Citation: GAO Peng, BING Ying-Ying, ZHANG Ling-Ling, HU Ming. Five Transition Metal Complexes with 5-Hydroxy-pyridine-2-carboxylic Acid: Syntheses, Crystal Structures and Luminescence Properties[J]. Chinese Journal of Inorganic Chemistry, ;2015, (11): 2236-2242. doi: 10.11862/CJIC.2015.287 shu

Five Transition Metal Complexes with 5-Hydroxy-pyridine-2-carboxylic Acid: Syntheses, Crystal Structures and Luminescence Properties

1.
Inner Mongolia Key Laboratory of Chemistry and Physics of Rare Earth Materials, School of Chemistry and Chemical Engineering, Inner Mongolia University, Hohhot 010021, China

Corresponding author: HU Ming,
Received Date: 8 June 2015
Available Online: 17 September 2015
Fund Project: 国家自然科学基金(No.21361017) (No.21361017)内蒙古自然科学基金(No.2012MS0214) (No.2012MS0214)内蒙古高等学校科学技术研究重点研究(No.NJZZ12012)资助项目。 (No.NJZZ12012)

Five transition metal complexes based on the 5-hydroxy-pyridine-2-carboxylic acid (H₂L) were synthesized under hydrothermal conditions, namely, [M(HL)₂(H₂O)₂] (M=Zn, 1; Mn, 2; Co, 3; Ni, 4), [Cu(HL)₂] (5). Compounds 1~5 were structurally characterized by the elemental analyses, infrared spectra, and single crystal X-ray diffractions. The structural analyses show that 1~5 are discrete mononuclear complexes, which are extended to form the 3D supramolecular frameworks by hydrogen bonds interactions. The solid-state photoluminescence of 1 and thermal properties of 1~5 were further explored, respectively.
- transition metal;coordination compound;hydrothermal synthesis;crystal structure
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