Citation: YANG Yong-Chao, GAI Li-Zhi, ZHANG Dan, YAN Jing, ZHAO Hao-Li-Bao, SHEN Zhen. Synthesis and Spectroscopic Properties of Bithiophene-Fused BODIPY[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(4): 601-606. doi: 10.11862/CJIC.2017.066 shu

Synthesis and Spectroscopic Properties of Bithiophene-Fused BODIPY

YANG Yong-Chao ^1,2 ,
GAI Li-Zhi ² ,
ZHANG Dan ¹ ,
YAN Jing ¹ ,
ZHAO Hao-Li-Bao ¹ ,
SHEN Zhen ^2,*,,

1.
Tianjin Entry-Exit Inspection and Quarantine Bureau, Tianjin 300308, China
2.
School of Chemistry & Chemical Engineering, Nanjing University, Nanjing 210023, China

Corresponding author: SHEN Zhen, zshen@nju.edu.cn
Received Date: 27 November 2016
Revised Date: 15 February 2017

Figures(5)

A bithiophene-fused BODIPY (SY) dye is synthesized via acid catalyzed condensation of thiophene substituted thienopyrrole and 4-N, N-dimethylaminobenzaldehyde, followed by treatment with boron trifluoride diethyl ether. The structure of SY has been characterized by ¹H NMR, mass and elemental analysis. The absorption and emission bands of SY are centered at 654 nm and 689 nm in CH₂Cl₂, respectively. Fluorometric titration experiment shows that the fluorescence intensity is enhanced upon protonation of the electron donating N, N-dimethylamino group, suggesting that SY can be used as a NIR fluorescence probe for pH value.
- BODIPY,
- bithiophene,
- pH value,
- fluorescence probe
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