Citation: YANG Bing-Ye, LI Hang, SHANG Ning-Zhao, FENG Cheng, GAO Shu-Tao, WANG Chun. Visible-Light Responsive Photocatalyst g-C₃N₄@BiOCl with Hollow Flower-like Structure: Preparation and Photocatalytic Performance[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(3): 396-404. doi: 10.11862/CJIC.2017.033 shu

Visible-Light Responsive Photocatalyst g-C₃N₄@BiOCl with Hollow Flower-like Structure: Preparation and Photocatalytic Performance

College of Science, Agricultural University of Hebei, Baoding, Hebei 071001, China

Corresponding author: GAO Shu-Tao, gst824@163.com
Received Date: 31 August 2016
Revised Date: 1 December 2016

Figures(12)

The visible-light responsive photocatalyst of g-C₃N₄@BiOCl with hollow flower-like structure was fabricated via self-assembly strategy. The as-prepared heterojunction photocatalyst was characterized by X-ray diffraction, scanning electron microscopy, high-resolution transmission microscopy, energy dispersive X-ray spectroscopy, ultraviolet-visible diffuse reflection spectra and X-ray photoelectron spectroscopy. Due to the excellent ability of charge separation, the heterojunction photocatalyst exhibited much higher photocatalytic activity than g-C₃N₄ and BiOCl. The degradation efficiency of 50 mg·L^-1 rhodamine B can be reached to 99% within 12 min under visible-light irradiation (λ≥420 nm).
- g-C₃N₄,
- BiOCl,
- visible light,
- photocatalysis,
- degradation
1. [1]
  Wang H, Zhang L, Chen Z, et al. Chem. Soc. Rev., 2014, 43: 5234-5244 doi: 10.1039/C4CS00126E
2. [2]
  Rayalu S S, Jose D, Joshi M V, et al. Appl. Catal. B, 2013, 142-143:684-693 doi: 10.1016/j.apcatb.2013.05.057
3. [3]
  Tian J, Sang Y, Zhao Z, et al. Small, 2013, 9:3864-3872 doi: 10.1002/smll.v9.22
4. [4]
  Ye L, Su Y, Jin X, et al. Environ. Sci.:Nano, 2014, 1:90-112 doi: 10.1039/c3en00098b
5. [5]
  Gao F, Zeng D, Huang Q, et al. Phys. Chem. Chem. Phys., 2012, 14:10572-10578 doi: 10.1039/c2cp41045a
6. [6]
  Xiong J, Cheng G, Li G, et al. RSC Adv., 2011, 1:1542-1553 doi: 10.1039/c1ra00335f
7. [7]
  Wang D H, Gao G Q, Zhang Y W, et al. Nanoscale, 2012, 4: 7780-7785 doi: 10.1039/c2nr32533k
8. [8]
  Cheng G, Xiong J, Stadler F J. New J. Chem., 2013, 37:3207-3213 doi: 10.1039/c3nj00413a
9. [9]
  Sun D, Li J, Feng Z, et al. Catal. Commun., 2014, 51:1-4 doi: 10.1016/j.catcom.2014.03.004
10. [10]
  Yang W, Ma B, Wang W, et al. Phys. Chem. Chem. Phys., 2013, 15:19387-19394 doi: 10.1039/c3cp53628a
11. [11]
  Li T B, Chen G, Zhou C, et al. Dalton Trans., 2011, 40:6751-6758 doi: 10.1039/c1dt10471c
12. [12]
  Shamaila S, Sajjad A K L, Chen F, et al. J. Colloid Interface Sci., 2011, 356:465-472 doi: 10.1016/j.jcis.2011.01.015
13. [13]
  Cao S, Low J, Yu J, et al. Adv. Mater., 2015, 27:2150-2176 doi: 10.1002/adma.201500033
14. [14]
  Wang X, Maeda K, Thomas A, et al. Nat. Mater., 2009, 8:76-80 doi: 10.1038/nmat2317
15. [15]
  Gong Y, Zhang P, Xu X, et al. J. Catal., 2013, 297:272-280 doi: 10.1016/j.jcat.2012.10.018
16. [16]
  Xia J, Di J, Yin S, et al. Mater. Sci. Semicond. Process., 2014, 24:96-103 doi: 10.1016/j.mssp.2014.02.036
17. [17]
  Hou J, Cheng H, Takeda O, et al. Energy Environ. Sci., 2015, 8:1348-1357 doi: 10.1039/C4EE03707C
18. [18]
  Zheng Y, Lin L, Wang B, et al. Angew. Chem. Int. Ed., 2015, 54:12868-12884 doi: 10.1002/anie.v54.44
19. [19]
  Pan C, Xu J, Wang Y, et al. Adv. Funct. Mater., 2012, 22: 1518-1524 doi: 10.1002/adfm.v22.7
20. [20]
  Liu L, Qi Y, Lu J, et al. Appl. Catal. B, 2016, 183:133-141 doi: 10.1016/j.apcatb.2015.10.035
21. [21]
  Wang X J, Wang Q, Li F T, et al. Chem. Eng. J., 2013, 234: 361-371 doi: 10.1016/j.cej.2013.08.112
22. [22]
  Chang F, Xie Y, Zhang J, et al. RSC Adv., 2014, 4:28519-28528 doi: 10.1039/c4ra02735c
23. [23]
  Lei L, Jin H, Zhang Q, et al. Dalton Trans., 2015, 44:795-803 doi: 10.1039/C4DT02082K
24. [24]
  Li Q, Zhao X, Yang J, et al. Nanoscale, 2015, 7:18971-18983 doi: 10.1039/C5NR05154A
25. [25]
  Zhou Z, Wang J, Yu J, et al. J. Am. Chem. Soc., 2015, 137: 2179-2182 doi: 10.1021/ja512179x
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Visible-Light Responsive Photocatalyst g-C3N4@BiOCl with Hollow Flower-like Structure: Preparation and Photocatalytic Performance

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通讯作者: 陈斌, bchen63@163.com

Visible-Light Responsive Photocatalyst g-C₃N₄@BiOCl with Hollow Flower-like Structure: Preparation and Photocatalytic Performance