Citation: MAO Yan-Li, LUO Shi-Tian, WU Jun-Feng, KANG Hai-Yan, LIU Biao, PAN Jian-Ming, HUO Peng-Wei. Selective Adsorption and Separation of Ciprofloxacin by Molecularly Imprinted Polymers Based on Magnetic Kaolinite Composites[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(1): 81-88. doi: 10.11862/CJIC.2017.007 shu

Selective Adsorption and Separation of Ciprofloxacin by Molecularly Imprinted Polymers Based on Magnetic Kaolinite Composites

1.
School of Municipal and Environmental Engineering, Henan University of Urban Construction, Pingdingshan, Henan 467036, China
2.
Construction Engineering Quality Supervise Station of Pingdingshan Construction Commmittee, Pingdingshan, Henan 467036, China
3.
School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang, Jiangsu 212013, China

Corresponding author: MAO Yan-Li, myanliao@163.com
Received Date: 10 July 2016
Revised Date: 11 November 2016

Figures(10)

Based on the magnetic kaolinite-MPS, magnetic molecularly imprinted particles (MMIPs) were further synthesized via activators regenerated by electron transfer atom transfer radical polymerization (AGET ATRP). The as-prepared MMIPs were charcterized by FTIR, TEM, XRD, TGA and VSM, which indicated that the MMIPs exhibited magnetic sensitivity (M_s=13.365 emu·g^-1), thermal stability and the larger specific surface area(112 m²·g^-1). The results of batch adsorption experiments suggested that pH value of 6.0 in testing solution was the optimal adsorption condition. The kinetic properties of MMIPs were well described by the pseudo-second-order model. The Langmuir isotherm model was fitted to the equilibrium data, and the monolayer adsorption capacity of MMIPs at 25℃ was 89.36 mg·g^-1. The selective recognition experiments demonstrated high affinity and selectivity of MMIPs towards ciprofloxacin (CIP) over competitive antibiotics. Combined with high performance liquid chromatographic analysis technology, the prepared MMIPs were successfully applied to extract trace CIP in fish samples, and the recoveries of CIP was 92.15%.
- magnetic kaolinite,
- magnetic molecularly imprinted particles,
- ciprofloxacin,
- specific adsorption
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沈阳化工大学材料科学与工程学院沈阳 110142