Citation: LI Xiao-Jing, XU Zhou-Qing, XU Jun, WU Wei-Na, FAN Yun-Chang. Cu(Ⅱ), Zn(Ⅱ) and Cd(Ⅱ) Complexes with Picolinamide Azine Derived from 2-Acetyl Pyridine and 2-Picolinamide Hydrazone: Crystal Structures and Fluorescence Properties[J]. Chinese Journal of Inorganic Chemistry, ;2015, (12): 2418-2424. doi: 10.11862/CJIC.2015.292 shu

Cu(Ⅱ), Zn(Ⅱ) and Cd(Ⅱ) Complexes with Picolinamide Azine Derived from 2-Acetyl Pyridine and 2-Picolinamide Hydrazone: Crystal Structures and Fluorescence Properties

1.
Department of Physics and Chemistry, Henan Polytechnic University, Jiaozuo, Henan 454000, China

Corresponding author: XU Jun, FAN Yun-Chang,
Received Date: 16 July 2015
Available Online: 13 September 2015
Fund Project: 国家自然科学基金(No.21404033, 21401046, 21001040) (No.21404033, 21401046, 21001040) 河南省教育厅自然科学基金(No.12B150011, 14B150029)资助项目。 (No.12B150011, 14B150029)

Three complexes [(Cu)(L)(Cl)₂](1), [(Zn)(L)(Cl)₂](2) and {[(Cd)₂(L)(I)₄]}_n(3) (L is derived from 2-acetyl pyridine and picolinamide hydrazone) have been synthesized and characterized by single-crystal X-ray diffraction, elemental analysis and IR spectroscopy. X-ray diffraction analysis results show that complexes 1 and 2 are isostructural. The coordination geometry of the metal ion in each complex is a distorted trigonal biyramid with three nitrogen atoms from the ligand L and two chloride anions. However, in complex 3, two adjacent five-coordinated Cd(Ⅱ) ion are connected by two bridged μ₂-I^- anions, resulting in the formation of one-dimensional chain along c axis. In addition, the thermal stability and luminescent properties of the complexes are also studied in detail.
- picolinamide azine;complex ;fluorescence;crystal structure;thermostability
1. [1]
  [1] HUANG Chao(黄超), WU Juan(吴娟), CHEN Dong-Mei (陈冬梅), et al. Chinese J. Inorg. Chem. (无机化学学报), 2015,31:109-113
2. [2]
  [2] CHEN Yan-Min(陈延民), XIE Qing-Fan(解庆范), LIU Jin- Hua(刘金花), et al. Chinese J. Inorg. Chem. (无机化学学报), 2015,31:74-80
3. [3]
  [3] CHEN Yan-Min(陈延民), CHU Zhao-Hua(储召华), HAO Gui-Xia(郝桂霞), et al. Chinese J. Inorg. Chem. (无机化学学报), 2015,31:317-322
4. [4]
  [4] CHEN Xiao-Hua(陈小华), WU Qiong-Jie(吴琼洁), Lü Wei (吕玮), et al. Chinese J. Inorg. Chem. (无机化学学报), 2013,29:1521-1526
5. [5]
  [5] LI Shi-Xiong(李石雄), LIAO Bei-Ling(廖蓓玲), LUO Pei (罗培), et al. Chinese J. Inorg. Chem. (无机化学学报), 2015,31:291-296
6. [6]
  [6] Yang Z Y, Yang R D, Li F S, et al. Polyhedron, 2000,19: 2599-2604
7. [7]
  [7] Yang Z Y, Wang B D, Li Y H, J. Organomet. Chem., 2006,691:4159-4166
8. [8]
  [8] Wang Y, Yang Z Y. Transition Met. Chem., 2005,30:902-906
9. [9]
  [9] Zhou X Y, Li P X, Shi Z H, et al. Inorg. Chem., 2012,51: 9226-9231
10. [10]
  [10] Wu Z K, Chen Q Q, Yang G Q, et al. Sens. Actuators B, 2004,99:511-515
11. [11]
  [11] Zhang G Q, Yang G Q, Zhu L N, et al. Sens. Actuators B, 2006,114:995-1000
12. [12]
  [12] Sali S, Grabchev I, Chovelon J M, et al. Spectrochim. Acta A, 2006,65:591-597
13. [13]
  [13] Kulatilleke C P, Silva S A, Eliav Y. Polyhedron, 2006,25: 2593-2596
14. [14]
  [14] Xu Z Q, Laurence K, Thompson, et al. Inorg. Chem., 1997, 36:3985-3995
15. [15]
  [15] Sheldrick G M. SADABS, University of Göttingen, Germany, 1996.
16. [16]
  [16] Sheldrick G M. SHELX-97, Program for the Solution and the Refinement of Crystal Structures, University of Göttingen, Germany, 1997.
17. [17]
  [17] Addison A W, Rao T N. J. Chem. Soc. Dalton Trans., 1984,5:1349-1356
18. [18]
  [18] Song X Q, Zang Z P, Liu W S, et al. J. Solid State Chem., 2009,182:841-848
19. [19]
  [19] ZHUO Xin (卓馨), PAN Zhao-Rui (潘兆瑞), WANG Zuo- Wei (王作为), et al. Chinese J. Inorg. Chem.( 无机化学学报), 2006,22:1847-1851
1. [1]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
2. [2]
  Xiao SANG , Qi LIU , Jianping LANG . Synthesis, structure, and fluorescence properties of Zn(Ⅱ) coordination polymers containing tetra-alkenylpyridine ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2124-2132. doi: 10.11862/CJIC.20240158
3. [3]
  Xuewei BA , Cheng CHENG , Huaikang ZHANG , Deqing ZHANG , Shuhua LI . Preparation and luminescent performance of Sr_1-xZrSi₂O₇∶xDy³⁺ phosphor with high thermal stability. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 357-364. doi: 10.11862/CJIC.20240096
4. [4]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
5. [5]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
6. [6]
  Changqing MIAO , Fengjiao CHEN , Wenyu LI , Shujie WEI , Yuqing YAO , Keyi WANG , Ni WANG , Xiaoyan XIN , Ming FANG . Crystal structures, DNA action, and antibacterial activities of three tetranuclear lanthanide-based complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2455-2465. doi: 10.11862/CJIC.20240192
7. [7]
  Jing WU , Puzhen HUI , Huilin ZHENG , Pingchuan YUAN , Chunfei WANG , Hui WANG , Xiaoxia GU . Synthesis, crystal structures, and antitumor activities of transition metal complexes incorporating a naphthol-aldehyde Schiff base ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2422-2428. doi: 10.11862/CJIC.20240278
8. [8]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
9. [9]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
10. [10]
  Zuozhong Liang , Lingling Wei , Yiwen Cao , Yunhan Wei , Haimei Shi , Haoquan Zheng , Shengli Gao . Exploring the Development of Undergraduate Scientific Research Ability in Basic Course Instruction: A Case Study of Alkali and Alkaline Earth Metal Complexes in Inorganic Chemistry. University Chemistry, 2024, 39(7): 247-263. doi: 10.3866/PKU.DXHX202310103
11. [11]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173
12. [12]
  Yuchen Zhou , Huanmin Liu , Hongxing Li , Xinyu Song , Yonghua Tang , Peng Zhou . 设计热力学稳定的贵金属单原子光催化剂用于乙醇的高效非氧化转化形成高纯氢和增值产物乙醛. Acta Physico-Chimica Sinica, 2025, 41(6): 100067-. doi: 10.1016/j.actphy.2025.100067
13. [13]
  Yan Liu , Yuexiang Zhu , Luhua Lai . Introduction to Blended and Small-Class Teaching in Structural Chemistry: Exploring the Structure and Properties of Crystals. University Chemistry, 2024, 39(3): 1-4. doi: 10.3866/PKU.DXHX202306084
14. [14]
  Weina Wang , Fengyi Liu , Wenliang Wang . “Extracting Commonality, Delving into Typicals, Deriving Individuality”: Constructing a Knowledge Graph of Crystal Structures. University Chemistry, 2024, 39(3): 36-42. doi: 10.3866/PKU.DXHX202308029
15. [15]
  Junqiao Zhuo , Xinchen Huang , Qi Wang . Symbol Representation of the Packing-Filling Model of the Crystal Structure and Its Application. University Chemistry, 2024, 39(3): 70-77. doi: 10.3866/PKU.DXHX202311100
16. [16]
  Chen LU , Qinlong HONG , Haixia ZHANG , Jian ZHANG . Syntheses, structures, and properties of copper-iodine cluster-based boron imidazolate framework materials. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 149-154. doi: 10.11862/CJIC.20240407
17. [17]
  Feng Lu , Tao Wang , Qi Wang . Preparation and Characterization of Water-Soluble Silver Nanoclusters: A New Design and Teaching Practice in Materials Chemistry Experiment. University Chemistry, 2025, 40(4): 375-381. doi: 10.12461/PKU.DXHX202406005
18. [18]
  Wenyan Dan , Weijie Li , Xiaogang Wang . The Technical Analysis of Visual Software ShelXle for Refinement of Small Molecular Crystal Structure. University Chemistry, 2024, 39(3): 63-69. doi: 10.3866/PKU.DXHX202302060
19. [19]
  Linjie ZHU , Xufeng LIU . Electrocatalytic hydrogen evolution performance of tetra-iron complexes with bridging diphosphine ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 321-328. doi: 10.11862/CJIC.20240207
20. [20]
  Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(223)
HTML views(21)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142