Citation: MAO Pan-Dong, YAN Ling-Ling, WANG Wen-Jing, YANG Qian-Qian, CUI Meng-Qiang, WANG Yuan, WU Wei-Na. Syntheses, Crystal Structures and DNA-Binding Properties of Co (Ⅲ)/Cd (Ⅱ) Complexes with Quinoline Thiosemicarbazone Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(3): 555-560. doi: 10.11862/CJIC.2016.064 shu

Syntheses, Crystal Structures and DNA-Binding Properties of Co (Ⅲ)/Cd (Ⅱ) Complexes with Quinoline Thiosemicarbazone Ligand

1.
Department of Physics and Chemistry, Henan Polytechnic University, Jiaozuo, Henan 454000, China
2.
School of Materials Science and Engineering, Henan Polytechnic University, Jiaozuo, Henan 454000, China

Corresponding author: YAN Ling-Ling, yll@hpu.edu.cn WANG Yuan, wangyuan08@hpu.edu.cn
Received Date: 18 November 2015
Revised Date: 15 January 2016

Figures(4)

Two complexes [CoL₂]Cl·2CH₃OH (1) and [CdL₂] (2) (HL=(quinolin-8-ylmethylene) thiosemicarbazide) have been synthesized and structurally determined by single-crystal X-ray diffraction. The results show that the metal ion in each complex with a distorted octahedron geometry is surrounded by two anionic thiosemicarbazone ligand with N₂S donor set. Complexes 1 and 2 can bind to DNA via electrostatic intercalation and partial intercalation modes, respectively. CCDC: 1436092, 1; 1436093, 2.
- quinoline,
- thiosemicarbazone,
- complex,
- crystal structure,
- DNA-biding property
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沈阳化工大学材料科学与工程学院沈阳 110142