Citation: TANG Hui, GUO Yan-Hong, SHENG Jun-Feng, TONG Yu-Zhu, SONG Fei, WANG Zuo-Xiang, QU Zhi-Rong. Syntheses, Crystal Structures and Spectral Properties of Two SilverⅠ Complexes with 3-Methyl-4-ehtyl-5-(2(or 4)-pyridyl)-1,2,4-triazoles[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(1): 134-142. doi: 10.11862/CJIC.2017.012 shu

Syntheses, Crystal Structures and Spectral Properties of Two SilverⅠ Complexes with 3-Methyl-4-ehtyl-5-(2(or 4)-pyridyl)-1,2,4-triazoles

1.
College of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, China
2.
Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education, Hangzhou Normal University, Hangzhou 311121, China

Corresponding author: WANG Zuo-Xiang, wangzx0908@aliyun.com
Received Date: 23 June 2016
Revised Date: 16 November 2016

Figures(12)

Two Ag(Ⅰ) complexes of[Ag2(μ-L)₂L₂(NO₃)₂] (1) and {[Ag₂(μ-L')₂(H₂O)₂](NO₃)₂}_n (2), where L (or L')=3-methyl-4-ethyl-5-(2(or 4)-pyridyl)-1,2,4-triazole, have been synthesized and characterized by single-crystal X-ray diffraction, IR, fluorescence measurement and TGA. Complexes 1 and 2 crystallize in triclinic system with space group P1. Crystallographic studies show that both complex 1 and 2 have a distorted tetrahedral core[AgN₃O] with one NO₃^- in 1 but one coordinated H₂O molecule in 2. Complex 1 is a binuclear silver(Ⅰ) complex bridged through the nitrogen atoms of triazole rings. Complex 2 is a polymer complex bridged by the nitrogen atoms of pyridine and triazole rings. CCDC:1046706, L'; 1046707, 1; 1046708, 2.
- crystal structure,
- synthesis,
- triazole,
- silver(Ⅰ) complex
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沈阳化工大学材料科学与工程学院沈阳 110142