Citation: ZHAO Hai-Tao, LIU Rui-Ping, ZHANG Qiang, WANG Qiao, MA Rui-Ting. Synthesis and Magnetocaloric Effect of Monodisperse Ni_xZn_1-xFe₂O₄ Nanoparticles[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(1): 63-68. doi: 10.11862/CJIC.2016.015 shu

Synthesis and Magnetocaloric Effect of Monodisperse Ni_xZn_1-xFe₂O₄ Nanoparticles

School of Materials Science and Engineering, Shenyang Ligong University, Shenyang 110159, China

Corresponding author: ZHAO Hai-Tao, zht95711@163.com
Received Date: 8 July 2015
Revised Date: 16 October 2015

Figures(6)

Ni_1-xZn_xFe₂O₄ ferrites (x=0, 0.3, 0.5, 0.7 and 1.0) nanoparticles have been achieved by the polyol process using triethylene glycol as a solvent and acetylacetonate metal salts as precursors. The structure, morphology, magnetic properties and magnetocaloric effect under alternating magnetic field of resultant particles were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM) and vibrating sample magnetometry (VSM). The results show that NiZn ferrites nanoparticles have uniform size and good dispersibility with approximate spherical shape. The average sizes are about 4~5 nm. The monodisperse Ni_xZn_1-xFe₂O₄ nano-particles show a typical ferrimagnetic behavior at room temperature. The saturation magnetization increases and then decreases with the increase of Ni²⁺ concentration. The maximum saturation magnetization with concentration of Ni²⁺ up to x=0.5 is determined to be 29.38 emu·g^-1. The temperature of Ni_0.5Zn_0.5Fe₂O₄ ferrites can reach up to 313 K under a 382 kHz magnetic field which reveals its sufficient heating ability.
- NiZn ferrites,
- polyol process,
- magnetic properties,
- magnetocaloric effect
1. [1]
  XING Zhen-Zhen, ZHU Hong. Mater. Rev., 2010, 24(5):63-66
2. [2]
  YAO Ai-Hua, WANG De-Ping, HUANG Wen-Hai, et al. J. Inorg. Mater., 2007, 22(2):201-204
3. [3]
  ZHANG Lin, WANG De-Ping, YAO Ai-Hua, et al. Funct. Mater., 2007, 38(7):1085-1088
4. [4]
  Afkhami A, Sayari S, Moosavi R, et al. J. Ind. Eng. Chem., 2015, 21:920-924 doi: 10.1016/j.jiec.2014.04.033
5. [5]
  Lazarević Z Ž Milutinović A N, Jovalekić Č D, et al. Mater. Res. Bull., 2015, 63:239-247 doi: 10.1016/j.materresbull.2014.12.005
6. [6]
  Kumbhar S S, Mahadik M A, Mohite V S, et al. Mater. Res. Bull., 2015, 67:47-54 doi: 10.1016/j.materresbull.2015.02.056
7. [7]
  Sun M M, Zhu A M, Zhang Q G, et al. J. Magn. Magn. Mater., 2014, 369:49-54 doi: 10.1016/j.jmmm.2014.06.013
8. [8]
  Zhang Q, Zhu M F, Zhang Q H, et al. J. Magn. Magn. Mater., 2009, 321:3203-3206 doi: 10.1016/j.jmmm.2009.05.049
9. [9]
  Kumar S, Singh V, Aggarwal S, et al. J. Magn. Magn. Mater., 2012, 324:3683-3689 doi: 10.1016/j.jmmm.2012.05.048
10. [10]
  Shi R R, Liu X H, Gao G H, et al. J. Alloys Compd., 2009, 485:548-553 doi: 10.1016/j.jallcom.2009.06.024
11. [11]
  Tahar L B, M′Nasri W, Smiri L S, et al. Mater. Lett., 2013, 113:198-201 doi: 10.1016/j.matlet.2013.09.055
12. [12]
  Kumar S, Kumar P, Singh V, et al. J. Magn. Magn. Mater., 2015, 379:50-57 doi: 10.1016/j.jmmm.2014.12.006
13. [13]
  Shinde T J, Gadkari A B, Vasambekar P N. J. Magn. Magn. Mater., 2013, 333:152-155 doi: 10.1016/j.jmmm.2012.12.049
14. [14]
  Gabal M A, El-Shishtawy R M, Al Angari Y M. J. Magn. Magn. Mater., 2012, 324:2258-2264 doi: 10.1016/j.jmmm.2012.02.112
15. [15]
  Gao J M, Yan Z K, Liu J, et al. Mater. Lett., 2015, 141:122-124 doi: 10.1016/j.matlet.2014.11.062
16. [16]
  Chavan S M, Babrekar M K, More S S, et al. J. Alloys Compd., 2010, 507:21-25 doi: 10.1016/j.jallcom.2010.07.171
17. [17]
  Chen F H, Zhao T N, Chen Q T, et al. Mater. Res. Bull., 2013, 48:4093-4099 doi: 10.1016/j.materresbull.2013.06.027
18. [18]
  Gabal M A, Kosa S, Mutairi T S Al. J. Mol. Struct., 2014, 1063:269-273 doi: 10.1016/j.molstruc.2014.01.070
19. [19]
  Surinwong S, Rujiwatra A. Particuology, 2013, 11:588-593 doi: 10.1016/j.partic.2012.06.008
20. [20]
  Hassan A, Khan M A, Shahid M, et al. J. Magn. Magn. Mater., 2015, 393:56-61 doi: 10.1016/j.jmmm.2015.05.033
21. [21]
  Patange S M, Shirsath S E, Toksha B G, et al. J. Appl. Phys, 2009, 106:0239141-7
22. [22]
  ZHANG Xiao-Chuan, WANG De-Ping, YAO Ai-Hua, et al. J. Inorg. Mater., 2008, 23(4):677-682 doi: 10.3724/SP.J.1077.2008.00677
1. [1]
  Siyu HOU , Weiyao LI , Jiadong LIU , Fei WANG , Wensi LIU , Jing YANG , Ying ZHANG . Preparation and catalytic performance of magnetic nano iron oxide by oxidation co-precipitation method. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1577-1582. doi: 10.11862/CJIC.20230469
2. [2]
  Qianqian Zhong , Yucui Hao , Guotao Yu , Lijuan Zhao , Jingfu Wang , Jian Liu , Xiaohua Ren . Comprehensive Experimental Design for the Preparation of the Magnetic Adsorbent Based on Enteromorpha Prolifera and Its Utilization in the Purification of Heavy Metal Ions Wastewater. University Chemistry, 2024, 39(8): 184-190. doi: 10.3866/PKU.DXHX202312013
3. [3]
  Weikang Wang , Yadong Wu , Jianjun Zhang , Kai Meng , Jinhe Li , Lele Wang , Qinqin Liu . Green H₂O₂ synthesis via melamine-foam supported S-scheme Cd_0.5Zn_0.5In₂S₄/S-doped carbon nitride heterojunction: synergistic interfacial charge transfer and local photothermal effect. Acta Physico-Chimica Sinica, 2025, 41(8): 100093-0. doi: 10.1016/j.actphy.2025.100093
4. [4]
  Chao Liu , Huan Yu , Jiaming Li , Xi Yu , Zhuangzhi Yu , Yuxi Song , Feng Zhang , Qinfang Zhang , Zhigang Zou . 具有光热效应的多级Ti₃C₂/Bi₁₂O₁₇Br₂肖特基异质结简单合成及其太阳能驱动抗生素光降解的研究. Acta Physico-Chimica Sinica, 2025, 41(7): 100075-0. doi: 10.1016/j.actphy.2025.100075
5. [5]
  Yipeng Zhou , Chenxin Ran , Zhongbin Wu . Metacognitive Enhancement in Diversifying Ideological and Political Education within Graduate Course: A Case Study on “Solar Cell Performance Enhancement Technology”. University Chemistry, 2024, 39(6): 151-159. doi: 10.3866/PKU.DXHX202312096
6. [6]
  Zhike Yang , Jinfan Xu , Junhao Chen , Zheng Yang , Fei Ding , Neil Qiang Su . AI NMR Assistant: A DP5-Based Intelligent System for NMR Spectral Interpretation. University Chemistry, 2026, 41(1): 20-28. doi: 10.12461/PKU.DXHX202506013
7. [7]
  Tengyue ZHANG , Jingjing FENG , Zili LIANG , Jia′nan DAI , Jing MA . Optimization of C-doped BiVO₄ performance for tetracycline degradation using response surface methodology-assisted orthogonal experiments. Chinese Journal of Inorganic Chemistry, 2025, 41(12): 2561-2574. doi: 10.11862/CJIC.20250104
8. [8]
  Gengyuan Li , Yexin Wang , Song Gao , Shangda Jiang . Advances in Light-Induced Spin Polarization of Magnetic Molecules. University Chemistry, 2025, 40(12): 87-94. doi: 10.12461/PKU.DXHX202509112
9. [9]
  Kaimin WANG , Na HE , Shiyi LI , Xuling BAI , Weiqing SUN , Yanqing YE , Yulu MA . Synthesis, Hirshfeld surface analysis and properties of two Zn(Ⅱ)/Ni(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2026, 42(1): 55-64. doi: 10.11862/CJIC.20250178
10. [10]
  Jin CHANG . Supercapacitor performance and first-principles calculation study of Co-doping Ni(OH)₂. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1697-1707. doi: 10.11862/CJIC.20240108
11. [11]
  Jianqiao ZHANG , Yang LIU , Yan HE , Yaling ZHOU , Fan YANG , Shihui CHENG , Bin XIA , Zhong WANG , Shijian CHEN . Ni-doped WP₂ nanowire self-standingelectrode: Preparation and alkaline electrocatalytic hydrogen evolution property. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1610-1616. doi: 10.11862/CJIC.20240444
12. [12]
  Feng Lin , Zhongxin Jin , Caiying Li , Cheng Shao , Yang Xu , Fangze Li , Siqi Liu , Ruining Gu . Preparation and Electrochemical Properties of Nickel Foam-Supported Ni(OH)₂-NiMoO₄ Electrode Material. University Chemistry, 2025, 40(10): 225-232. doi: 10.12461/PKU.DXHX202412017
13. [13]
  Cheng PENG , Jianwei WEI , Yating CHEN , Nan HU , Hui ZENG . First principles investigation about interference effects of electronic and optical properties of inorganic and lead-free perovskite Cs₃Bi₂X₉ (X=Cl, Br, I). Chinese Journal of Inorganic Chemistry, 2024, 40(3): 555-560. doi: 10.11862/CJIC.20230282
14. [14]
  Tieping CAO , Yuejun LI , Dawei SUN . Surface plasmon resonance effect enhanced photocatalytic CO₂ reduction performance of S-scheme Bi₂S₃/TiO₂ heterojunction. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 903-912. doi: 10.11862/CJIC.20240366
15. [15]
  Xin XIONG , Qian CHEN , Quan XIE . First principles study of the photoelectric properties and magnetism of La and Yb doped AlN. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1519-1527. doi: 10.11862/CJIC.20240064
16. [16]
  Siyi ZHONG , Xiaowen LIN , Jiaxin LIU , Ruyi WANG , Tao LIANG , Zhengfeng DENG , Ao ZHONG , Cuiping HAN . Targeting imaging and detection of ovarian cancer cells based on fluorescent magnetic carbon dots. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1483-1490. doi: 10.11862/CJIC.20240093
17. [17]
  Zhiyang Li , Hui Deng , Xinqi Cai , Zhuo Chen . Magnetic Core/Shell-Capsules Locally Neutralize Gastric Acid for Efficient Delivery of Active Probiotics. Acta Physico-Chimica Sinica, 2024, 40(7): 2306051-0. doi: 10.3866/PKU.WHXB202306051
18. [18]
  Youlin SI , Shuquan SUN , Junsong YANG , Zijun BIE , Yan CHEN , Li LUO . Synthesis and adsorption properties of Zn(Ⅱ) metal-organic framework based on 3, 3', 5, 5'-tetraimidazolyl biphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1755-1762. doi: 10.11862/CJIC.20240061
19. [19]
  Qingyun Yang , Yue Ma , Quanyi Ye , Yiqing Liu , Yuhong Luo , Yongbo Wu , Zhiguang Xu , Xiaoming Lin . Prussian blue analogues derived MO/MFe2O4 (M = Ni, Cu, Zn) nanoparticles as a high-performance anode material for enhanced lithium storage. Chinese Journal of Structural Chemistry, 2025, 44(8): 100631-100631. doi: 10.1016/j.cjsc.2025.100631
20. [20]
  Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga₂O₃ coated modification and electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(926)
HTML views(147)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis and Magnetocaloric Effect of Monodisperse NixZn1-xFe2O4 Nanoparticles

Metrics

通讯作者: 陈斌, bchen63@163.com

Synthesis and Magnetocaloric Effect of Monodisperse Ni_xZn_1-xFe₂O₄ Nanoparticles