Citation: ZHANG Yan-Ru, WANG Meng-Qin, CUI Yang-Zhe, LIU Min, LI Zhong-Feng, JIN Qiong-Hua. Syntheses and Characterization of Two Luminescent Silver(Ⅰ) Complexes Based on Mixed Phosphine Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(10): 2089-2094. doi: 10.11862/CJIC.2015.274 shu

Syntheses and Characterization of Two Luminescent Silver(Ⅰ) Complexes Based on Mixed Phosphine Ligands

1.
1 Department of Chemistry, Capital Normal University, Beijing 100048, China;
2.
2 College of Materials Science and Engineering, Beijing University of Technology, Beijing 100124, China

Corresponding author: JIN Qiong-Hua,
Received Date: 28 June 2015
Available Online: 12 July 2015
Fund Project: 国家自然科学基金(No.21171119) (No.21171119)863国家高技术研究发展计划(No.2012AA063201) (No.2012AA063201)北京教育委员会基金(No.KM201210028020) (No.KM201210028020)北京市优秀人才项目(No.2010D005016000002) (No.2010D005016000002)北京市自然科学基金(No.7122015)资助项目。 (No.7122015)

Two novel silver(Ⅰ) complexes [Ag₂Br₂(DPEphos)₂(dppe)](1) and [Ag(DPEphos)(dppe)]NO₃(2) (DPEphos=bis[2-(diphenylphosphino)phenyl]ether, dppe=bis(diphenylphosphino)ethane) have been synthesized and characterized by IR, single-crystal X-ray diffraction, ¹H NMR, ³¹P NMR spectroscopy and fluorescence spectra. 1 is comprised of AgBr, DPEphos and dppe in 2:2:1 molar ratio generating a binuclear complex. The dppe ligand bridges two Ag atoms through two P atoms in 1. While, 2 is obtained by the reactions of AgNO₃, DPEphos and dppe in 1:1:1 molar ratio generating a sample mono-nuclear complex. The Ag(Ⅰ) atom is chelated by DPEphos and dppe ligand. In the ³¹P NMR spectra of 2, there are four splitting signals (doublets or triplets). The luminescent spectra show that the origin of these emissions all involves emissive state derived from ligand centered π-π^* transition. CCDC: 1043375, 1; 1043376, 2.
- bis[2-(diphenylphosphino)phenyl]ether;bis(diphenylphosphino)ethane;silver(Ⅰ);fluorescence
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