Citation: Ikhile Monisola I, Ngila J Catherine. Synthesis and Characterization of Some Ferrocenylphenylimine Compounds[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(10): 2079-2088. doi: 10.11862/CJIC.2015.272 shu

Synthesis and Characterization of Some Ferrocenylphenylimine Compounds

Ikhile Monisola I ^, ,
Ngila J Catherine ^,

1.
Department of Applied Chemistry, University of Johannesburg, Doornfontein Campus, P. O. Box 17011, Doornfontein 2028, Johannesburg, South Africa

Corresponding author: Ikhile Monisola I, Ngila J Catherine,
Received Date: 23 June 2015
Available Online: 31 August 2015
Fund Project:

A novel series of ferrocenylimine compounds (5~12) were synthesized via the same route by refluxing a mixture of corresponding ferrocenylaniline with aromatic aldehyde. Compounds 5~12 were air stable without any decomposition when exposed to air. The compounds were all characterized by ¹H and ¹³C NMR spectroscopy, mass spectrometry, IR, UV-Visible and elemental analysis. The single crystal structure of compound 10 was also reported, which revealed that compound 10 crystallized in monoclinic system with P2₁/c space group. CCDC: 1010246, 10.
- ferrocene;synthesis;characterization;imine;X-ray diffraction
1. [1]
  [1] Coleman K S, Turberville S, Pascu S I, et al. J. Organomet. Chem., 2005,690:653-658
2. [2]
  [2] Ikhile M I, Bala M D, Nyamori V O, et al. Appl. Organometal. Chem., 2013,27:98-108
3. [3]
  [3] Togni A, Hayashi T (Eds.) Ferrocenes:Homogeneous Catalysis, Organic Synthesis and Material Science. Weinheim:VCH, 1995.
4. [4]
  [4] Diallo A K, Ornelas C, Salmon L, et al. Chem. Commun., 2007:4946-4948
5. [5]
  [5] Nazarov A A, Hartinger C. G, Arion V B, et al. Tetrahedron, 2002,58:8489
6. [6]
  [6] Gibson V C, Gregson C K A, Halliwell C M, et al. Organomet. Chem., 2004,690:6271-6283
7. [7]
  [7] Andrieux C P, Blocman C, Dumas-Bouchiat J M, et al. J. Am. Chem. Soc., 1980,102:3806-3813
8. [8]
  [8] Ferreira C L, Ewart C B, Barta C A, et al. Inorg. Chem., 2006,45:8414-8422
9. [9]
  [9] Mishra L, Dubey S K. Spectrochim. Acta A, 2007,68:364-368
10. [10]
  [10] Bildstein B, Malaun M, Kopacka H, et al. J. Organomet. Chem., 1999,572:177-187
11. [11]
  [11] Thomas J L, Howarth J, Kennedy A M. Molecules, 2002,7:861-866
12. [12]
  [12] Bai Y, Zhang B G, Duan C Y, et al. New J. Chem., 2006, 30:266-271
13. [13]
  [13] Ling S, Xin Z, Yan H, et al. Chin. Chem. Lett., 2006,36:325-330
14. [14]
  [14] Van Staveren D R, Metzler-Nolte N. Chem. Rev., 2004,104:5931-5985
15. [15]
  [15] Allardyce C S, Dorcier A, Scolaro C, et al. Appl. Organomet. Chem., 2005,19:1-10
16. [16]
  [16] Neuse E W J. Inorg. Organomet. Polym. Mater., 2005,15:3-32
17. [17]
  [17] Fouda M F R, Abd-Elzaher M M, Abdelsamaia R A, et al. Appl. Organomet. Chem., 2007,21:613-625
18. [18]
  [18] Ornelas C. New J. Chem., 2011,35:1973-1985
19. [19]
  [19] Mathiyalagan K, Gopal S, Ramasamy E, et al. Int. J. ChemTech Res., 2012,4:1775-1781
20. [20]
  [20] Kondapi A K, Satyanarayana N, Saikrishna A D. Arch. Biochem. Biophys., 2006,450:123-132
21. [21]
  [21] Itoh T, Shirakami S, Ishida N, et al. Bioorg. Med. Chem. Lett., 2000,10:1657-1659
22. [22]
  [22] Zhang J. Appl. Organomet. Chem., 2008,22:6-11
23. [23]
  [23] Hillard E A, Vessieres A, Jaouen G. Top Organomet. Chem., 2010,32:81-117
24. [24]
  [24] Mohammed I A, Subrahmanyam E V S. Acta Pharma. Sci., 2009,51:163-168
25. [25]
  [25] Anand P, Patil V M, Sharma V K, et al. Int. J. Drug. Des. Discov., 2012,3:851-868
26. [26]
  [26] Hranjec M, Starcevic K, Pavelic K S, et al. Eur. J. Med. Chem., 2011,46:2274-2279
27. [27]
  [27] Chetan B, Bunha M, Jagrat M, et al. Bioorg. Med. Chem. Lett., 2010,20:3906-3910
28. [28]
  [28] Kundariya D S, Bheshdadia B M, Joshi N K, et al. Int. J. Chem. Tech. Res., 2011,3:238-243
29. [29]
  [29] Thomas A B, Nanda R K, Kothapalli L P, et al. Arabian J. Chem., 2011,55:960-968
30. [30]
  [30] Sondhi S, Singh N, Kumar A, et al. Bioorg. Med. Chem., 2006,14:3758-3765
31. [31]
  [31] Kumar K S, Ganguly S, Veerasamy R, et al. Eur. J. Med. Chem., 2010,45:5474-5479
32. [32]
  [32] Shreenivas M T, Chetan B P, Bhat A R. J. Pharm. Sci. Tech., 2009,1:88-94
33. [33]
  [33] Sashidhara K V, Rosaiah J N, Bhatia G, et al. Eur. J. Med. Chem., 2008,43:2592-2596
34. [34]
  [34] Baluja S, Solanki A, Kachhadia N. J. Iranian Chem. Soc., 2006,3:312-317
35. [35]
  [35] Khan K M, Khan M, Ali M, et al. Bioorg. Med. Chem., 2009,17:7795-7801
36. [36]
  [36] Aly M M, Mohameda Y A, El-Bayouki K A M, et al. Eur. J. Med. Chem., 2010,45:3365-3373
37. [37]
  [37] Bhat M A, Al-Omar M A. Acta Poloniae Pharmaceutica Drug Res., 2011,64:375-380
38. [38]
  [38] Zaheer M, Shah A, Akhter Z, et al. Appl. Organometal. Chem., 2011,25:61-69
39. [39]
  [39] Chen W O, Wang L, Hao Y, et al. Dalton Trans., 2013,42:15678-15686
40. [40]
  [40] Abd-Elzaher M M. Chin. J. Chem. Soc., 2004,51:499-504
41. [41]
  [41] Ping H, Zhao K Q, Xu H B. Molecules, 2001,6:M250 DOI:10.3390/M250
42. [42]
  [42] Dolomanov O V, Bourhis L J, Gildea R J, et al. J. Appl. Cryst., 2009,42:339-341
43. [43]
  [43] Sheldrick G M. Acta Cryst., 2008,A64:112-122
44. [44]
  [44] Ping H, Zhao K Q, Xu H B. Molecules, 2001,6:M249 DOI:10.3390/M249
45. [45]
  [45] Motswainyana W M, Onani M O, Madieke A M. Polyhedron, 2014,41:44-51
1. [1]
  Wei Li , Guoqiang Feng , Ze Chang . Teaching Reform of X-ray Diffraction Using Synchrotron Radiation in Materials Chemistry. University Chemistry, 2024, 39(3): 29-35. doi: 10.3866/PKU.DXHX202308060
2. [2]
  Jing WU , Puzhen HUI , Huilin ZHENG , Pingchuan YUAN , Chunfei WANG , Hui WANG , Xiaoxia GU . Synthesis, crystal structures, and antitumor activities of transition metal complexes incorporating a naphthol-aldehyde Schiff base ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2422-2428. doi: 10.11862/CJIC.20240278
3. [3]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
4. [4]
  Jiaming Xu , Yu Xiang , Weisheng Lin , Zhiwei Miao . Research Progress in the Synthesis of Cyclic Organic Compounds Using Bimetallic Relay Catalytic Strategies. University Chemistry, 2024, 39(3): 239-257. doi: 10.3866/PKU.DXHX202309093
5. [5]
  Lirui Shen , Kun Liu , Ying Yang , Dongwan Li , Wengui Chang . Synthesis and Application of Decanedioic Acid-N-Hydroxysuccinimide Ester: Exploration of Teaching Reform in Comprehensive Applied Chemistry Experiment. University Chemistry, 2024, 39(8): 212-220. doi: 10.3866/PKU.DXHX202312035
6. [6]
  Tingting Yu , Si Chen , Lianglong Sun , Tongtong Shi , Kai Sun , Xin Wang . Comprehensive Experimental Design for the Photochemical Synthesis, Analysis, and Characterization of Difluoropyrroles. University Chemistry, 2024, 39(11): 196-203. doi: 10.3866/PKU.DXHX202401022
7. [7]
  Jianfeng Yan , Yating Xiao , Xin Zuo , Caixia Lin , Yaofeng Yuan . Comprehensive Chemistry Experimental Design of Ferrocenylphenyl Derivatives. University Chemistry, 2024, 39(4): 329-337. doi: 10.3866/PKU.DXHX202310005
8. [8]
  Qilu DU , Li ZHAO , Peng NIE , Bo XU . Synthesis and characterization of osmium-germyl complexes stabilized by triphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1088-1094. doi: 10.11862/CJIC.20240006
9. [9]
  Hongwei Ma , Hui Li . Three Methods for Structure Determination from Powder Diffraction Data. University Chemistry, 2024, 39(3): 94-102. doi: 10.3866/PKU.DXHX202310035
10. [10]
  Liang TANG , Jingfei NI , Kang XIAO , Xiangmei LIU . Synthesis and X-ray imaging application of lanthanide-organic complex-based scintillators. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1892-1902. doi: 10.11862/CJIC.20240139
11. [11]
  Jiaxin Su , Jiaqi Zhang , Shuming Chai , Yankun Wang , Sibo Wang , Yuanxing Fang . Optimizing Poly(heptazine imide) Photoanodes Using Binary Molten Salt Synthesis for Water Oxidation Reaction. Acta Physico-Chimica Sinica, 2024, 40(12): 2408012-. doi: 10.3866/PKU.WHXB202408012
12. [12]
  Fei Liu , Dong-Yang Zhao , Kai Sun , Ting-Ting Yu , Xin Wang . Comprehensive Experimental Design for Photochemical Synthesis, Analysis, and Characterization of Seleno-Containing Medium-Sized N-Heterocycles. University Chemistry, 2024, 39(3): 369-375. doi: 10.3866/PKU.DXHX202309047
13. [13]
  Aidang Lu , Yunting Liu , Yanjun Jiang . Comprehensive Organic Chemistry Experiment: Synthesis and Characterization of Triazolopyrimidine Compounds. University Chemistry, 2024, 39(8): 241-246. doi: 10.3866/PKU.DXHX202401029
14. [14]
  Jinfeng Chu , Yicheng Wang , Ji Qi , Yulin Liu , Yan Li , Lan Jin , Lei He , Yufei Song . Comprehensive Chemical Experiment Design: Convenient Preparation and Characterization of an Oxygen-Bridged Trinuclear Iron(III) Complex. University Chemistry, 2024, 39(7): 299-306. doi: 10.3866/PKU.DXHX202310105
15. [15]
  Jiapei Zou , Junyang Zhang , Xuming Wu , Cong Wei , Simin Fang , Yuxi Wang . A Comprehensive Experiment Based on Electrocatalytic Nitrate Reduction into Ammonia: Synthesis, Characterization, Performance Exploration, and Applicable Design of Copper-based Catalysts. University Chemistry, 2024, 39(6): 373-382. doi: 10.3866/PKU.DXHX202312081
16. [16]
  Yikai Wang , Xiaolin Jiang , Haoming Song , Nan Wei , Yifan Wang , Xinjun Xu , Cuihong Li , Hao Lu , Yahui Liu , Zhishan Bo . 氰基修饰的苝二酰亚胺衍生物作为膜厚不敏感型阴极界面材料用于高效有机太阳能电池. Acta Physico-Chimica Sinica, 2025, 41(3): 2406007-. doi: 10.3866/PKU.WHXB202406007
17. [17]
  Li'na ZHONG , Jingling CHEN , Qinghua ZHAO . Synthesis of multi-responsive carbon quantum dots from green carbon sources for detection of iron ions and L-ascorbic acid. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 709-718. doi: 10.11862/CJIC.20240280
18. [18]
  Liangzhen Hu , Li Ni , Ziyi Liu , Xiaohui Zhang , Bo Qin , Yan Xiong . A Green Chemistry Experiment on Electrochemical Synthesis of Benzophenone. University Chemistry, 2024, 39(6): 350-356. doi: 10.3866/PKU.DXHX202312001
19. [19]
  Yinwu Su , Xuanwen Zheng , Jianghui Du , Boda Li , Tao Wang , Zhiyan Huang . Green Synthesis of 1,3-Dibromoacetone Using Halogen Exchange Method: Recommending a Basic Organic Synthesis Teaching Experiment. University Chemistry, 2024, 39(5): 307-314. doi: 10.3866/PKU.DXHX202311092
20. [20]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(205)
HTML views(1)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142