110107-. doi: 10.1016/j.cclet.2024.110107
14. [14]
  Zhen Zhang , Xue-ling Chen , Xiu-Mei Xie , Tian-Yu Gao , Jing Qin , Jun-Jie Li , Chao Feng , Da-Gang Yu . Iron-promoted carbonylation–rearrangement of α-aminoaryl-tethered alkylidenecyclopropanes with CO₂: Facile synthesis of quinolinofurans. Chinese Chemical Letters, 2025, 36(4): 110056-. doi: 10.1016/j.cclet.2024.110056
15. [15]
  Ting Pan , Dinghu Zhang , Guomei You , Xiaoxia Wu , Chenguang Zhang , Xinyu Miao , Wenzhi Ren , Yiwei He , Lulu He , Yuanchuan Gong , Jie Lin , Aiguo Wu , Guoliang Shao . PD-L1 targeted iron oxide SERS bioprobe for accurately detecting circulating tumor cells and delineating tumor boundary. Chinese Chemical Letters, 2025, 36(1): 109857-. doi: 10.1016/j.cclet.2024.109857
16. [16]
  Xinyu Guo , Chang Li , Wenjun Deng , Yi Zhou , Yan Chen , Yushuang Xu , Rui Li . Phase engineering and heteroatom incorporation enable defect-rich MoS₂ for long life aqueous iron-ion batteries. Chinese Chemical Letters, 2025, 36(3): 109715-. doi: 10.1016/j.cclet.2024.109715
17. [17]
  Haitao Yin , Liang Meng , Li Li , Jiamu Xiao , Longrui Liang , Nannan Huang , Yansong Shi , Angang Zhao , Jingwen Hou . Polydopamine-modified biochar supported polylactic acid and zero-valent iron affects the functional microbial community structure for 1,1,1-trichloroethane removal in simulated groundwater. Chinese Chemical Letters, 2025, 36(1): 110313-. doi: 10.1016/j.cclet.2024.110313
18. [18]
  Xueling Yu , Lixing Fu , Tong Wang , Zhixin Liu , Na Niu , Ligang Chen . Multivariate chemical analysis: From sensors to sensor arrays. Chinese Chemical Letters, 2024, 35(7): 109167-. doi: 10.1016/j.cclet.2023.109167
19. [19]
  Guorong Li , Yijing Wu , Chao Zhong , Yixin Yang , Zian Lin . Predesigned covalent organic framework with sulfur coordination: Anchoring Au nanoparticles for sensitive colorimetric detection of Hg(Ⅱ). Chinese Chemical Letters, 2024, 35(5): 108904-. doi: 10.1016/j.cclet.2023.108904
20. [20]
  Jia Chen , Yun Liu , Zerong Long , Yan Li , Hongdeng Qiu . Colorimetric detection of α-glucosidase activity using Ni-CeO₂ nanorods and its application to potential natural inhibitor screening. Chinese Chemical Letters, 2024, 35(9): 109463-. doi: 10.1016/j.cclet.2023.109463

Get Citation

PDF

XML

Metrics

PDF Downloads(7)
Abstract views(1214)
HTML views(116)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142