Citation: HAN Wang-Kang, TIAN Lei, XU Zong-Li, ZHU Wei, LI Zhi-Hua, LI Tao, GU Zhi-Guo, LI Zai-Jun. Self-Sorting of Binuclear Schiff-Base Complexes under Solvent-Free Grinding Conditions[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(4): 550-559. doi: 10.11862/CJIC.2017.069 shu

Self-Sorting of Binuclear Schiff-Base Complexes under Solvent-Free Grinding Conditions

HAN Wang-Kang ¹ ,
TIAN Lei ¹ ,
XU Zong-Li ¹ ,
ZHU Wei ¹ ,
LI Zhi-Hua ¹ ,
LI Tao ¹ ,
GU Zhi-Guo ^1,2,*,, ,
LI Zai-Jun ^1,2

1.
School of Chemistry and Material Engineering, Jiangnan University, Wuxi, Jiangsu 214122, China
2.
The Key Laboratory of Food Colloids and Biotechnology, Wuxi, Jiangsu 214122, China

Corresponding author: GU Zhi-Guo, zhiguogu@jiangnan.edu.cn
Received Date: 10 November 2016
Revised Date: 18 January 2017

Figures(5)

Three binuclear iron (Ⅱ) imidazole Schiff-base complexes were constructed by one-pot multicomponent assembly of di (imidazole aldehyde)(A~C), 2-aminoethyl (ethyl) amine (D) and Fe (OTf)₂ under solvent-free grinding conditions. X-ray crystallography revealed that the three complexes crystallized in different space groups of Cmca for 1, P2₁/c for 2~3. And the molecular structures of 1~3 all display Fe₂L₂ arrangement. In complexes 1~3, two ligand strands wrap around two Fe²⁺ ions and the Fe²⁺ ions are coordinated to chelating moieties from two imidazole nitrogen atoms and four amine nitrogen atoms, resulting in the pseudo octahedral FeN₆ coordination geometry. Taking advantage of the facile approach above, we then investigated the discrimination abilities of the multicomponent assembly process under the solvent-free condition when different components were mixed together (a mixture of D, two kinds of di (imidazole aldehyde) of A~C and Fe (OTf)₂). In this assemble system, combinations[D+A+B+Fe²⁺] or[D+A+C+Fe²⁺] adopt narcissistic self-sorting with only two species, while social self-sorting took place in the combination[D+B+C+Fe²⁺] forming the single heteromer 4, which was composed of two different ligands and exhibited Fe₂LL' arrangement. The structure of 4 was further verified by the X-ray analysis by preparing the single crystal of the heteromer 4. To compare the efficiency of solvent-free grinding solid self-sorting against the solution self-sorting, the conventional solution-based self-sorting reactions were also performed using the same starting materials with equal amount. In consequence of the complexity of ¹H NMR peaks of mixture, the selectivity is poor in solution. Overall, compared with self-sorting in solution, the solvent-free grinding self-sorting is more efficient due to the certain restrictions of molecular movement.
- self-sorting,
- solvent-free grinding,
- binuclear iron (Ⅱ) complexes,
- Schiff-base ligands
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