Citation: XU Xi-Hua, LOU Jia-Wei, XIE Xing-Xing, FEI Zhao-Yang, LIU Qing, CHEN Xian, TANG Ji-Hai, CUI Mi-Fen, QIAO Xu. Superfine CeO₂ Embedded in a Porous ZrO₂ Matrix for Catalytic HCl Oxidation[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(3): 421-428. doi: 10.11862/CJIC.2017.047 shu

Superfine CeO₂ Embedded in a Porous ZrO₂ Matrix for Catalytic HCl Oxidation

XU Xi-Hua ^1,2 ,
LOU Jia-Wei ^1,2 ,
XIE Xing-Xing ^1,2 ,
FEI Zhao-Yang ^1,2,*,, ,
LIU Qing ^1,2 ,
CHEN Xian ² ,
TANG Ji-Hai ² ,
CUI Mi-Fen ² ,
QIAO Xu ^1,2,*,,

1.
State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing Tech University, Nanjing 210009, China
2.
College of Chemical Engineering, Nanjing Tech University, Nanjing 210009, China

Corresponding author: FEI Zhao-Yang, zhaoyangfei@njtech.edu.cn QIAO Xu, qct@njtech.edu.cn
Received Date: 29 August 2016
Revised Date: 20 December 2016

Figures(7)

Ce-Zr composite oxide catalysts were prepared by different methods for catalytic HCl oxidation. The nano-sized CeO₂ particles embedded in the amorphous ZrO₂ matrix fabricated by spontaneous deposition strategy. A significant "size effect" of CeO₂ nanoparticles leads to considerably high concentration of Ce³⁺ and oxygen vacancy sites, which makes the catalyst have excellent low-temperature oxidation reduction performance and oxygen storage capacity. Catalytic performance tests indicate that the CeO₂@ZrO₂ catalyst shows superior activity (1.90 g_Cl₂·g_cat^-1·h^-1) and good durability. The isolation of CeO₂ nanoparticles by the amorphous ZrO₂ is a key factor of durability of the catalyst.
- catalytic oxidation,
- CeO₂,
- chlorine recycle,
- oxygen vacancy,
- size effect
1. [1]
  Pérez-Ramírez J, Mondelli C, Schmidt T, et al. Energy Environ. Sci., 2011, 4(12):4786-4799 doi: 10.1039/c1ee02190g
2. [2]
  Over H, Kim Y D, Seitsonen A P, et al. Science, 2000, 287(5457):1474-1476 doi: 10.1126/science.287.5457.1474
3. [3]
  Deacon H. Manufacture of chlorine. US Patent, 85370. 1868-12-16.
4. [4]
  Engel W F, Freddy W. US Patent, 3210158.1965-10-5.
5. [5]
  Seki K. Catal. Surv. Asia, 2010, 14(14):168-175
6. [6]
  Seitsonen A P, Over H. J. Phys. Chem. C, 2010, 114(51): 22624-22629 doi: 10.1021/jp108603a
7. [7]
  Zweidinger S, Crihan D, Knapp M, et al. Chem. Eng. Sci., 2001, 56(7):2305-2313 doi: 10.1016/S0009-2509(00)00439-5
8. [8]
  Mondelli C, Amrute A P, Krumeich F, et al. ChemCatChem., 2011, 3(4):657-660 doi: 10.1002/cctc.201000424
9. [9]
  Ricken M, Nölting J, Riess I, et al. J. Solid. State. Chem., 1984, 54(54):89-99
10. [10]
  Li H, Wu C Y, Li L, et al. Fuel, 2013, 113(6):726-732
11. [11]
  CAO Hong-Yan, WANG Jian-Li, YAN Sheng-Hui, et al. Acta Phys.-Chim. Sin., 2012, 28(8):1936-1942
12. [12]
  Amrute A P, Mondelli C, Moser M, et al. J. Catal., 2012, 286(4):287-297
13. [13]
  Crihan D, Knapp M, Zweidinger S, et al. Angew. Chem. Int. Ed., 2008, 47(11):2131-2134 doi: 10.1002/(ISSN)1521-3773
14. [14]
  Moser M, Vilé G, Colussi S, et al. J. Catal., 2015, 331(5): 444-447
15. [15]
  Zhang Z, Han D, Wei S, et al. J. Catal., 2010, 276(1):16-23 doi: 10.1016/j.jcat.2010.08.017
16. [16]
  Fei Z Y, Xie X X, Dai Y, et al. Ing. Eng. Chem. Res., 2014, 53:19438-19445 doi: 10.1021/ie503297k
17. [17]
  Lin J, Huang Y, Li L, et al. Chem. Eng. J., 2011, 168(2): 822-826 doi: 10.1016/j.cej.2011.01.081
18. [18]
  Rangaswamy A, Putla, Sudarsanam, et al. J. Rare Earth, 2015, 33(11):1162-1169 doi: 10.1016/S1002-0721(14)60541-X
19. [19]
  Moser M, Mondelli C, Schmidt T, et al. J. Appl. Catal. B: Environ., 2013, 132-133(9):123-131
20. [20]
  Katta L, Sudarsanam P, Thrimurthulu G, et al. Appl. Catal. B:Environ., 2010, 101(1/2):101-108
21. [21]
  HU Jian-Dong, LI Yong-Xiu, CHENG Chang-Ming, et al. Chinese J. Inorg. Chem., 2006, 22(7):1354-1358
22. [22]
  XIE Xing-Xing, FEI Zhao-Yang, ZOU Chou, et al. Acta Phys.-Chim. Sin., 2015, 31(6):1153-1161 doi: 10.3866/PKU.WHXB201504145
23. [23]
  Reddy B M, Katta L, Thrimurthulu G. Catal. Today, 2011, 175(1):585-592 doi: 10.1016/j.cattod.2011.02.047
24. [24]
  Bangi U K H, Park C S, Baek S, et al. Powder Technol., 2013, 239(17):314-318
25. [25]
  Reddy B M, Ataullah K, Pian L, et al. J. Phys. Chem. B, 2005, 109(8):3355-3363 doi: 10.1021/jp045193h
26. [26]
  ZHENG Yu-Ying, HUANG Hui-Ming, DENG Shu-Hua, et al. Chinese J. Inorg. Chem., 2005, 21(8):1227-1230
27. [27]
  Si R, Zhang Y, Li S, et al. J. Phys. Chem. B, 2004, 108(33): 12481-12488 doi: 10.1021/jp048084b
28. [28]
  Aramendía M A, Boráu V, Jiménez C, et al. J. Chem. Soc., Faraday Trans., 1997, 93, 1431-1438 doi: 10.1039/a606813h
29. [29]
  Menon U, Poelman H, Bliznuk V, et al. J. Catal., 2012, 295(6):91-103
30. [30]
  Mcbride J R, Hass K C, Poindexter B D, et al. Appl. Catal. B:Environ., 1994, 76(4):2435-2441
31. [31]
  Zhang Y, Yuwono A H, Wang J, et al. J. Phys. Chem. C, 2009, 113, 21406-21412 doi: 10.1021/jp907901k
32. [32]
  Dai Q, Bai S, Wang Z, et al. Appl. Catal. B:Environ., 2012, 126(126):64-75
1. [1]
  Deyun Ma , Fenglan Liang , Qingquan Xue , Yanping Liu , Chunqiang Zhuang , Shijie Li . Interfacial engineering of Cd_0.5Zn_0.5S/BiOBr S-scheme heterojunction with oxygen vacancies for effective photocatalytic antibiotic removal. Acta Physico-Chimica Sinica, 2025, 41(12): 100190-0. doi: 10.1016/j.actphy.2025.100190
2. [2]
  Yongmei Liu , Lisen Sun , Zhen Huang , Tao Tu . Curriculum-Based Ideological and Political Design for the Experiment of Methanol Oxidation to Formaldehyde Catalyzed by Electrolytic Silver. University Chemistry, 2024, 39(2): 67-71. doi: 10.3866/PKU.DXHX202308020
3. [3]
  Yachao HUANG , Chuanwang ZENG , Guiyong LIU , Jinming ZENG , Chao LIU , Xiaopeng QI . Oxygen vacancies and phosphorus doping enhanced metal-organic framework derived nitrogen-doped carbon-coated Co₃O₄ bifunctional electrocatalyst. Chinese Journal of Inorganic Chemistry, 2025, 41(11): 2251-2260. doi: 10.11862/CJIC.20250133
4. [4]
  Chunchun Wang , Changjun You , Ke Rong , Chuqi Shen , Fang Yang , Shijie Li . An S-Scheme MIL-101(Fe)-on-BiOCl Heterostructure with Oxygen Vacancies for Boosting Photocatalytic Removal of Cr(Ⅵ). Acta Physico-Chimica Sinica, 2024, 40(7): 2307045-0. doi: 10.3866/PKU.WHXB202307045
5. [5]
  Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421
6. [6]
  Weicheng Feng , Jingcheng Yu , Yilan Yang , Yige Guo , Geng Zou , Xiaoju Liu , Zhou Chen , Kun Dong , Yuefeng Song , Guoxiong Wang , Xinhe Bao . Regulating the High Entropy Component of Double Perovskite for High-Temperature Oxygen Evolution Reaction. Acta Physico-Chimica Sinica, 2024, 40(6): 2306013-0. doi: 10.3866/PKU.WHXB202306013
7. [7]
  Junjie TANG , Yunting ZHANG , Zhengjiang LIU , Jiani WU . Preparation of CeO₂ by starch template method for photo-Fenton degradation of methyl orange. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1617-1631. doi: 10.11862/CJIC.20240420
8. [8]
  Yinjie Xu , Suiqin Li , Lihao Liu , Jiahui He , Kai Li , Mengxin Wang , Shuying Zhao , Chun Li , Zhengbin Zhang , Xing Zhong , Jianguo Wang . Enhanced Electrocatalytic Oxidation of Sterols using the Synergistic Effect of NiFe-MOF and Aminoxyl Radicals. Acta Physico-Chimica Sinica, 2024, 40(3): 2305012-0. doi: 10.3866/PKU.WHXB202305012
9. [9]
  Hailang JIA , Pengcheng JI , Hongcheng LI . Preparation and performance of nickel doped ruthenium dioxide electrocatalyst for oxygen evolution. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1632-1640. doi: 10.11862/CJIC.20240398
10. [10]
  Xin Han , Zhihao Cheng , Jinfeng Zhang , Jie Liu , Cheng Zhong , Wenbin Hu . Design of Amorphous High-Entropy FeCoCrMnBS (Oxy) Hydroxides for Boosting Oxygen Evolution Reaction. Acta Physico-Chimica Sinica, 2025, 41(4): 100033-0. doi: 10.3866/PKU.WHXB202404023
11. [11]
  Wang Wang , Yucheng Liu , Shengli Chen . Use of NiFe Layered Double Hydroxide as Electrocatalyst in Oxygen Evolution Reaction: Catalytic Mechanisms, Electrode Design, and Durability. Acta Physico-Chimica Sinica, 2024, 40(2): 2303059-0. doi: 10.3866/PKU.WHXB202303059
12. [12]
  Yongpo Zhang , Xinfeng Li , Yafei Song , Mengyao Sun , Congcong Yin , Chunyan Gao , Jinzhong Zhao . Synthesis of Chlorine-Bridged Binuclear Cu(I) Complexes Based on Conjugation-Driven Cu(II) Oxidized Secondary Amines. University Chemistry, 2024, 39(5): 44-51. doi: 10.3866/PKU.DXHX202309092
13. [13]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
14. [14]
  Huafeng SHI . Construction of MnCoNi layered double hydroxide@Co-Ni-S amorphous hollow polyhedron composite with excellent electrocatalytic oxygen evolution performance. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1380-1386. doi: 10.11862/CJIC.20240378
15. [15]
  Qishen Wang , Changzhao Chen , Mengqing Li , Lingmin Wu , Kai Dai . Lignin derived carbon quantum dots and oxygen vacancies coregulated S-scheme LCQDs/Bi₂WO₆ heterojunction for photocatalytic H₂O₂ production. Acta Physico-Chimica Sinica, 2025, 41(11): 100147-0. doi: 10.1016/j.actphy.2025.100147
16. [16]
  Minna Ma , Yujin Ouyang , Yuan Wu , Mingwei Yuan , Lijuan Yang . Green Synthesis of Medical Chemiluminescence Reagents by Photocatalytic Oxidation. University Chemistry, 2024, 39(5): 134-143. doi: 10.3866/PKU.DXHX202310093
17. [17]
  Xiaotian ZHU , Fangding HUANG , Wenchang ZHU , Jianqing ZHAO . Layered oxide cathode for sodium-ion batteries: Surface and interface modification and suppressed gas generation effect. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 254-266. doi: 10.11862/CJIC.20240260
18. [18]
  Xiaofeng Zhu , Bingbing Xiao , Jiaxin Su , Shuai Wang , Qingran Zhang , Jun Wang . Transition Metal Oxides/Chalcogenides for Electrochemical Oxygen Reduction into Hydrogen Peroxides. Acta Physico-Chimica Sinica, 2024, 40(12): 2407005-0. doi: 10.3866/PKU.WHXB202407005
19. [19]
  Ye Wang , Ruixiang Ge , Xiang Liu , Jing Li , Haohong Duan . An Anion Leaching Strategy towards Metal Oxyhydroxides Synthesis for Electrocatalytic Oxidation of Glycerol. Acta Physico-Chimica Sinica, 2024, 40(7): 2307019-0. doi: 10.3866/PKU.WHXB202307019
20. [20]
  Liu Lin , Zemin Sun , Huatian Chen , Lian Zhao , Mingyue Sun , Yitao Yang , Zhensheng Liao , Xinyu Wu , Xinxin Li , Cheng Tang . Recent Advances in Electrocatalytic Two-Electron Water Oxidation for Green H₂O₂ Production. Acta Physico-Chimica Sinica, 2024, 40(4): 2305019-0. doi: 10.3866/PKU.WHXB202305019

Get Citation

PDF

XML

Metrics

PDF Downloads(3)
Abstract views(1600)
HTML views(161)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Superfine CeO2 Embedded in a Porous ZrO2 Matrix for Catalytic HCl Oxidation

Metrics

通讯作者: 陈斌, bchen63@163.com

Superfine CeO₂ Embedded in a Porous ZrO₂ Matrix for Catalytic HCl Oxidation