Citation: XIONG Hang-Xing. Syntheses, Crystal Structures and Catalytic Oxidation of Dioxomolybdenum(Ⅵ)Complexes with Hydrazone Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(9): 1596-1602. doi: 10.11862/CJIC.2016.180 shu

Syntheses, Crystal Structures and Catalytic Oxidation of Dioxomolybdenum(Ⅵ)Complexes with Hydrazone Ligands

XIONG Hang-Xing ^*,,

College of Chemical Engineering and Pharmacy, Jingchu University of Technology, Jingmen, Hubei 448000, China

Corresponding author: XIONG Hang-Xing, xionghx168@163.com
Received Date: 1 May 2016
Revised Date: 20 June 2016

Figures(7)

Two new mononuclear dioxomolybdenum(Ⅵ) complexes with general formula [MoO₂L(MeOH)], where L¹ and L² are the dianionic form of N'-(3-bromo-2-hydroxybenzylidene)-3, 5-dimethoxybenzohydrazide and N'-(5-bromo-2-hydroxybenzylidene)isonicotinohydrazide, respectively, were prepared and structurally characterized by physico-chemical, spectroscopic methods and single crystal X-ray determination. The crystal of complex 1 crystallizes in monoclinic space group P2₁/n, with a=0.848 98(3) nm, b=2.275 4(1) nm, c=1.069 82(5) nm, β=109.108(1)°, V=1.952 8(1) nm³, Z=4, R₁=0.036 7, wR₂=0.084 0, S=1.027. The crystal of complex 2 crystallizes in triclinic space group P1, with a=0.655 05(9) nm, b=1.076 63(7) nm, c=1.303 3(1) nm, α=67.383(2)°, β=84.264(1)°, γ=76.195(2)°, V=0.823 9(1) nm³, Z=2, R₁=0.071 3, wR₂=0.151 0, S=1.004. X-ray analysis indicates that the Mo atom in each complex is in an octahedral coordination environment, constructed by two oxo groups and NO₂ donor set of the hydrazone ligand, as well as a methanol O atom. The catalytic property of the complexes indicates that they are efficient catalysts for the oxidation of olefins. CCDC: 1476621, 1; 1476622, 2.
- hydrazone,
- molybdenum complex,
- crystal structure,
- catalytic property
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