Citation: SHI Wei-Dong, ZHENG De-Hua, WANG Mei. Preparation and Crystal Structures of Cobalt and Nickel Complexes Containing a Pyridine-Amine Polydentate Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2015, (11): 2205-2212. doi: 10.11862/CJIC.2015.297 shu

Preparation and Crystal Structures of Cobalt and Nickel Complexes Containing a Pyridine-Amine Polydentate Ligand

1.
State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian, Liaoning 116024, China

Corresponding author: ZHENG De-Hua,
Received Date: 6 July 2015
Available Online: 21 September 2015
Fund Project: 国家自然科学基金(No.21373040)资助项目。 (No.21373040)

Four new cobalt and nickel complexes containing a polypyridine-amine ligand were designed and prepared, namely, [M(L1)](BF₄)₂ (L1=N,N,N',N'-tetrakis(2-pyridylmethyl)ethane-1,2-diamine; C1, M=Co; C2, M=Ni) and [M(L2)](BF₄)_n (L2=N,N,N',N'-tetrakis(2-pyridylmethyl)propane-1,3-diamine; C3 M=Co, n=3; C4, M=Ni, n=2). These complexes were characterized by infrared spectroscopy (IR) and element analysis (EA). The structures of the complexes were determined by X-ray single crystal diffraction. The four complexes all belong to the monoclinic crystal system but with different space groups (C1, Cc; C2, P2₁/n; C3, C2/c; C4, P2₁/c). Different three-dimensional packing structures were found for these complexes.
- pyridine-amine polydentate ligand;cobalt complex;nickel complex;crystal structure
1. [1]
  [1] ZHANG Feng-Bo(张峰博). Thesis for the Master of Dalian University of Technology(大连理工大学硕士论文). 2011.
2. [2]
  [2] Thoi V S, Sun Y, Long J R, et al. Chem. Soc. Rev., 2013,42: 2388-2400
3. [3]
  [3] Karunadasa H I, Chang C J, Long J R. Nature, 2010,464: 1329-1333
4. [4]
  [4] Karunadasa H I, Montalvo E, Sun Y. Science, 2012,335:698-702
5. [5]
  [5] Bigi J P, Hanna T E, Harman W H, et al. Chem. Commun., 2010,46:958-960
6. [6]
  [6] Sun Y, Bigi J P, Piro N A, et al. J. Am. Chem. Soc., 2011, 133:9212-9215
7. [7]
  [7] Stubbert B D, Peters J C, Gray H B. J. Am. Chem. Soc., 2011,133:18070-18073
8. [8]
  [8] Singh W M, Baine T, Kudo S, et al. Angew. Chem. Int. Ed., 2012,51:5941-5944
9. [9]
  [9] Zhang P L, Wang M, Gloaguan F, et al. Chem. Commun., 2013,49:9455-9457
10. [10]
  [10] Zhang P L, Wang M, Yang Y, et al. Chem. Commun., 2014, 50:14153-14156
11. [11]
  [11] Goldsmith J, Hudson W, Lowry M, et al. J. Am. Chem. Soc., 2005,127:7502-7510
12. [12]
  [12] Fisher B J, Eisenberg R. J. Am. Chem. Soc., 1980,102:7361-7363
13. [13]
  [13] Collin J P, Jouaiti A, Sauvage J P. Inorg. Chem., 1988,27: 1986-1990
14. [14]
  [14] Eriksen J, Goodson P, Hazell A, et al. Acta Chem. Scand., 1999,53:1083-1092
15. [15]
  [15] Masakazu T, Yasuteru U, Kazuya K, et al. J. Organomet. Chem., 2000,611:586-592
16. [16]
  [16] Software Packages SMART and SAINT, Siemens Energy & Automation Inc., Madison, Wisconsin USA, 1996.
17. [17]
  [17] Sheldrick G M. SHELXS-97, Program for the Refinement of Crystal Structure, University of Göttingen, Germany, 1997.
18. [18]
  [18] Spek A L. PLATON, Utrecht University, Utrecht, the Netherlands, 1998.
1. [1]
  Keweiyang Zhang , Zihan Fan , Liyuan Xiao , Haitao Long , Jing Jing . Unveiling Crystal Field Theory: Preparation, Characterization, and Performance Assessment of Nickel Macrocyclic Complexes. University Chemistry, 2024, 39(5): 163-171. doi: 10.3866/PKU.DXHX202310084
2. [2]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
3. [3]
  Changqing MIAO , Fengjiao CHEN , Wenyu LI , Shujie WEI , Yuqing YAO , Keyi WANG , Ni WANG , Xiaoyan XIN , Ming FANG . Crystal structures, DNA action, and antibacterial activities of three tetranuclear lanthanide-based complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2455-2465. doi: 10.11862/CJIC.20240192
4. [4]
  Jing WU , Puzhen HUI , Huilin ZHENG , Pingchuan YUAN , Chunfei WANG , Hui WANG , Xiaoxia GU . Synthesis, crystal structures, and antitumor activities of transition metal complexes incorporating a naphthol-aldehyde Schiff base ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2422-2428. doi: 10.11862/CJIC.20240278
5. [5]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
6. [6]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
7. [7]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
8. [8]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
9. [9]
  Linjie ZHU , Xufeng LIU . Electrocatalytic hydrogen evolution performance of tetra-iron complexes with bridging diphosphine ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 321-328. doi: 10.11862/CJIC.20240207
10. [10]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173
11. [11]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
12. [12]
  Jinfeng Chu , Lan Jin , Yu-Fei Song . Exploration and Practice of Flipped Classroom in Inorganic Chemistry Experiment: a Case Study on the Preparation of Inorganic Crystalline Compounds. University Chemistry, 2024, 39(2): 248-254. doi: 10.3866/PKU.DXHX202308016
13. [13]
  Yan Liu , Yuexiang Zhu , Luhua Lai . Introduction to Blended and Small-Class Teaching in Structural Chemistry: Exploring the Structure and Properties of Crystals. University Chemistry, 2024, 39(3): 1-4. doi: 10.3866/PKU.DXHX202306084
14. [14]
  Weina Wang , Fengyi Liu , Wenliang Wang . “Extracting Commonality, Delving into Typicals, Deriving Individuality”: Constructing a Knowledge Graph of Crystal Structures. University Chemistry, 2024, 39(3): 36-42. doi: 10.3866/PKU.DXHX202308029
15. [15]
  Junqiao Zhuo , Xinchen Huang , Qi Wang . Symbol Representation of the Packing-Filling Model of the Crystal Structure and Its Application. University Chemistry, 2024, 39(3): 70-77. doi: 10.3866/PKU.DXHX202311100
16. [16]
  Wenyan Dan , Weijie Li , Xiaogang Wang . The Technical Analysis of Visual Software ShelXle for Refinement of Small Molecular Crystal Structure. University Chemistry, 2024, 39(3): 63-69. doi: 10.3866/PKU.DXHX202302060
17. [17]
  Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
18. [18]
  Liyang ZHANG , Dongdong YANG , Ning LI , Yuanyu YANG , Qi MA . Crystal structures, luminescent properties and Hirshfeld surface analyses of three cadmium(Ⅱ) complexes based on 2-(3-(pyridin-2-yl)-1H-pyrazol-1-yl)benzoate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1943-1952. doi: 10.11862/CJIC.20240079
19. [19]
  Xiaoling WANG , Hongwu ZHANG , Daofu LIU . Synthesis, structure, and magnetic property of a cobalt(Ⅱ) complex based on pyridyl-substituted imino nitroxide radical. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 407-412. doi: 10.11862/CJIC.20240214
20. [20]
  Qiaowen CHANG , Ke ZHANG , Guangying HUANG , Nuonan LI , Weiping LIU , Fuquan BAI , Caixian YAN , Yangyang FENG , Chuan ZUO . Syntheses, structures, and photo-physical properties of iridium phosphorescent complexes with phenylpyridine derivatives bearing different substituting groups. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 235-244. doi: 10.11862/CJIC.20240311

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(698)
HTML views(107)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142