Citation: LIU Ying, HU Jun, YAN Jie, ZHI Xia, ZHANG Cai-Ling, PAN Qin-He. Template-Directed Synthesis of a Series of Rare-Earth Metal Oxalate Compounds Using Co(Ⅲ) Complex as Template[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(9): 1559-1564. doi: 10.11862/CJIC.2016.197 shu

Template-Directed Synthesis of a Series of Rare-Earth Metal Oxalate Compounds Using Co(Ⅲ) Complex as Template

LIU Ying ¹ ,
HU Jun ¹ ,
YAN Jie ¹ ,
ZHI Xia ¹ ,
ZHANG Cai-Ling ¹ ,
PAN Qin-He ^1,2,*,,

1.
Key Study Center of the National Ministry of Education for Tropical Resources Utilization, College of Materials and Chemical Engineering, Hainan University, Haikou 570228, China
2.
Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Nankai University, Tianjin 300071, China

Corresponding author: PAN Qin-He, panqinhe@163.com
Received Date: 12 April 2016
Revised Date: 25 July 2016

Figures(4)

Under hydrothermal conditions, three novel complexes {[Co(en)₃]·[KLa₂(C₂O₄)₅(H₂O)₆]·H₂O}_n (HNU-9), {[Co(dien)₂][La₂(C₂O₄)₄(H₂O)₂]·xH₂O}_n (HNU-11) and {K₃[Co(dien)₂][La₄(C₂O₄)₉(H₂O)₂]·5H₂O}_n (HNU-12) were synthesized by using Co(Ⅲ) complexes as template. Different templates ([Co(en)₃]³⁺, [Co(dien)₂]³⁺, K⁺+[Co(dien)₂]³⁺) exist in compounds in different ways, leading to different three-dimensional framework structures. Interesting, the structures of HNU-11 and HNU-12 present the novel topology structure due to different coordination modes of the central La³⁺. Therefore, it is suggested that rare earth metal with higher coordination number more easily lead to form complexes with novel structure. CCDC: 1495537, HNU-9; 1495538, HUN-11; 1495539, HUN-12.
- rare-earth-oxalate complexes,
- template,
- transition metal complexes,
- solvothermal synthesis
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沈阳化工大学材料科学与工程学院沈阳 110142