Citation: XU Xi-Hua, LOU Jia-Wei, XIE Xing-Xing, FEI Zhao-Yang, LIU Qing, CHEN Xian, TANG Ji-Hai, CUI Mi-Fen, QIAO Xu. Superfine CeO₂ Embedded in a Porous ZrO₂ Matrix for Catalytic HCl Oxidation[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(3): 421-428. doi: 10.11862/CJIC.2017.047 shu

Superfine CeO₂ Embedded in a Porous ZrO₂ Matrix for Catalytic HCl Oxidation

XU Xi-Hua ^1,2 ,
LOU Jia-Wei ^1,2 ,
XIE Xing-Xing ^1,2 ,
FEI Zhao-Yang ^1,2,*,, ,
LIU Qing ^1,2 ,
CHEN Xian ² ,
TANG Ji-Hai ² ,
CUI Mi-Fen ² ,
QIAO Xu ^1,2,*,,

1.
State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing Tech University, Nanjing 210009, China
2.
College of Chemical Engineering, Nanjing Tech University, Nanjing 210009, China

Corresponding author: FEI Zhao-Yang, zhaoyangfei@njtech.edu.cn QIAO Xu, qct@njtech.edu.cn
Received Date: 29 August 2016
Revised Date: 20 December 2016

Figures(7)

Ce-Zr composite oxide catalysts were prepared by different methods for catalytic HCl oxidation. The nano-sized CeO₂ particles embedded in the amorphous ZrO₂ matrix fabricated by spontaneous deposition strategy. A significant "size effect" of CeO₂ nanoparticles leads to considerably high concentration of Ce³⁺ and oxygen vacancy sites, which makes the catalyst have excellent low-temperature oxidation reduction performance and oxygen storage capacity. Catalytic performance tests indicate that the CeO₂@ZrO₂ catalyst shows superior activity (1.90 g_Cl₂·g_cat^-1·h^-1) and good durability. The isolation of CeO₂ nanoparticles by the amorphous ZrO₂ is a key factor of durability of the catalyst.
- catalytic oxidation,
- CeO₂,
- chlorine recycle,
- oxygen vacancy,
- size effect
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沈阳化工大学材料科学与工程学院沈阳 110142

Superfine CeO2 Embedded in a Porous ZrO2 Matrix for Catalytic HCl Oxidation

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Superfine CeO₂ Embedded in a Porous ZrO₂ Matrix for Catalytic HCl Oxidation