Citation: YU Yu-Ye, SHEN Wei, WU Xiao-Yong, ZHAO Guo-Liang. Syntheses, Structures and DNA-Binding of Cadmium Coordination Polymers with 3D Frameworks Constructed by Biphenyl-2, 4, 4′, 6-tetracarboxylic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(2): 259-266. doi: 10.11862/CJIC.2016.049 shu

Syntheses, Structures and DNA-Binding of Cadmium Coordination Polymers with 3D Frameworks Constructed by Biphenyl-2, 4, 4′, 6-tetracarboxylic Acid

YU Yu-Ye ^1,3 ,
SHEN Wei ¹ ,
WU Xiao-Yong ¹ ,
ZHAO Guo-Liang ^1,2,*,,

1.
College of Chemistry and Life Science, Zhejiang Normal University, Jinhua, Zhejiang 321004, China
2.
Xingzhi College, Zhejiang Normal University, Jinhua, Zhejiang 321004, China
3.
Jinhua Polytechnic, Jinhua, Zhejiang 321017, China

Corresponding author: ZHAO Guo-Liang, sky53@zjnu.cn
Received Date: 12 August 2015
Revised Date: 31 December 2015

Figures(7)

Two new cadmium coordination polymers, {[Cd₂(bptc)(H₂O)₃]·H₂O}_n (1) and {[Cd₂(bptc)(bpp)·H₂O]·2.25H₂O}_n (2), were synthesized under hydrothermal reactions by using biphenyl-2, 4, 4′, 6-tetracarboxylic acid (H₄bptc), CdCl₂·2.5H₂O and 1, 3-di (4-pyridyl) propane (bpp). Both of them were characterized by elemental analysis, IR spectra, single crystal X-ray diffraction. Complex 1 is a binuclear structure with two six-coordinated Cd (Ⅱ), both of which are distorted octahedral structures. The binuclear of Complex 2 is different. One Cd (Ⅱ) is distorted octahedral, and the other is seven-coordinated to form a pentagonal bipyramid. The interaction between two complexes, ligand and DNA was studied by EtBr fluorescence probe. Photoluminescence studies revealed that the interaction of complex 2 to the DNA is stronger than complex 1. CCDC: 952960, 1; 952962, 2.
- biphenyl-2, 4, 4′, 6-tetracarboxylic acid,
- cadmium coordination polymer,
- 1, 3-di (4-pyridyl) propane,
- DNA-binding
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沈阳化工大学材料科学与工程学院沈阳 110142

Syntheses, Structures and DNA-Binding of Cadmium Coordination Polymers with 3D Frameworks Constructed by Biphenyl-2, 4, 4′, 6-tetracarboxylic Acid

南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

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通讯作者: 陈斌, bchen63@163.com