Citation: XU Han, ZHENG He-Gen. Syntheses, Crystal Structures and Fluorescent Properties of Two Coordination Polymers Based on 4,4'-Bis(imidazol-l-yl)diphenyl Thioether and Phthalic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2015, (11): 2272-2278. doi: 10.11862/CJIC.2015.284 shu

Syntheses, Crystal Structures and Fluorescent Properties of Two Coordination Polymers Based on 4,4'-Bis(imidazol-l-yl)diphenyl Thioether and Phthalic Acid

XU Han ^1,2 ,
ZHENG He-Gen ^2,,

1.
1 School of Chemistry and Chemical Engineering, Huangshan University, Huangshan, Anhui 245041, China;
2.
2 State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing 210093, China

Corresponding author: ZHENG He-Gen,
Received Date: 3 August 2015
Available Online: 11 September 2015
Fund Project: 国家重点基础研究发展计划(No.2010CB923303) (No.2010CB923303)国家自然科学基金(No.21371092) (No.21371092)安徽高校省级自然科学研究基金(No.KJ2013B274)资助项目。 (No.KJ2013B274)

Two coordination polymers {[Zn(BIDPT)(pht)]₂·2H₂O·CH₃OH}_n (1) and {[Cd₅(BIDPT)₄(pht)₅]·H₂O}_n (2) based on mixed-ligands, BIDPT (4,4'-bis(imidazol-l-yl)diphenyl thioether) and H₂pht (phthalic acid), have been synthesized by mild hydrothermal method and characterized by single-crystal X-ray diffraction, elemental analysis, IRspectra. The results show that 1 and 2 feature 2D networks. Compound 1 crystallizes in the orthorhombic system, space group Pbcn. Compound 2 crystallizes in the monoclinic system of the P2₁/c space group. The thermal stability and luminescent properties of compounds 1 and 2 are also investigated.
- coordination polymer;crystal structure;photoluminescence;synthesis
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