Citation: MAO Xian-Jie, ZHOU Li-Hua, FU Si-Lian, YIN Hang, ZHAO Xiao-Lei, WU Wei-Na, WANG Yuan. Crystal Structures and Fluorescence Property of Cu(Ⅱ)/Zn(Ⅱ) Complexes of 1-(3-Ethylpyrazin-2-yl) ethylidene-4-phenylsemicarbazide[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(1): 163-168. doi: 10.11862/CJIC.2017.023 shu

Crystal Structures and Fluorescence Property of Cu(Ⅱ)/Zn(Ⅱ) Complexes of 1-(3-Ethylpyrazin-2-yl) ethylidene-4-phenylsemicarbazide

MAO Xian-Jie ¹ ,
ZHOU Li-Hua ² ,
FU Si-Lian ² ,
YIN Hang ² ,
ZHAO Xiao-Lei ^1,*,, ,
WU Wei-Na ^1,*,, ,
WANG Yuan ¹

1.
College of Chemistry and Chemical Engineering, Henan Polytechnic University, Jiaozuo, Henan 454000, China
2.
School of Materials Science and Engineering, Henan Polytechnic University, Jiaozuo, Henan 454000, China

Corresponding author: ZHAO Xiao-Lei, zhaoxiaolei@hpu.edu.cn WU Wei-Na, wuwn08@hpu.edu.cn
Received Date: 9 August 2016
Revised Date: 9 November 2016

Figures(4)

Two complexes, namely[Cu(HL)(H₂O)(NO₃)]NO₃ (1) and [Zn(HL)Cl₂] (2) (where HL is 1-(3-ethylpyrazin-2-yl)ethylidene-4-phenylsemicarbazide) have been synthesized and characterized by single crystal X-ray diffraction, elemental analysis and IR spectroscopy. X-ray diffraction analysis results show that in complex 1, the center Cu(Ⅱ) ion is penta-coordinated by one neutral tridentate semicarbazone, one coordinated water molecule and one monodentate nitrate, thus giving a distorted square pyramid coordination geometry. The coordination geometry of the Zn(Ⅱ) ion in complex 2 is same as that of the Cu(Ⅱ) ion in complex 1, while with N₂OCl₂ donor set. In methanol solution, the fluorescence spectra of the ligand HL and complex 2 are quite similar, whilst the emission peak of complex 1 has slightly red-shift, primarily due to the charge transfer between the ligand and metal ion. CCDC:1497370, 1; 1497371, 2.
- semicarbazone,
- Cu(Ⅱ) complex,
- Zn(Ⅱ) complex,
- pyrazine,
- fluorescence
1. [1]
  Ye X P, Zhu T F, Wu W N, et al. Inorg. Chem.Commun., 2014,47:60-62
2. [2]
  CHEN Yan-Min , XIE Qing-Fan, LIU Jin-Hua, et al. Chinese J. Inorg. Chem. , 2015,31:74-80
3. [3]
  Singh P, Singh D P, Singh V P. Polyhedron, 2014,81:56-65
4. [4]
  Nath M, Vats M, Roy P. Eur. J. Med. Chem., 2013,59:310-321
5. [5]
  Milenkovi M, Cantoni G, Bacchi A, et al. Polyhedron, 2014, 80:47-52
6. [6]
  Milenkovi M, Bacchi A, Cantoni G, et al. Inorg. Chim. Acta, 2013,395:33-43
7. [7]
  Chang H Q, Jia L, Xu Z Q, et al. Inorg. Chem.Commun., 2015,57:8-10
8. [8]
  Li M X, Zhang L Z, Yang M, et al. Bioorg. Med. Chem. Lett., 2012,22:2418-2433
9. [9]
  Li M X, Zhang L Z, Zhang D, et al. Eur. J. Med. Chem., 2011,46:4383-4390
10. [10]
  Qi J, Liang S, Gou Y, et al. Eur. J. Med. Chem., 2015,96: 360-368
11. [11]
  MAO Pan-Dong, HAN Xue-Feng, WU Wei-Na, et al. Chinese J. Inorg. Chem. , 2016,32:161-166
12. [12]
  Sheldrick G M. SADABS, University of Göttingen, Germany, 1996.
13. [13]
  Sheldrick G M. SHELX-97, Program for the Solution and the Refinement of Crystal Structures, University of Göttingen, Germany, 1997.
14. [14]
  WU Wei-Na, WANG Yuan , TANG Ning . Chinese J. Inorg. Chem., 2012,28: 425-428
15. [15]
  WANG Xiu-Li, SUI Fang-Fang, LIN Hong-Yan, et al. Chinese J. Inorg. Chem. , 2014,30:2626-2634
1. [1]
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2. [2]
  Shuwen SUN , Gaofeng WANG . Two cadmium coordination polymers constructed by varying Ⅴ-shaped co-ligands: Syntheses, structures, and fluorescence properties. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 613-620. doi: 10.11862/CJIC.20230368
3. [3]
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4. [4]
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5. [5]
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6. [6]
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7. [7]
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15. [15]
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18. [18]
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19. [19]
  Yingying Yan , Wanhe Jia , Rui Cai , Chun Liu . An AIPE-active fluorinated cationic Pt(Ⅱ) complex for efficient detection of picric acid in aqueous media. Chinese Chemical Letters, 2024, 35(5): 108819-. doi: 10.1016/j.cclet.2023.108819
20. [20]
  Jian Peng , Yue Jiang , Shuangyu Wu , Yanran Cheng , Jingyu Liang , Yixin Wang , Zhuo Li , Sijie Lin . A nonradical oxidation process initiated by Ti-peroxo complex showed high specificity toward the degradation of tetracycline antibiotics. Chinese Chemical Letters, 2024, 35(5): 108903-. doi: 10.1016/j.cclet.2023.108903

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