Citation: YE Dan-Dan, WANG Lei, GU Xiao-Min, NI Liang, ZHANG Wen-Li. Two POMs-Modified Transition Metal Compounds Constructed by Rigid Ligands:Structures, Catalytic and Electrochemical Properties[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(9): 1629-1636. doi: 10.11862/CJIC.2016.189 shu

Two POMs-Modified Transition Metal Compounds Constructed by Rigid Ligands:Structures, Catalytic and Electrochemical Properties

School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang, Jiangsu 212013, China

Corresponding author: ZHANG Wen-Li, wlzhang@ujs.edu.cn
Received Date: 5 May 2016
Revised Date: 23 June 2016

Figures(5)

By utilizing two kinds of simply rigid organic ligands, two new polyoxometalates-modified transition metal compounds (POMs-TMC), [Cu(dmbipy)₂(SiW₁₂O₄₀)][Cu(dmbipy)(H₂O)₃]·3H₂O(1), and {(Hdmphen)₂[Ag₂(dmphen)₂(SiW₁₂O₄₀)]}_n(2) (dmbipy=4, 4′-dimethyl-2, 2′-bipyridine, dmphen=2, 9-dimethyl-1, 10-phenanthrolin), were synthesized through hydrothermal technique. In compound 1, there are two crystallographically independent Cu(Ⅱ) ions. They all exhibit penta-coordinated modes, with three water molecules embedding through Cu-O bonds. Different Cu(Ⅱ) subunits cross-link each other to build a 1D chain by hydrogen bonding interactions between coordinated water molecules and [SiW₁₂O₄₀]^4- anions. Adjacent chains also pursue to construct a 2D layer by such hydrogen bonding. In compound 2, the Keggin anions are fused by Ag(Ⅱ) ions to form a 1D chain. The adjacent chains are further linked by π…π stacking and hydrogen bonding interactions. So, 2D polyoxometalates-modified organic layer is constructed. The main traits of compounds 1 and 2 are that these simply rigid organic ligands employ noncovalent interactions to form the 2D layer. CCDC: 1033952, 1; 1053009, 2.
- polyoxometalates,
- transition metal compound,
- catalytic activity,
- electrochemical property
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