Citation: LU Ning-Yue, ZHOU Fan, FAN Bin-Bin, LI Rui-Feng. Pt/MIL-101(Cr) for the Selective Hydrogenation of Cinnamaldehyde to Cinnamyl Alcohol[J]. Chinese Journal of Inorganic Chemistry, ;2015, (12): 2324-2330. doi: 10.11862/CJIC.2015.314 shu

Pt/MIL-101(Cr) for the Selective Hydrogenation of Cinnamaldehyde to Cinnamyl Alcohol

1.
Institute of Special Chemicals, Taiyuan University of Technology, Taiyuan 030024, China

Corresponding author: FAN Bin-Bin,
Received Date: 11 June 2015
Available Online: 20 October 2015
Fund Project: 国家自然科学基金(No.20971095,21576177) (No.20971095,21576177)山西省回国留学人员科研资助项目(No.2013-047)资助。 (No.2013-047)

MIL-101(Cr) supported Pt nanoparticles (Pt/MIL-101(Cr)) catalyst was prepared by a facile impregna-tion method and used as an efficient catalyst for selective hydrogenation of cinnamaldehyde (CAL). The results of XRD, TEM and N₂ adsorption and catalytic evaluation showed that Pt loadings greatly influenced the size of the supported nanoparticles on MIL-101(Cr) and the selectivity to cinnamyl alcohol (COL). Pt/MIL-101(Cr) catalyst with a low Pt loading (1.0%) exhibited much higher catalytic activity and COL selectivity in the selective hydrogenation of CAL as compared with Pt nanoparticles supported on other MOFs or inorganic supports, and its activity and selectivity to COL can reach 96.5% and 86.2% under optimized reaction conditions, respectively. The prepared Pt/MIL-101(Cr) catalyst is stable and can be reused at least five times without significant loss in the activity and selectivity. The excellent catalytic performance of Pt/MIL-101(Cr) is greatly related with the unique structure and surface property of MIL-101(Cr) support.
- heterogeneous catalysis;selective hydrogenation;cinnamaldehyde;MIL-101(Cr);Pt nanoparticles
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沈阳化工大学材料科学与工程学院沈阳 110142