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Citation: CAI Sheng-Rong, WANG Xiao-Fei, ZHU Ding, MU Shi-Jia, ZHANG Kai-Fang, HUANG Li-Wu, CHEN Yun-Gui. CoOOH as Cathode Catalyst for High Performance Non-Aqueous Li-O2 Batteries[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(12): 2082-2087. doi: 10.11862/CJIC.2016.272 shu

CoOOH as Cathode Catalyst for High Performance Non-Aqueous Li-O2 Batteries

  • 1.

    1 College of Materials Science and Engineering, Sichuan University, Chengdu 610065, China;

  • 2.

    2 Institute of New Energy and Low-Carbon Technology, Sichuan University, Chengdu 610065, China

  • Corresponding author: ZHU Ding,  CHEN Yun-Gui, 
  • Received Date: 26 July 2016
    Available Online: 7 October 2016

    Fund Project:

  • CoOOH was synthesized by a simple one-step co-precipitation method, and used as cathode catalyst in non-aqueous Li-O2 batteries. The introduction of CoOOH could catalyze the oxygen reduction reaction (ORR) upon discharge, making the CoOOH-contained cathode display a high discharge capacity of 5 093 mAh·g-1, which was about 1.7 times higher than that of the CoOOH-free cathode. Furthermore, the CoOOH-contained cathode exhibited a significantly reduced recharge overpotential (460 mV), enhancing recharge-ability. Thus, the reversibility was improved, and the cycling performance was ameliorated.
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