Citation: MAO Pan-Dong, HAN Xue-Feng, WU Wei-Na, WANG Guan-Jie, WANG Zhen, HOU Ying. Ni (Ⅱ) and Cd (Ⅱ) Complexes with a Schiff Base Ligand Derived from 2-Acetyl Pyrazine and Methyl Hydrazinocarboxylate: Crystal Structures and Fluorescence Properties[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(1): 161-166. doi: 10.11862/CJIC.2016.008 shu

Ni (Ⅱ) and Cd (Ⅱ) Complexes with a Schiff Base Ligand Derived from 2-Acetyl Pyrazine and Methyl Hydrazinocarboxylate: Crystal Structures and Fluorescence Properties

MAO Pan-Dong ¹ ,
HAN Xue-Feng ^2,*,, ,
WU Wei-Na ^1,*,, ,
WANG Guan-Jie ¹ ,
WANG Zhen ¹ ,
HOU Ying ¹

1.
Department of Physics and Chemistry, Henan Polytechnic University, Jiaozuo, Henan 454000, China
2.
Personnel Services, Henan Polytechnic University, Jiaozuo, Henan 454000, China

Corresponding author: HAN Xue-Feng, 108242720@qq.com WU Wei-Na, wuwn08@hpu.edu.cn
Received Date: 15 September 2015
Revised Date: 25 October 2015

Figures(5)

Two complexes, namely [Ni (L)₂] (1) and [Cd (HL)(CH₃OH)(NO₃)₂] (2) (HL is derived from 2-acetyl pyrazine and methyl hydrazinocarboxylate) have been synthesized and characterized by single-crystal X-ray diffraction, elemental analysis and IR spectroscopy. X-ray diffraction analysis results show that the central Ni (Ⅱ) ion in complex 1 is surrounded by two independent anionic ligands with N₂O donor set, thus possesses a distorted octahedral coordination geometry. However, in complex 2, the Cd (Ⅱ) ion with bicapped-triangular prism geometry is coordinated with one neutral ligand HL, two bidentate nitrate anions and one methanol molecule. In addition, the thermal stability and luminescent properties of the complexes are also studied in detail. CCDC: 1424257, 1; 1424258, 2.
- methyl hydrazinocarboxylate,
- pyrazine,
- fluorescence,
- crystal structure,
- thermostability
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沈阳化工大学材料科学与工程学院沈阳 110142