Citation: DU Jun-Chen, ZHANG Ai-Min, MA Jiang-Li, LIU Qiang, Feng FENG, CHEN Yu-Bao, ZHAO Yun-Kun. Pd-Al₂O₃-BEA Catalysts for the Preparation of Jet Fuel-Range Hydrocarbons from Oils Through One-Step Hydrogenation[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(3): 415-420. doi: 10.11862/CJIC.2017.027 shu

Pd-Al₂O₃-BEA Catalysts for the Preparation of Jet Fuel-Range Hydrocarbons from Oils Through One-Step Hydrogenation

DU Jun-Chen ^1,2 ,
ZHANG Ai-Min ^1,2,*,, ,
MA Jiang-Li ² ,
LIU Qiang ¹ ,
Feng FENG ^2,*,, ,
CHEN Yu-Bao ³ ,
ZHAO Yun-Kun ¹

1.
State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals, Kunming Institute of Precious Metals, Kunming 650106, China
2.
State-Local Joint Engineer Laboratory of Precious Metals Catalytic Technology and Application, Kunming Sino-platinum Metals Catalysts Co., Ltd., Kunming 650106, China
3.
College of Energy and Environmental Science, Yunnan Normal University, Kunming 650500, China

Corresponding author: ZHANG Ai-Min, aiming.zhang@126.com Feng FENG, feng.feng@spmcatalyst.com
Received Date: 24 August 2016
Revised Date: 6 December 2016

Figures(3)

H-β zeolite modified Pd/Al₂O₃ catalysts were prepared by impregnation. Effects of adding method and content of H-β zeolite on the catalytic performance were studied by XRD, BET, NH₃-TPD and other analytical characterization techniques, as well as the reaction system with methyl oleate as model compounds studied. The results showed that the interaction among the components of Pd-Al₂O₃-BEA catalyst has a great difference because of the different adding method of H-β zeolite, thus its catalytic properties were greatly different. In the Pd/(BEA-Al₂O₃) catalysts, with H-β zeolite amount increased, its specific surface area, pore volume, acid amount of strong acid site all showed a trend of increase, while acid amount of weak acid site was first increased and decreased then, and the average pore size was decreased. Pd/(45%BEA-Al₂O₃) catalyst has the largest jet fuel-range hydrocarbons selectivity, branched alkanes selectivity, a certain proportion of naphthenes and aromatics, since it has an appropriate pore size distribution, moderate amount of strong acid site, the biggest amount of weak acid site.
- Pd/Al₂O₃ catalysts,
- H-β zeolite,
- jet fuel-range hydrocarbons,
- hydrogenation,
- oils
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Pd-Al2O3-BEA Catalysts for the Preparation of Jet Fuel-Range Hydrocarbons from Oils Through One-Step Hydrogenation

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Pd-Al₂O₃-BEA Catalysts for the Preparation of Jet Fuel-Range Hydrocarbons from Oils Through One-Step Hydrogenation