Citation: LI Zhong-Feng, ZHANG Zhen-Wei, CUI Yang-Zhe, LIU Min, YANG Yu-Ping, JIN Qiong-Hua. Syntheses, Characterizations and Crystal Structures of Two Kinds of Silver (Ⅰ) Complexes Derived from Thiol Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(1): 139-144. doi: 10.11862/CJIC.2016.023 shu

Syntheses, Characterizations and Crystal Structures of Two Kinds of Silver (Ⅰ) Complexes Derived from Thiol Ligand

1.
Department of Chemistry, Capital Normal University, Beijing 100048, China
2.
Department of Physics, Capital Normal University, Beijing 100048, China
3.
The College of Materials Scienceand Engineering, Beijing University of Technology, Beijing 100124, China
4.
School of Science, Minzu University of China, Beijing 100081, China

Corresponding author: JIN Qiong-Hua, jinqh@cnu.edu.cn
Received Date: 19 August 2015
Revised Date: 11 November 2015

Figures(4)

Two kinds of complexes [AgCl (PPh₃)₂(BTZT)]·CH₃OH (1) and [AgCl (PPh₃)₂(BTZT)]₂ (2) were obtained by the reaction of AgCl, PPh₃, and MBT in 1:2:1 molar ratio (PPh₃=triphenylphosphine; MBT=2-mercaptobenzo-thiazole BTZT=benzothiazoline-2-thione) (2 has been reported). [AgBr (PPh₃)₂(BTZT)]·CH₃OH (3) and [AgBr (PPh₃)₂(BTZT)]₂ (4) were prepared in a manner similar to 1 and 2 using AgBr (4 has been reported). Complexes 1 and 3 have been characterized by IR, elemental analysis, ¹H NMR spectroscopy, fluorescence spectrum and single-crystal X-ray diffraction. The MBT ligand can transform into the BTZT ligand in different chemical environment because of its chemically active groups. The luminescent spectra show that emission peaks of 1 and 3 are assigned to the ligand centered π-π^* transition. CCDC: 1407305, 1; 1407306, 3.
- triphenylphosphine,
- 2-mercaptobenzothiazole,
- benzothiazoline-2-thione,
- complex
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沈阳化工大学材料科学与工程学院沈阳 110142