Citation: DI Bao-Sheng, LUO Yan-Sheng, ZENG Xue-Hua, HE Li-Hua, CHEN Jing-Lin, LIAO Jin-Sheng, LIU Sui-Jun, WEN He-Rui. Effect of the Methylation on Mononuclear Gd(Ⅲ) Bipyridyl Tetrazolate Complexes[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(2): 323-328. doi: 10.11862/CJIC.2017.031 shu

Effect of the Methylation on Mononuclear Gd(Ⅲ) Bipyridyl Tetrazolate Complexes

School of Metallurgy and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou, Jiangxi 341000, China

Corresponding author: CHEN Jing-Lin, gzchenjinglin@126.com
Received Date: 8 August 2016
Revised Date: 7 December 2016

Figures(3)

Two new mononuclear Gd (Ⅲ)complexes, [Gd (tbpy)₂ (DMF) (H₂O)₂]NO₃·2H₂O (1)and[Gd (tmbpy)₂ (DMF) (NO₃)]·DMF·THF (2), have been synthesized by using 6-(1H-tetrazole-5-yl)-2, 2'-bipyridyle (tbpyH)and 6-(1H-tetrazole-5-yl)-4, 4'-dimethyl-2, 2'-bipyridyle (tmbpyH). As revealed by single-crystal X-ray diffraction, each Gd (Ⅲ)ion has a distorted tricapped trigonal prism with two mono-anionic tridentate chelating ligands, originating from N-H deprotonation of the tetrazolyl ring, and the introduction of two methyl groups into the 2, 2'-bypridyl ring has a significant effect on the coordination environment of the Gd (Ⅲ)core, showing that two mono-coordinated H₂O molecules are displaced by one chelating nitrate. CCDC:1496645, 1; 1496646, 2.
- Gd(Ⅲ) complex,
- bipyridyl tetrazole,
- methylation,
- crystal structure
1. [1]
  Leonard J P, Nolan C B, Stomeo F, et al. Top. Curr. Chem., 2007, 281:1-43 doi: 10.1007/978-3-540-73349-2
2. [2]
  Eliseeva S V, Bünzli J C G. Chem. Soc. Rev., 2010, 39:189-227 doi: 10.1039/B905604C
3. [3]
  Binnemans K. Chem. Rev., 2009, 109:4283-4374 doi: 10.1021/cr8003983
4. [4]
  Gao F, Cui L, Liu W, et al. Inorg. Chem., 2013, 52:11164-11172 doi: 10.1021/ic401421h
5. [5]
  Gao F, Cui L, Song Y, et al. Inorg. Chem., 2014, 53:562-567 doi: 10.1021/ic4026624
6. [6]
  Li H X, Cheng M L, Ren Z G, et al. Inorg. Chem., 2006, 45:1885-1887 doi: 10.1021/ic052073v
7. [7]
  Liu L L, Ren Z G, Zhu L W, et al. Cryst. Growth Des., 2011, 11:3479-3488 doi: 10.1021/cg200308k
8. [8]
  BING Ying-Ying, WU Zhen-Ting, HU Ming. Chinese J. Inorg. Chem., 2015, 31:2059-2064
9. [9]
  Zebret S, Dupont N, Bernardinelli G, et al. Chem. Eur. J., 2009, 15:3355-3358 doi: 10.1002/chem.v15:14
10. [10]
  Zebret S, Dupont N, Besnard C, et al. Dalton Trans., 2012, 41:4817-4823 doi: 10.1039/c2dt12227h
11. [11]
  Rybak J C, Meyer L V, Wagenhfer J, et al. Inorg. Chem., 2012, 51:13204-13213 doi: 10.1021/ic301482e
12. [12]
  Gusev A N, Shul'gin V F, Meshkova S B, et al. Inorg. Chim. Acta, 2012, 387:321-326 doi: 10.1016/j.ica.2012.02.016
13. [13]
  Gusev A N, Hasegawa M, Nishchymenko G A, et al. Dalton Trans., 2013, 42:6936-6943 doi: 10.1039/c3dt50297j
14. [14]
  D'Alessio D, Muzzioli S, Skelton B W, et al. Dalton Trans., 2012, 41:4736-4739 doi: 10.1039/c2dt12246d
15. [15]
  Facchetti A, Abbotto A, Beverina L, et al. Chem. Commun., 2004, 15:1770-1771
16. [16]
  Andrews P C, Junk P C, Massi M, et al. Chem. Commun., 2006, 31:3317-3319
17. [17]
  Giraud M, Andreiadis E S, Fisyuk A S, et al. Inorg. Chem., 2008, 47:3952-3954 doi: 10.1021/ic8005663
18. [18]
  Bozoklu G, Marchal C, Pécaut J, et al. Dalton Trans., 2010, 39:9112-9122 doi: 10.1039/c0dt00225a
19. [19]
  Andreiadis E S, Imbert D, Pécaut J, et al. Dalton Trans., 2012, 41:1268-1277 doi: 10.1039/C1DT11627D
20. [20]
  Lin J M, Guan Y F, Wang D Y, et al. Dalton Trans., 2008, 37:6165-6169
21. [21]
  Wu M F, Wang M S, Guo S P, et al. Crystal. Growth Des., 2011, 11:372-381 doi: 10.1021/cg100817s
22. [22]
  Liang L, Peng G, Ma L, et al. Crystal. Growth Des., 2012, 12:1151-1158 doi: 10.1021/cg200856e
23. [23]
  Kratsch J, Beele B B, Koke C, et al. Inorg. Chem., 2014, 53:8949-8958 doi: 10.1021/ic5007549
24. [24]
  Song Y H, Chiu Y C, Chi Y, et al. Organometallics, 2008, 27:80-87 doi: 10.1021/om700577y
25. [25]
  Chen J L, Tan X Z, Chen X X, et al. Inorg. Chem. Commun., 2013, 30:120-123 doi: 10.1016/j.inoche.2013.02.003
26. [26]
  Chen J L, Luo Y S, Gao G P, et al. Polyhedron, 2016, 117:388-393 doi: 10.1016/j.poly.2016.06.019
27. [27]
  Sheldrick G M. Acta Crystallogr. Sect. A, 1990, 46:467-473 doi: 10.1107/S0108767390000277
28. [28]
  Sheldrick G M. Acta Crystallogr. Sect. A, 2008, 64:112-122 doi: 10.1107/S0108767307043930
29. [29]
  Fukuda Y, Nakao A, Hayashi K. J. Chem. Soc., Dalton Trans., 2002:527-533
30. [30]
  LIU Ying-Hong, REN Qing, MA Jian-Ru, et al. Chinese J. Inorg. Chem., 2007, 23:1322-1328 doi: 10.3321/j.issn:1001-4861.2007.08.002
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