Citation: TAN Xiong-Wen, LI Heng-Feng, LI Chang-Hong. Syntheses, Crystal Structures and Fluorescence Properties of Two Complexes Constructed from Rigid 1,4-bis(4-methyl-imidazolyl) Benzene[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(1): 156-162. doi: 10.11862/CJIC.2017.002 shu

Syntheses, Crystal Structures and Fluorescence Properties of Two Complexes Constructed from Rigid 1,4-bis(4-methyl-imidazolyl) Benzene

1.
School of Materials Science and Engineering, Central South University, Changsha 410083, China
2.
College of Chemistry and Materials Science, Hengyang Normal University, Hengyang, Hunan 421008, China

Corresponding author: LI Heng-Feng, lihf@csu.edu.cn
Received Date: 1 September 2016
Revised Date: 28 October 2016

Figures(5)

The reaction of M(NO₃)₂·6H₂O (M=Cd, Zn), isophthalic acid(H₂IP) as well as 1,4-bis(4-methyl-imidazolyl)benzene(BMIB) results in formation of a 1D complex {[Cd(BMIB)(H₂O)₂](NO₃)₂}_n (1) and 3D complex {[Zn₂(BMIB)_1.5(OH)(IP)_1.5]·H₂O}_n (2). X-ray diffraction crystal structure analysis shows that 1 crystallizes in triclinic system, space group P1 with a=0.3820 8(3) nm, b=0.904 72(7) nm, c=1.378 29(10) nm, α=98.581(4)°, β=97.020(3)°, γ=94.398(3)°. In 1, BMIB links all the Cd atoms into a 1D chain, which forms 2D bilayer through the H-bond interactions. The complex 2 crystallizes in monoclinic system, space group C2/c with a=3.764 07(9) nm, b=1.017 18(5) nm, c=2.015 31(11) nm, β=120.860(2)°. On the other hand, in 2, the carboxylate group of ligand IP^2- with μ₂-η¹:η¹ coor-dination mode links metal atoms to give a 1D double-chain structure, which forms 3D network through Zn-N and Zn-OH interactions. In addition, the fluorescence property of complexes 1 and 2 have been investigated, which exhibit good fluorescence in the solid state at room temperature. CCDC:1511866, 1; 1511867, 2.
- 1,4-bis(4-methyl-imidazolyl)benzene,
- crystal structure,
- fluorescence
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沈阳化工大学材料科学与工程学院沈阳 110142