Citation: ZHAO Qiang, LIU Xiu-Ming, FENG Rui, ZHANG Ying-Hui, KONG Man-Man, LIU Yang. Polypyridyl Ligands-Based Double-Decker Triggered by Silver (Ⅰ) Coordination: Crystal Structures and Spectroscopic Analysis[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(3): 537-544. doi: 10.11862/CJIC.2016.060 shu

Polypyridyl Ligands-Based Double-Decker Triggered by Silver (Ⅰ) Coordination: Crystal Structures and Spectroscopic Analysis

1.
College of Chemistry and Pharmaceutical Engineering, Nanyang Normal University, Nanyang, Henan 473061, China
2.
School of matrerials science and engineering, Nankai University, Tianjin 300071, China

Corresponding author: ZHANG Ying-Hui, zhangyhi@nankai.edu.cn
Received Date: 5 September 2015
Revised Date: 6 January 2016

Figures(5)

Three Ag (Ⅰ) coordination complexes, namely [Ag (dpq)(NO₃)₂]_n (1), [Ag₄ (tppq)₂(NO₃)₄](2) and [Ag₆(hpdq)₂(NO₃)₆](3) have been synthesized based on three polypyridyl ligands: 2, 3-di (pyridin-2-yl) quinoxaline (dpq), 2, 3, 7, 8-tetra (pyridine-2-yl) pyrazino[2, 3-g]-quinoxaline (tppq) and 2, 3, 6, 7, 10, 11-hexakis (2-pyridyl) dipyrazino[2, 3-f:2′, 3′-h]quinoxaline) (hpdq), respectively. Single crystal X-ray diffraction analyses reveal that complexes 1~3 assembled based on distinct double-decker unit comprising two respective polypyridyl ligands but four, four, and six Ag (Ⅰ) ions, respectively. Among them, The double-decker units in 1 and 2 both extended to two dimensional net via the coordination interaction between Ag (Ⅰ) and NO₃^- anion, while that in 3 to three dimensional net via C-H…O hydrogen bond. Furthermore, the coordintion interaciton of polypyridyl ligands and Ag (Ⅰ) ion in solution was also investigated by UV-Vis absorption and fluorescence spectroscopic analyses, which witnesses the much more sensitive spectral response of hpdq to the additon of Ag (Ⅰ) ion than other two ligands. CCDC: 868734, 1; 868735, 2; 790268, 3.
- polypyridyl ligands,
- metal-organic coordination complexes,
- self-assembly,
- UV-Vis spectrum,
- fluorescence spectrum
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沈阳化工大学材料科学与工程学院沈阳 110142