Citation: KUANG Dai-Zhi, ZHU Xiao-Ming, FENG Yong-Lan, ZHANG Fu-Xing, YU Jiang-Xi, JIANG Wu-Jiu, TAN Yu-Xing, ZHANG Zhi-Jian. Syntheses, Crystal Structures and Biological Activities of Bis(tricyclohexyltin)dicarboxylates with Macrocyclic Building 2D Network[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(10): 2044-2050. doi: 10.11862/CJIC.2015.268 shu

Syntheses, Crystal Structures and Biological Activities of Bis(tricyclohexyltin)dicarboxylates with Macrocyclic Building 2D Network

1.
1 College of Chemistry and Material Science, Hengyang Normal University;Key Laboratory of Functional Organometallic Materials of Hengyang Normal University, College of Hunan Province, Hengyang, Hunan 421008, China;
2.
2 College of Life Science and Environment, Hengyang Normal University, Hengyang, Hunan 421008, China

Corresponding author: KUANG Dai-Zhi,
Received Date: 26 May 2015
Available Online: 15 July 2015
Fund Project: 湖南省自然科学基金(13JJ3112) (13JJ3112)科技计划(2014NK3086,2014FJ3060)项目,功能金属有机材料湖南省普通高校重点实验室开放基金资助项目(13K105,14K014,13K01-05,GN14K01) (2014NK3086,2014FJ3060)项目,功能金属有机材料湖南省普通高校重点实验室开放基金资助项目(13K105,14K014,13K01-05,GN14K01)湖南省重点学科基金和湖南省高校科技创新团队支持计划资助项目,衡阳师范学院协同创新中心培育项目(No.12XT02) (No.12XT02)湖南省教育厅基金项目(No.15C0199,15C0200,14C0171,14C0168)资助。 (No.15C0199,15C0200,14C0171,14C0168)

Two bis(tricyclohexyltin)dicarboxylate(CH₂)_n(CO₂SnCy₃)₂[(n:6(1), 7(2)] have been synthesized by the reaction of suberic acid and azelaic acid with tricyclohexyltin hydroxide, respectively. The structures of the products were confirmed by IR, ¹H and ¹³C NMR, elemental analysis and X-ray diffraction. The complexes 1 and 2 belong to monoclinic, space group P2₁/n and P2₁/c. A 2D network structure was formed by 30-membered or 32-membered macrocyclic tetratin species, which has been alternately connected through the Sn-O covalent bond or the Sn-O covalent bond and Sn...O weak interaction, respectively. The tests showed the two complexes displayed strong in vitro anti-tumor activity against five human tumor cell lines, Colo205, HepG2, MCF-7, Hela and NCI-H460 and has selective antibacterial property for S. Aureus, B. Subtilis, E. Coli and S. Typhi. CCDC: 1047100,11; 1047101,2.
- bis(tricyclohexyltin)dicarboxylate;macrocycle compounds;crystal structure;biological activity
1. [1]
  [1] Yin H D, Dong L, Hong M, et al. J. Organomet. Chem., 2011,696(9):1824-1833
2. [2]
  [2] Deblitz R, Hrib C G, Plenikowski G, et al. Inorg. Chem. Commun., 2012,18:57-60
3. [3]
  [3] Du D F, Jiang Z J, Liu C L, et al. J. Organomet. Chem., 2011,696(13):2549-2558
4. [4]
  [4] Chandrasekhar V, Thirumoorthi R, Metre R K, et al. J. Organomet. Chem., 2011,696(2):600-606
5. [5]
  [5] Sirajuddin M, Ali S, Haider A, et al. Polyhedron., 2012,40(1):19-31
6. [6]
  [6] Affan M A, Salam M A, Ahmad F B, et al. Inorg. Chim. Acta, 2011,366(1):227-232
7. [7]
  [7] Yin H D, Hong M, Yang M L, et al. J. Mol. Struct., 2010, 984:383-388
8. [8]
  [8] Deblitz R, Hrib C G, Plenikowski G, et al. Inorg. Chem. Commun., 2012,18:57-60
9. [9]
  [9] Ng S W, Das V G K. J. Organomet. Chem., 1993,456(2):175-179
10. [10]
  [10] Ng S W, Das V G K. J. Organomet. Chem., 1990,390(1):19-28
11. [11]
  [11] Ng S W, Das V G K, Gielen M, et al. Appl. Organomet. Chem., 1992,6(1):19-25
12. [12]
  [12] Ng S W, Das V G K. J. Organomet. Chem., 1994,467(1):47-49
13. [13]
  [13] Gueye N, Diop L, Molloy K C K, et al. Acta Cryst., 2010, E66:m1645-m1646
14. [14]
  [14] Ng S W, Das V G K. J. Organomet. Chem., 1992,430(2):139-148
15. [15]
  [15] Anjorin C, Song X Q, Kumar D, et al. J. Coord. Chem., 2010,63(23):4031-4040
16. [16]
  [16] Ng S W. Acta Cryst. E., 1998,C54:1368-1389
17. [17]
  [17] Ng S W. Acta Cryst. E., 1998,C54:745-750
18. [18]
  [18] CAO Hui(曹慧), LI Dong-Liang(李东亮), Yu You(于游), et al. J. Jinggangshan University:Nat. Sci.(井冈山大学学报), 2012,33(4):30-33
19. [19]
  [19] Ibrahima C, Omar G, Bernard M, et al. Appl. Organomet. Chem., 2003,17(10):821-822
20. [20]
  [20] YIN Han-Dong(尹汉东), WANG Chuan-Hua(王传华), MA Chun-Lin(马春林), et al. Chinese J. Struct. Chem.(结构化学), 2003,22(4):387-390
21. [21]
  [21] Alejandro R R, Masood P, Viqar U A, et al. Acta Cryst. E., 2002,58:278-280
22. [22]
  [22] MA Chun-Lin(马春林), ZHANG Ru-Fen(张汝芬), ZHU De-Zhong(朱德中), et al. Chinese J. Struct. Chem.(结构化学), 2002,21(6):659-662
23. [23]
  [23] YIN Han-Dong(尹汉东), WANG Chuan-Hua(王传华), WANG Yong(王勇), et al. Chin. J. Org. Chem.(有机化学), 2002,22(7):489-495
24. [24]
  [24] TAN Yu-Xing(谭宇星), FENG Yong-Lan(冯泳兰), YIN Du-Lin(尹笃林), et al. Chinese J. Inorg. Chem.(无机化学学报), 2014,30(12):2781-2788
25. [25]
  [25] YAN Wen-Hua(闫文华), KANG Wan-Li(康万利), LI Jin-Hua(李金环). Chemistry(化学通报), 2007,(4):313-316
26. [26]
  [26] Sheldrick G M. SHELXL97, Program for Crystal Structure Refinement, University of Gttingen, Germany, 1997.
27. [27]
  [27] Tian L J, Cao H, Wang S X, et al. J. Coord. Chem., 2013,66(4):624-637
28. [28]
  [28] YIN Han-Dong(尹汉东), CUI Ji-Chun(崔继春), LI Jing(李静). J Liaocheng University:Nat. Sci.(聊城大学学报), 2009,22(3):66-68
29. [29]
  [29] WENG Shi-Fu(翁诗甫). Fourier Translation Infrared Spectroscopy Analysis. 2nd Ed(傅里叶变换红外光谱分析. 2版). Beijing:Chemical Industry Press, 2005:305-306
30. [30]
  [30] XIE Qin-Lan(谢庆兰), HE Xi-Lin(贺烯林), HE Shui-Ji (贺水济), et al. Acta Chim. Sinica(化学学报), 1999,57:210-218
31. [31]
  [31] ZHANG Zhi-Jian(张志坚), KUANG Dai-Zhi(邝代治), ZHANG Fu-Xing(张复兴), et al. Chinese J. Appl. Chem. (应用化学), 2014,31(9):1058-1062
32. [32]
  [32] KUANG Dai-Zhi(邝代治), FENG Yong-Lan(冯泳兰), YU Jiang-Xi(庾江喜), et al. Chem. J. Chinese Universities(高等学校化学学报), 2014,35(8):1629-1634
33. [33]
  [33] YU Jiang-Xi(庾江喜), FENG Yong-Lan(冯泳兰), KUANG Dai-Zhi(邝代治), et al. Chinese J. Appl. Chem.(应用化学), 2014,31(8):937-942
34. [34]
  [34] YU Jiang-Xi(庾江喜), FENG Yong-Lan(冯泳兰), KUANG Dai-Zhi(邝代治), et al. Chinese J. Inorg. Chem.(无机化学学报), 2014,30(6):1267-1272
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