Citation: HU Peng, WU Yan-Ni, HUANG Qi-Xiao, LIAN Si-Mian, FU Xing-Hui, HE Gao-Peng, CHEN Xia-Min. Gd (Ⅲ), Tb (Ⅲ) and Dy (Ⅲ) Complexes Based on a Nitronyl Nitroxide Radical: Syntheses, Structures and Magnetic Properties[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(2): 297-304. doi: 10.11862/CJIC.2016.032 shu

Gd (Ⅲ), Tb (Ⅲ) and Dy (Ⅲ) Complexes Based on a Nitronyl Nitroxide Radical: Syntheses, Structures and Magnetic Properties

College of Chemistry and Chemical Engineering, Zhaoqing University, Zhaoqing, Guangdong 526061, China

Corresponding author: HU Peng, hp8286799@zqu.edu.cn
Received Date: 20 June 2015
Revised Date: 1 December 2015

Figures(9)

One novel nitronyl nitroxide radical and its three mononuclear tri-spin compounds Ln (hfac)₃(NIT-Ph-4-OCHCH₃CH₃)₂ (Ln=Gd (1), Tb (2), Dy (3); hfac=hexafluoroacetylacetonate; NIT-Ph-4-OCHCH₃CH₃=2-(4-isopropoxyphenyl)-4, 4, 5, 5-tetramethyl-imidazoline-1-oxyl-3-oxide) have been successfully prepared and characterized. Single crystal X-ray crystallographic analyses reveal that complexes 1, 2, and 3 shows similar radical-Ln (Ⅲ)-radical structures, which ar composed of one Ln (hfac)₃ units and two NIT-Ph-4-OCHCH₃CH₃ radicals. Magnetic studies reveal that ferromagnetic interactions (between intramolecular Ln and radical) and antiferromagnetic interactions (between the intramolecular radicals) are coexist in these complexes. CCDC: 985443, 1; 1043098, 2; 985444, 3.
- nitronyl nitroxide radical,
- lanthanides,
- crystal structure,
- magnetic properties
1. [1]
  Kahn O. Molecular Magnetism. New York: Wiley-VCH, 1993.
2. [2]
  Moller S, Perlov C, Jackson W, et al. Nature, 2003, 426:166-169 doi: 10.1038/nature02070
3. [3]
  Kahn M L, Sutter J P, Golhen S, et al. J. Am. Chem. Soc., 2000, 122:3413-3421 doi: 10.1021/ja994175o
4. [4]
  Zhang P, Guo Y N, Tang J K. Coord. Chem. Rev., 2013, 257: 1728-1737 doi: 10.1016/j.ccr.2013.01.012
5. [5]
  Ruiz-Molina D, Mas-Torrent M, Gómez J, et al. Adv. Mater., 2003, 15:42-49 doi: 10.1002/(ISSN)1521-4095
6. [6]
  Clemente-León M, Soyer H, Coronado E, et al. Angew. Chem. Int. Ed., 1998, 37:2842-2845 doi: 10.1002/(ISSN)1521-3773
7. [7]
  Cornia A, Fabretti A C, Pacchioni M, L, et al. Angew. Chem. Int. Ed., 2003, 42:1645-1651 doi: 10.1002/anie.200350981
8. [8]
  Gatteschi D, Caneschi A, Pardi L, et al. Science, 1994, 265: 1054-1058 doi: 10.1126/science.265.5175.1054
9. [9]
  Bar A K, Pichon C, Gogoi N, et al. Chem. Commun., 2015, 51:3616-3619 doi: 10.1039/C4CC10182K
10. [10]
  Liu R N, Li L C, Wang X L, et al. Chem. Commun., 2010, 46:2566-2570 doi: 10.1039/b918554b
11. [11]
  Bogani L, Wernsdorfer W. Nat. Mater., 2008, 7:179-183 doi: 10.1038/nmat2133
12. [12]
  Caneschi A, Gatteschi D, Lalioti N, et al. Angew. Chem. Int. Ed., 2001, 40:1760-1793 doi: 10.1002/(ISSN)1521-3773
13. [13]
  Bogani L, Sangregorio C, Sessoli R, et al. Angew. Chem. Int. Ed., 2005, 44:5817-5821 doi: 10.1002/(ISSN)1521-3773
14. [14]
  Bernot K, Luzon J, Bogani L, et al. J. Am. Chem. Soc., 2009, 131:5573-5579 doi: 10.1021/ja8100038
15. [15]
  Liu J L, Wu J Y, Chen Y C, et al. Angew. Chem. Int. Ed., 2014, 53:12966-12970 doi: 10.1002/anie.201407799
16. [16]
  Chatelain L, Walsh J P S, Pecaut J, et al. Angew. Chem. Int. Ed., 2014, 53:13434-13439 doi: 10.1002/anie.201407334
17. [17]
  Zhang P, Zhang L, Wang C. J. Am. Chem. Soc., 2014, 136: 4484-4489 doi: 10.1021/ja500793x
18. [18]
  Poneti G, Bernot K, Bogani L, et al. Chem. Commun., 2007 1807-1809
19. [19]
  Rinehart J D, Fang M, Evans W J, et al. J. Am. Chem. Soc., 2011, 133:14236-14239 doi: 10.1021/ja206286h
20. [20]
  Rinehart J D, Fang M, Evans W J, et al. Nat. Chem., 2011, 3:538-542 doi: 10.1038/nchem.1063
21. [21]
  Chernick E T, Casillas R, Zirzlmeier J, et al. J. Am. Chem. Soc., 2015, 137:857-863 doi: 10.1021/ja510958k
22. [22]
  Mailman A, Winter S M, Wong J W L, et al. J. Am. Chem. Soc., 2015, 137:1044-1049 doi: 10.1021/ja512235h
23. [23]
  Wang X F, Hu P, Li Y G, et al. Chem. Asian J., 2015, 10: 325-330 doi: 10.1002/asia.v10.2
24. [24]
  Zhu M, Hu P, Li Y, et al. Chem. Eur. J., 2014, 20:13356-13364 doi: 10.1002/chem.201403581
25. [25]
  Wang Z X, Zhang X, Zhang Y Z, et al. Angew. Chem. Int. Ed., 2014, 53:11567-11570 doi: 10.1002/anie.201407628
26. [26]
  Ullman E F, Osiecki J H, Boocock D G B, et al. J. Am. Chem. Soc., 1972, 94:7049-7059 doi: 10.1021/ja00775a031
27. [27]
  Sheldrick G M. SHELXS-97: Program for the Solution of Crystal Structures, University of Göttingen, Germany, 1997.
28. [28]
  Sheldrick G M. SHELXL-97: Program for the Refinement of Crystal Structures, University of Göttingen, Germany, 1997.
29. [29]
  Hu P, Zhang C, Gao Y, et al. Inorg. Chim. Acta, 2013, 398: 136-140 doi: 10.1016/j.ica.2012.12.025
30. [30]
  Zhou N, Ma Y, Wang C, et al. Dalton Trans., 2009:8489-8492
31. [31]
  Wang C, Wang Y L, Qin Z X, et al. Inorg. Chem. Commun., 2012, 20:112-117 doi: 10.1016/j.inoche.2012.02.030
32. [32]
  Zhang C X, Chen H W, Wang W M, et al. Inorg. Chem. Commun., 2012, 24:177-181 doi: 10.1016/j.inoche.2012.07.003
33. [33]
  Du F X, Hu P, Gao Y Y, et al. Inorg. Chem. Commun., 2014, 48:166-170 doi: 10.1016/j.inoche.2014.08.035
34. [34]
  Zhang C X, Qiao X M, Kong Y K, et al. J. Mol. Struct., 2015, 108:1348-1354
35. [35]
  Li L L, Liu S, Zhang Y, et al. Dalton Trans., 2015, 44:6118-6125 doi: 10.1039/C4DT03941F
1. [1]
  Xiaoling WANG , Hongwu ZHANG , Daofu LIU . Synthesis, structure, and magnetic property of a cobalt(Ⅱ) complex based on pyridyl-substituted imino nitroxide radical. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 407-412. doi: 10.11862/CJIC.20240214
2. [2]
  Lulu DONG , Jie LIU , Hua YANG , Yupei FU , Hongli LIU , Xiaoli CHEN , Huali CUI , Lin LIU , Jijiang WANG . Synthesis, crystal structure, and fluorescence properties of Cd-based complex with pcu topology. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 809-820. doi: 10.11862/CJIC.20240171
3. [3]
  Xiaoxia WANG , Ya'nan GUO , Feng SU , Chun HAN , Long SUN . Synthesis, structure, and electrocatalytic oxygen reduction reaction properties of metal antimony-based chalcogenide clusters. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1201-1208. doi: 10.11862/CJIC.20230478
4. [4]
  Kaimin WANG , Xiong GU , Na DENG , Hongmei YU , Yanqin YE , Yulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009
5. [5]
  Yao HUANG , Yingshu WU , Zhichun BAO , Yue HUANG , Shangfeng TANG , Ruixue LIU , Yancheng LIU , Hong LIANG . Copper complexes of anthrahydrazone bearing pyridyl side chain: Synthesis, crystal structure, anticancer activity, and DNA binding. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 213-224. doi: 10.11862/CJIC.20240359
6. [6]
  Jia JI , Zhaoyang GUO , Wenni LEI , Jiawei ZHENG , Haorong QIN , Jiahong YAN , Yinling HOU , Xiaoyan XIN , Wenmin WANG . Two dinuclear Gd(Ⅲ)-based complexes constructed by a multidentate diacylhydrazone ligand: Crystal structure, magnetocaloric effect, and biological activity. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 761-772. doi: 10.11862/CJIC.20240344
7. [7]
  Lu LIU , Huijie WANG , Haitong WANG , Ying LI . Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1180-1188. doi: 10.11862/CJIC.20230489
8. [8]
  Xiumei LI , Yanju HUANG , Bo LIU , Yaru PAN . Syntheses, crystal structures, and quantum chemistry calculation of two Ni(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 2031-2039. doi: 10.11862/CJIC.20240109
9. [9]
  Xiumei LI , Linlin LI , Bo LIU , Yaru PAN . Syntheses, crystal structures, and characterizations of two cadmium(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 613-623. doi: 10.11862/CJIC.20240273
10. [10]
  Chao LIU , Jiang WU , Zhaolei JIN . Synthesis, crystal structures, and antibacterial activities of two zinc(Ⅱ) complexes bearing 5-phenyl-1H-pyrazole group. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1986-1994. doi: 10.11862/CJIC.20240153
11. [11]
  Yan XU , Suzhi LI , Yan LI , Lushun FENG , Wentao SUN , Xinxing LI . Structure variation of cadmium naphthalene-diphosphonates with the changing rigidity of N-donor auxiliary ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 395-406. doi: 10.11862/CJIC.20240226
12. [12]
  Huan ZHANG , Jijiang WANG , Guang FAN , Long TANG , Erlin YUE , Chao BAI , Xiao WANG , Yuqi ZHANG . A highly stable cadmium(Ⅱ) metal-organic framework for detecting tetracycline and p-nitrophenol. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 646-654. doi: 10.11862/CJIC.20230291
13. [13]
  Ruikui YAN , Xiaoli CHEN , Miao CAI , Jing REN , Huali CUI , Hua YANG , Jijiang WANG . Design, synthesis, and fluorescence sensing performance of highly sensitive and multi-response lanthanide metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 834-848. doi: 10.11862/CJIC.20230301
14. [14]
  Meirong HAN , Xiaoyang WEI , Sisi FENG , Yuting BAI . A zinc-based metal-organic framework for fluorescence detection of trace Cu²⁺. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1603-1614. doi: 10.11862/CJIC.20240150
15. [15]
  Shuyan ZHAO . Field-induced Co^Ⅱ single-ion magnet with pentagonal bipyramidal configuration. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1583-1591. doi: 10.11862/CJIC.20240231
16. [16]
  Yinling HOU , Jia JI , Hong YU , Xiaoyun BIAN , Xiaofen GUAN , Jing QIU , Shuyi REN , Ming FANG . A rhombic Dy₄-based complex showing remarkable single-molecule magnet behavior. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 605-612. doi: 10.11862/CJIC.20240251
17. [17]
  Hongdao LI , Shengjian ZHANG , Hongmei DONG . Magnetic relaxation and luminescent behavior in nitronyl nitroxide-based annuluses of rare-earth ions. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 972-978. doi: 10.11862/CJIC.20230411
18. [18]
  Xiaxia LIU , Xiaofang MA , Luxia GUO , Xianda HAN , Sisi FENG . Structure and magnetic properties of Mn(Ⅱ) coordination polymers regulated by N-auxiliary ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 587-596. doi: 10.11862/CJIC.20240269
19. [19]
  Zhaodong WANG . In situ synthesis, crystal structure, and magnetic characterization of a trinuclear copper complex based on a multi-substituted imidazo[1,5-a]pyrazine scaffold. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 597-604. doi: 10.11862/CJIC.20240268
20. [20]
  Shenhao QIU , Qingquan XIAO , Huazhu TANG , Quan XIE . First-principles study on electronic structure, optical and magnetic properties of rare earth elements X (X=Sc, Y, La, Ce, Eu) doped with two-dimensional GaSe. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2250-2258. doi: 10.11862/CJIC.20240104

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(245)
HTML views(12)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142